Synthesis and Structural Characterization of a Novel Carboxy-Functionalized Diiron Dithiolate Complex

Pei-Hua Zhao; Ya-Qing Liu; Xin-ang Li

doi:10.14233/ajchem.2013.14537

Issue

Vol. 25 No. 10 (2013): Vol 25 Issue 10

Issue Published : April 29, 2013

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Structural Characterization of a Novel Carboxy-Functionalized Diiron Dithiolate Complex

https://doi.org/10.14233/ajchem.2013.14537

Pei-Hua Zhao

Research Center for Engineering Technology of Polymeric Composites of Shanxi Province, College of Materials Science and Engineering, North University of China, Taiyuan 030051, P.R. China

Ya-Qing Liu

Research Center for Engineering Technology of Polymeric Composites of Shanxi Province, College of Materials Science and Engineering, North University of China, Taiyuan 030051, P.R. China

Xin-ang Li

Research Center for Engineering Technology of Polymeric Composites of Shanxi Province, College of Materials Science and Engineering, North University of China, Taiyuan 030051, P.R. China

Corresponding Author(s) : Pei-Hua Zhao

zph2004@yahoo.com.cn

Asian Journal of Chemistry, Vol. 25 No. 10 (2013): Vol 25 Issue 10
Article Published : May 2, 2013

Abstract

A novel carboxy-functionalized diiron dithiolate complex, [(μ-SCH₂)₂NCH₂CH₂CO₂CH₂CH₂Cl][Fe₂(CO)₆] (I) as active site model of [FeFe]-hydrogenase, has been successfully synthesized by condensation reaction of [(μ-SCH₂)₂NCH₂CH₂CO₂H][Fe₂(CO)₆] (A) with HOCH₂CH₂Cl in the presence of 4-dimethylaminopyridine and dicyclohexylcarbodiimide. Its structure was characterized by combustion analysis, ESI-MS, IR and ¹H (¹³C) NMR spectroscopic techniques.

Keywords

Carboxy-functionalized Diiron dithiolate Synthesis Structural characterization

Zhao, P.-H., Liu, Y.-Q., & Li, X.- ang. (2013). Synthesis and Structural Characterization of a Novel Carboxy-Functionalized Diiron Dithiolate Complex. Asian Journal of Chemistry, 25(10), 5428–5430. https://doi.org/10.14233/ajchem.2013.14537

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References

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Y. Nicolet, C. Piras, P. Legrand, C.E. Hatchikian and J.C. FontecillaCamps, Structure, 7, 13 (1999).
A. Le Cloirec, S.P. Best, S.C. Davies, D.J. Evans, D.L. Hughes and C.J. Pickett, Chem. Commun., 2285 (1999).
H. Fan and M.B. Hall, J. Am. Chem. Soc., 123, 3828 (2001).
Y. Nicolet, B.J. Lemon, J.C. Fontecilla-Camps and J.W. Peters, Trends Biochem. Sci., 25, 138 (2000).
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W.M. Gao, J.L. Sun, T. Åkermark, M.R Li, L. Eriksson, L. Sun and B. Åkermark, Chem. Eur. J., 16, 2537 (2010)

References

(a) H. Ogino, S. Inomata and H. Tobita, Chem. Rev., 98, 2093 (1998); (b) L.C. Song, Trends Organomet. Chem., 3, 1 (1999); (c) L.C. Song, Acc. Chem. Res., 38, 21 (2005); (d) L.C. Song, P.H. Zhao, Z.Q. Du, M.Y. Tang and Q.M. Hu, Organometallics, 29, 5751 (2010).

(a) M. Stephenson and L.H. Stickland, Biochem. J., 25, 205 (1931); (b) R. Cammack, Nature, 397, 214 (1999); (c) M.Y. Darensbourg, E.J. Lyon and J.J. Smee, Coord. Chem. Rev., 206-207, 533 (2000); (d) J.F. Capon, F. Gloaguen, P. Schollhammer and J. Talarmin, Coord. Chem. Rev., 249, 1664 (2005); (e) J.C. Fontecilla-Camps, A. Volbeda, C. Cavazza and Y. Nicolet, Chem. Rev., 107, 4273 (2007).

J.W. Peters, W.N. Lanzilotta, B.J. Lemon and L.C. Seefeldt, Science, 282, 1853 (1998).

Y. Nicolet, C. Piras, P. Legrand, C.E. Hatchikian and J.C. FontecillaCamps, Structure, 7, 13 (1999).

A. Le Cloirec, S.P. Best, S.C. Davies, D.J. Evans, D.L. Hughes and C.J. Pickett, Chem. Commun., 2285 (1999).

H. Fan and M.B. Hall, J. Am. Chem. Soc., 123, 3828 (2001).

Y. Nicolet, B.J. Lemon, J.C. Fontecilla-Camps and J.W. Peters, Trends Biochem. Sci., 25, 138 (2000).

(a) C. Tard and C.J. Pickett, Chem. Rev., 109, 2245 (2009); (b) F. Gloaguen and T.B. Rauchfuss, Chem. Soc. Rev., 38, 100 (2009); (c) M.H. Harb, U.P. Apfel, T. Sakamoto, M. EI-khateeb and W. Weigand, Eur. J. Inorg. Chem., 986 (2011); (d) M.Y. Darensbourg and W. Weigand, Eur. J. Inorg. Chem., 994 (2011); (e) X.F. Liu and Y.B. Shao, J. Coord. Chem., 63, 4061 (2010); (f) X.F. Liu, X.W. Xiao and L.J. Shen, J. Coord. Chem., 64, 1023 (2011); (g) B.S. Yin, T.B. Li and M.S. Yang, J. Coord. Chem., 64, 2066 (2011).

W.M. Gao, J.L. Sun, T. Åkermark, M.R Li, L. Eriksson, L. Sun and B. Åkermark, Chem. Eur. J., 16, 2537 (2010)

Issue

Vol. 25 No. 10 (2013): Vol 25 Issue 10

Synthesis and Structural Characterization of a Novel Carboxy-Functionalized Diiron Dithiolate Complex

Corresponding Author(s) : Pei-Hua Zhao

Abstract

Keywords

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