Copyright (c) 2013 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Removal of Toxic Lead Ions in Presence of Cationic Surfactants
Corresponding Author(s) : A.M. Ahmed
Asian Journal of Chemistry,
Vol. 25 No. 11 (2013): Vol 25 Issue 11
Abstract
The removal of toxic Pb2+ from waste water by cementation on rotating zinc cylinder takes place in absence and in presence of cationic surfactants as cetyl trimethylammonium bromide (CTAB) and cetyl pyridinium bromide (CPYB). The rate of removal of Pb2+ was studied under different conditions of rotation speed, initial Pb2+ concentration, temperature and different types of cationic surfactants. It was found that, the rate of removal of Pb2+ increases with increasing rotation speed (rpm) and temperatures. The presence of surfactants was found to decrease the rate of cementation. The decrease in the rate of cementation was ranged from 29 to 78 % depending on the type of surfactants and its concentration. Thermodynamic parameters DG*, DH* and DS* were calculated.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- N.R. Axtell, S.P.K. Sternberg and K. Claussen, Bioresour. Technol., 89, 41 (2003).
- D. Ozdes, A. Gundogdu, B. Kemer and C. Duran, J. Hazard. Mater., 166, 1480 (2009).
- T.G. Kazi, N. Jalbani, N. Kazi, M.K. Jamali, M.B. Arain, H.I. Afridi, A. Kandhro and Z. Pirzado, Renal Failure, 30, 737 (2008).
- H.I. Afridi, T.G. Kazi, G.H. Kazi, M.K. Jamali and G.Q. Shar, Biol. Trace Elem. Res., 113, 19 (2006).
- M. Soylak, L. Elci, Y. Akkaya and M. Dogan, Anal. Lett., 35, 487 (2002).
- N. Unlu and M. Ersoz, J. Hazard. Mater., 136, 272 (2006).
- J.W. Patterson, Wastewater Treatment Technology, Ann Arbor Science, Ann Arbor, MI, edn. 3 (1978).
- M. Sittig, Pollutant Removal Handbook, Noyes Data Coperation, London, edn. 1 (1973).
- M.A. Slapic, J. Wat. Pollut. Cont. Fed., 3, 238 (1982).
- T. Agelidis, K. Fytianos and G. Vasilikiotis, Environ. Pollut., 50, 243 (1988).
- T. Agelidis, K. Fytianos and G. Vasilikiotis,Chemosphere, 18, 1001 (1985).
- A.S. Özcan, Ö. Gok and A. Özcan, J. Hazard. Mater., 161, 499 (2009).
- A.K. Biswas and W.G. Daven, Part Extractuve Metallurgy of Copper Lergamon Press, New York (1979).
- V. Ettel, in ed.: J.O.M. Bockris, Comprehensive Treatise in Electrochemistry, Plenum, New York, Vol. 2 (1981).
- P. Bro and K.C. Lang, Environ. Sci. Technol., 8, 925 (1974).
- G. Genon and P. Parti, Gaglia Chem. Ind. (Milan), 65, 79 (1983).
- G.P. Power and I.M. Ritchie, Metal Displacement Reaction in Modern Aspects of Electrochemistry, Plenum Press, London, Vol. 2.
- A.M. Ismail, G.A. El-Nagger and A.M. Ahmed, Bull. Electrochem., 17, 385 (2001).
- D.A. El-Monem, M.Sc. Thesis, Faculty of Science, Alexandria University, Alexandria, Egypt (2001).
- K. Kubo and A. Mishima, J. Chem. Eng. Jpn., 12, 495 (1979).
- K. Kubo and T. Aratani, Bull. Osaka Pref. Tech. College, 21, 49 (1987).
- G. Rossi, Biohydrometallurgy, McGraw-Hill, New York, edn. 1 (1990).
- P.H. Strickland and F. Lawson, Proc. Aust. Inst. Min., 236, 25 (1970).
- A. Findly and A.J. Kitchener, Practical Physical Chemistry, Longmans, London, edn. 8 (1965).
- A.M. Ahmed and Sh.M. Zourab, Z. Metalked., 74, 471 (1988).
- K. Aramaki and N. Hackerman, J. Electrochem. Soc., 116, 568 (1969).
References
N.R. Axtell, S.P.K. Sternberg and K. Claussen, Bioresour. Technol., 89, 41 (2003).
D. Ozdes, A. Gundogdu, B. Kemer and C. Duran, J. Hazard. Mater., 166, 1480 (2009).
T.G. Kazi, N. Jalbani, N. Kazi, M.K. Jamali, M.B. Arain, H.I. Afridi, A. Kandhro and Z. Pirzado, Renal Failure, 30, 737 (2008).
H.I. Afridi, T.G. Kazi, G.H. Kazi, M.K. Jamali and G.Q. Shar, Biol. Trace Elem. Res., 113, 19 (2006).
M. Soylak, L. Elci, Y. Akkaya and M. Dogan, Anal. Lett., 35, 487 (2002).
N. Unlu and M. Ersoz, J. Hazard. Mater., 136, 272 (2006).
J.W. Patterson, Wastewater Treatment Technology, Ann Arbor Science, Ann Arbor, MI, edn. 3 (1978).
M. Sittig, Pollutant Removal Handbook, Noyes Data Coperation, London, edn. 1 (1973).
M.A. Slapic, J. Wat. Pollut. Cont. Fed., 3, 238 (1982).
T. Agelidis, K. Fytianos and G. Vasilikiotis, Environ. Pollut., 50, 243 (1988).
T. Agelidis, K. Fytianos and G. Vasilikiotis,Chemosphere, 18, 1001 (1985).
A.S. Özcan, Ö. Gok and A. Özcan, J. Hazard. Mater., 161, 499 (2009).
A.K. Biswas and W.G. Daven, Part Extractuve Metallurgy of Copper Lergamon Press, New York (1979).
V. Ettel, in ed.: J.O.M. Bockris, Comprehensive Treatise in Electrochemistry, Plenum, New York, Vol. 2 (1981).
P. Bro and K.C. Lang, Environ. Sci. Technol., 8, 925 (1974).
G. Genon and P. Parti, Gaglia Chem. Ind. (Milan), 65, 79 (1983).
G.P. Power and I.M. Ritchie, Metal Displacement Reaction in Modern Aspects of Electrochemistry, Plenum Press, London, Vol. 2.
A.M. Ismail, G.A. El-Nagger and A.M. Ahmed, Bull. Electrochem., 17, 385 (2001).
D.A. El-Monem, M.Sc. Thesis, Faculty of Science, Alexandria University, Alexandria, Egypt (2001).
K. Kubo and A. Mishima, J. Chem. Eng. Jpn., 12, 495 (1979).
K. Kubo and T. Aratani, Bull. Osaka Pref. Tech. College, 21, 49 (1987).
G. Rossi, Biohydrometallurgy, McGraw-Hill, New York, edn. 1 (1990).
P.H. Strickland and F. Lawson, Proc. Aust. Inst. Min., 236, 25 (1970).
A. Findly and A.J. Kitchener, Practical Physical Chemistry, Longmans, London, edn. 8 (1965).
A.M. Ahmed and Sh.M. Zourab, Z. Metalked., 74, 471 (1988).
K. Aramaki and N. Hackerman, J. Electrochem. Soc., 116, 568 (1969).