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Vol. 28 No. 5 (2016): Vol 28 Issue 5

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Bis(2-hydroxy-1-naphthalenehydrato) Metal Complexes as Source of Face-Centered-Cubic Trioctylphosphine Oxide-Capped ZnO and CdO Nanoparticles Using Oleylamine as Dispersion Medium

https://doi.org/10.14233/ajchem.2016.19565
T. Xaba
Department of Chemistry, Vaal University of Technology, P/Bag X021, Vanderbijlpark, South Africa
M.J. Moloto
Department of Chemistry, Vaal University of Technology, P/Bag X021, Vanderbijlpark, South Africa
N. Moloto
School of Chemistry, Wits University, P.O. Wits, Braamfontein 2025, South Africa

Corresponding Author(s) : M.J. Moloto

makwenam@vut.ac.za

Asian Journal of Chemistry, Vol. 28 No. 5 (2016): Vol 28 Issue 5

Abstract

[Bis(2-hydroxy-1-naphthaldehydato)zinc(II)] and cadmium(II) complexes were prepared, characterized to confirm the bidentate bonding to metal centre by aldehyde ligand through the two oxygen atoms. The complexes used as precursors for the synthesis of zinc and cadmium oxide nanoparticles via thermal decomposition method using oleylamine as a dispersion medium of the complexes prior to injection into trioctylphosphine oxide as a capping agent at 210 °C. The 4-coordinate complexes were confirmed by FTIR spectroscopy, elemental analysis and thermogravimetric analysis. The synthesized metal oxide nanoparticles gave the face-centered cubic phase of materials with average particle sizes of 4.12 (± 1.23) and 7.02 (± 2.57) nm for zinc and cadmium oxide nanoparticles, respectively.

