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Vol. 28 No. 5 (2016): Vol 28 Issue 5

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Use of Polyfuran/Chitosan Composite Films Deposited by Atmospheric Pressure Plasma Glow Discharge as Glucose Sensors

https://doi.org/10.14233/ajchem.2016.19093
Banu Esencan Turkaslan
Department of Chemical Engineering, Faculty of Engineering, Suleyman Demirel University, 32260 Isparta, Turkey
Taner Aktan
Department of Physics, Faculty of Arts and Science, Suleyman Demirel University, 32260 Isparta, Turkey
Lutfi Oksuz
Department of Physics, Faculty of Arts and Science, Suleyman Demirel University, 32260 Isparta, Turkey
Aysegul Uygun Oksuz
Department of Chemistry, Faculty of Arts and Science, Suleyman Demirel University, 32260 Isparta, Turkey

Corresponding Author(s) : Aysegul Uygun Oksuz

ayseguluygun@sdu.edu.tr

Asian Journal of Chemistry, Vol. 28 No. 5 (2016): Vol 28 Issue 5

Abstract

In this study, the properties of composites of polyfuran/chitosan (PFu/Ch) were electrochemically investigated as potential glucose sensors. Polyfuran (PFu) and polyfuran/chitosan composite films were coated onto indium thin oxide electrode by atmospheric pressure plasma glow discharge method.The prepared films were characterized by Fourier transform infrared spectroscopy and scanning electron microscopy analyses. Characteristic bands of both polyfuran and chitosan were observed in FTIR spectra of polyfuran/chitosan composite films. SEM images of the composite polyfuran/chitosan films showed more granular and porous surfaces than both of pure polyfuran and chitosan films. It was observed that though pure polyfuran films were not stable for glucose oxidase (GOD) immobilization. The polyfuran/chitosan composite films were quite stable and displayed good immobilization properties as enzyme sensors. Glucose oxidase enzyme electrodes were prepared onto the surface of polyfuran and polyfuran/chitosan composite films by physical adsorption method of glucose oxidize for comparison. Polyfuran/glucose oxidase and polyfuran/chitosan/glucose oxidase enzyme electrodes were utilized for glucose sensing using the amperometric method. The current response of polyfuran/chitosan/glucose oxidase electrode increased linearly with increasing glucose concentration, indicating a better glucose sensing for composite films.

Keywords

Atmospheric pressure plasma polymerization Polyfuran Chitosan Biosensor
Turkaslan, B. E., Aktan, T., Oksuz, L., & Oksuz, A. U. (2016). Use of Polyfuran/Chitosan Composite Films Deposited by Atmospheric Pressure Plasma Glow Discharge as Glucose Sensors. Asian Journal of Chemistry, 28(5), 941–946. https://doi.org/10.14233/ajchem.2016.19093
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