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Adsorption of 2-Chlorophenol on Hypercrosslinked Resins
Corresponding Author(s) : J.P. Wang
Asian Journal of Chemistry,
Vol. 25 No. 11 (2013): Vol 25 Issue 11
Abstract
Two kinds of hypercrosslinked resin ZH-01 and ZH-03 were prepared in this study. The batch static experiments were conducted to investigate the adsorption characteristics of 2-chlorophenol on the hypercrosslinked resins. The equilibrium adsorption data was fitted to Freundlich adsorption isotherm model to evaluate the related parameters. The results considering the changes of enthalpy, free energy, entropy indicated an exothermic, spontaneous and disorder decreasing process happens in the adsorption. The adsorbents prepared here are better than the Amberlite XAD-4 for removing the 2-chlorophenol in aqueous solutions, based on the adsorption capacity.
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- A. Dabrowski, P. Podkoscielny, Z. Hubicki and M. Barczak,Chemosphere, 58, 1049 (2005).
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- A.M. Li, Q.X. Zhang, G.C. Zhang, J.L. Chen, Z.H. Fei and F.Q. Liu, Chemosphere, 47, 981 (2002).
- R. Kunin, Pure Appl. Chem., 46, 205 (1976).
- V.V. Azanova and J. Hradil, React. Funct. Polym., 41, 163 (1999).
- P. Li and A.K. SenGupta, React. Funct. Polym., 44, 273 (2000).
- A.M. Li, Q.X. Zhang, C. Long, J.L. Chen and Z.H. Fei, Sep. Sci. Technol., 37, 3211 (2002).
- P.J. Dumont and J.S. Fritz, J. Chromatogr. A, 691, 123 (1995).
- R.A. Garcla-Delgado, L.M. Cotouelo-Minguez and J.J. Rodfiguez, Sep. Sci. Technol., 27, 975 (1992).
- P.B. John and T. Marios, J. Water Pollut. Contr., 59, 191 (1987).
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- Z.H. Fei, J.L. Chen, G.D. Gao,A.M. Li and Q.X. Zhang, Chin. J. Polym. Sci., 22, 425 (2004).
References
A. Dabrowski, P. Podkoscielny, Z. Hubicki and M. Barczak,Chemosphere, 58, 1049 (2005).
I. Rodriguez, M.H. Mejuto and R.C. Bollain, J. Chromatogr. A, 786, 285 (1997).
C. Long, J.D. Lu, A.M. Li, D.B. Hu and F.Q. Liu, J. Hazard. Mater., 150, 656 (2008).
B. Koumanova and P. Peeva-Antova, J. Hazard. Mater., 90, 229 (2002).
S. Rengaraj, S.H. Moon, R. Sivabalan, B. Arabindoo and V. Murugesan, J. Hazard. Mater., 89, 185 (2002).
A.M. Li, Q.X. Zhang, G.C. Zhang, J.L. Chen, Z.H. Fei and F.Q. Liu, Chemosphere, 47, 981 (2002).
R. Kunin, Pure Appl. Chem., 46, 205 (1976).
V.V. Azanova and J. Hradil, React. Funct. Polym., 41, 163 (1999).
P. Li and A.K. SenGupta, React. Funct. Polym., 44, 273 (2000).
A.M. Li, Q.X. Zhang, C. Long, J.L. Chen and Z.H. Fei, Sep. Sci. Technol., 37, 3211 (2002).
P.J. Dumont and J.S. Fritz, J. Chromatogr. A, 691, 123 (1995).
R.A. Garcla-Delgado, L.M. Cotouelo-Minguez and J.J. Rodfiguez, Sep. Sci. Technol., 27, 975 (1992).
P.B. John and T. Marios, J. Water Pollut. Contr., 59, 191 (1987).
R.L. Gustafson, R.L. Albright, Joel Heisler, J.A. Lirio and O.T. Reid Jr., Ind. Eng. Chem. Prod. Res. Develop., 7, 107 (1968).
Z.H. Fei, J.L. Chen, G.D. Gao,A.M. Li and Q.X. Zhang, Chin. J. Polym. Sci., 22, 425 (2004).