Keywords

Naphthaldehyde ligand Metal oxide Nanoparticles Oleylamine Trioctylphosphine oxide
Xaba, T., Moloto, M., & Moloto, N. (2016). Bis(2-hydroxy-1-naphthalenehydrato) Metal Complexes as Source of Face-Centered-Cubic Trioctylphosphine Oxide-Capped ZnO and CdO Nanoparticles Using Oleylamine as Dispersion Medium. Asian Journal of Chemistry, 28(5), 1015–1020. https://doi.org/10.14233/ajchem.2016.19565
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References
  1. S. Priyarega, M.M. Tamizh, R. Karvembu, R. Prabhakaran and K. Natarajan, J. Chem. Sci., 123, 319 (2011); doi:10.1007/s12039-011-0087-2.
  2. H. Naeimi, Z. Sadat Nazifi, S. Matin Amininezhad and M. Amouheidari, J. Antibiot., 66, 687 (2013); doi:10.1038/ja.2013.73.
  3. W.F. Elseviers and H. Verelst, Fuel, 78, 601 (1999); doi:10.1016/S0016-2361(98)00185-9.
  4. K.M. Abd El-Salaam and E.A. Hassan, Surf. Technol., 16, 121 (1982); doi:10.1016/0376-4583(82)90031-0.
  5. R.Mochinaga, T.Yamasaki and T.Arakawa, Sens. Actuators B, 52, 96 (1998); doi:10.1016/S0925-4005(98)00262-7.
  6. D.G. Shchukin, D.V. Sviridov and A.I. Kulak, Sens. Actuators B, 76, 556 (2001); doi:10.1016/S0925-4005(01)00628-1.
  7. R.S. Mane, H.M. Pathan, C.D. Lokhande and S.-H. Han, Sol. Energy, 80, 185 (2006); doi:10.1016/j.solener.2005.08.013.
  8. K. Kalpanadevi, C.R. Sinduja and R. Manimekalai, Mater. Sci.-Poland, 32, 34 (2014); doi:10.2478/s13536-013-0153-1.
  9. W.-Y. Su, J.-S. Huang and C.-F. Lin, J. Cryst. Growth, 310, 2806 (2008); doi:10.1016/j.jcrysgro.2008.01.040.
  10. K. Gurumurugan, D. Mangalaraj and S.K. Narayandass, J. Cryst. Growth, 147, 355 (1995); doi:10.1016/0022-0248(94)00634-2.
  11. C.R.K. Rao and D.C. Trivedi, Synth. Met., 155, 324 (2005); doi:10.1016/j.synthmet.2005.01.038.
  12. T. Tsuji, D.-H. Thang, Y. Okazaki, M. Nakanishi, Y. Tsuboi and M. Tsuji, Appl. Surf. Sci., 254, 5224 (2008); doi:10.1016/j.apsusc.2008.02.048.
  13. N. Vigneshwaran, R.P. Nachane, R.H. Balasubramanya and P.V. Varadarajan, Carbohydr. Res., 341, 2012 (2006); doi:10.1016/j.carres.2006.04.042.
  14. R. Zamiri, B.Z. Azmi, M. Darroudi, A.R. Sadrolhosseini, M.S. Husin, A.W. Zaidan and M.A. Mahdi, Appl. Phys. A, 102, 189 (2011); doi:10.1007/s00339-010-6129-7.
  15. R. Kaur, A.V. Singh and R.M. Mehra, J. Non-Cryst. Solids, 352, 2335 (2006); doi:10.1016/j.jnoncrysol.2006.03.011.
  16. J. Zhang, H. Feng, W. Hao and T. Wang, J. Sol-Gel Sci. Technol., 39, 37 (2006); doi:10.1007/s10971-006-9416-1.
  17. W. Dong and C. Zhu, Opt. Mater., 22, 227 (2003); doi:10.1016/S0925-3467(02)00269-0.
  18. D. Sarkar, S. Tikku, V. Thapar, R.S. Srinivasa and K.C. Khilar, Colloids Surf. A, 381, 123 (2011); doi:10.1016/j.colsurfa.2011.03.041.
  19. F. Zhang, F.L. Bei, J.M. Cao and X. Wang, J. Solid State Chem., 181, 143 (2008); doi:10.1016/j.jssc.2007.11.004.
  20. Y. Wang and M. Li, Mater. Lett., 60, 266 (2006); doi:10.1016/j.matlet.2005.08.028.
  21. R.B. Waghulade, P.P. Patil and R. Pasricha, Talanta, 72, 594 (2007); doi:10.1016/j.talanta.2006.11.024.
  22. H.B. Lu, L. Liao, H. Li, Y. Tian, D.F. Wang, J.C. Li, Q. Fu, B.P. Zhu and Y. Wu, Mater. Lett., 62, 3928 (2008); doi:10.1016/j.matlet.2008.05.010.
  23. B. Yearwood, Am. J. Org. Chem., 4, 11 (2014); doi:10.5923/j.ajoc.20140401.02.
  24. A. Becheri, M. Dürr, P. Lo Nostro and P. Baglioni, J. Nanopart. Res., 10, 679 (2008); doi:10.1007/s11051-007-9318-3.
  25. M. Menelaou, K. Georgoula, K.Simeonidis and C. Dendrinou-Samara, Dalton Trans., 43, 3626 (2014); doi:10.1039/c3dt52860j.
  26. C.B. Murray, D.J. Norris and M.G. Bawendi, J. Am. Chem. Soc., 115, 8706 (1993); doi:10.1021/ja00072a025.
  27. W. Wang, I. Germanenko and M.S. El-Shall, Chem. Mater., 14, 3028 (2002); doi:10.1021/cm020040x.
  28. N. Chestnoy, T.D. Harris, R. Hull and L.E. Brus, J. Phys. Chem., 90, 3393 (1986); doi:10.1021/j100406a018.
  29. J. Xie, C. Xu, N. Kohler, Y. Hou and S. Sun, Adv. Mater., 19, 3163 (2007); doi:10.1002/adma.200701975.
  30. W. Erley and J.C. Hemminger, Surf. Sci., 316, L1025 (1994); doi:10.1016/0039-6028(94)91116-9.
  31. H.M. Ismail, J. Anal. Appl. Pyrolysis, 21, 315 (1991); doi:10.1016/0165-2370(91)80006-T.
  32. M.A.S. Sadjadi, B. Sadeghi, M. Meskinfam, K. Zare and J. Azizian, Physica E, 40, 3183 (2008); doi:10.1016/j.physe.2008.05.010.
  33. S.K. Panda, A. Datta and S. Chaudhuri, Chem. Phys. Lett., 440, 235 (2007); doi:10.1016/j.cplett.2007.03.063.
  34. T. Allen, Particle Size Measurement, Chapman & Hall, edn 5, Vol. 1 & 2 (1997).
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