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Vol. 28 No. 5 (2016): Vol 28 Issue 5

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Study of Glucose Adsorption on Synthetic Humin

https://doi.org/10.14233/ajchem.2016.19558
A. Wahyuningtyas
Department of Chemistry, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia
R. Roto
Department of Chemistry, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia
A. Kuncaka
Department of Chemistry, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia

Corresponding Author(s) : A. Wahyuningtyas

aultyas@gmail.com

Asian Journal of Chemistry, Vol. 28 No. 5 (2016): Vol 28 Issue 5

Abstract

Synthetic humin, a new kind of adsorbents, has been synthesized and the adsorption of glucose on synthetic humin has been performed. The starting compound was obtained by leaching synthetic humus, which has been made by mixing biochar and hydrochar, by solution of 0.5 M NaOH. The effects of contact time, initial glucose concentration and pH on the adsorption process were studied through batch experiment. After adsorption, the residual glucose concentration was measured by UV-visible spectrometry using Nelson-Somogyi method. Results show that the synthetic humin can adsorp100 ppm glucose concentration completely at 48 h. Both the Langmuir and Freundlich models have analyzed the adsorption isotherm. However, the adsorption data were best fitted to the Freundlich isotherm with K value 0.00478 mg g-1. The adsorption of glucose by humin follows Ho’s pseudo-second order kinetic model. It was found that the adsorption capacity of humin was 4.8 mg g-1 with rate constant of 8.42 × 10-5 g mg-1 min-1.

Keywords

Synthetic humin Glucose adsorption
Wahyuningtyas, A., Roto, R., & Kuncaka, A. (2016). Study of Glucose Adsorption on Synthetic Humin. Asian Journal of Chemistry, 28(5), 987–992. https://doi.org/10.14233/ajchem.2016.19558
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References
  1. W.R. Howarth, Western Nutrient Management Conference, Vol. 6, pp. 244-249 (2005).
  2. E.A. Paul and F.E. Clark, Soil Microbiology and Biochemistry, edn 2, Academic Press, San Diego, Califorina (1996).
  3. E.H. Novotny, M.H.B. Hayes, B.E. Madari, T.J. Bonagamba, E.R. Azevedo, A.A. Souza, G. Song, C.M. Nogueira and A.S. Mangrich, J. Braz. Chem. Soc., 20, 1003 (2009); doi:10.1590/S0103-50532009000600002.
  4. M.H.B. Hayes, R.S. Swift, C.M. Byrne, G. Song and A.J. Simpson, International Humic Substances Society (IHSS) (2010).
  5. A. Piccolo, Adv. Agron., 75, 57 (2002); doi:10.1016/S0065-2113(02)75003-7.
  6. G. Song, E.H. Novotny, A.J. Simpson, C.E. Clapp and M.H.B. Hayes, Eur. J. Soil Sci., 59, 505 (2008); doi:10.1111/j.1365-2389.2007.01006.x.
  7. D. Smejkalová and A. Piccolo, Environ. Sci. Technol., 42, 699 (2008);doi:10.1021/es071828p.
  8. IHSS, Carbohydrates compositions of IHSS Samples (2010).
  9. J. Kong and S. Yu, Acta Biochim. Biophys. Sin., 39, 549 (2007); doi:10.1111/j.1745-7270.2007.00320.x.
  10. C.H. Chia, B. Gong, S.D. Joseph, C.E. Marjo, P. Munroe and A.M. Rich, Vib. Spectrosc., 62, 248 (2012); doi:10.1016/j.vibspec.2012.06.006.
  11. A. Naidja, P.M. Huang, D.W. Anderson and C. dan Van Kessel, Appl. Spectrosc., 56, 318 (2002).
  12. B.J. Saikia, G. Parthasarathy and N.C. Sarmah, Bull. Mater. Sci., 31, 775 (2008); doi:10.1007/s12034-008-0123-0.
  13. R. Bodirlau and C.A. Teaca, Rom. J. Physiol., 54, 93 (2009).
  14. D. Ciolacu, F. Ciolacu and V.I. Popa, Cellul. Chem. Technol., 45, 13 (2010).
  15. H. Yilmaz and H. Kacmaz, Appl. Clay Sci., 62-63, 80 (2012); doi:10.1016/j.clay.2012.03.007.
  16. S.V. Vassilev, D. Baxter, L.K. Andersen, C.G. Vassileva and T.J. Morgan, Fuel, 94, 1 (2012); doi:10.1016/j.fuel.2011.09.030.
  17. P. Yu, Y. Tsai, F.-S. Yen, W.-P. Yang and C.-L. Huang, J. Eur. Ceram. Soc., 35, 673 (2015); doi:10.1016/j.jeurceramsoc.2014.08.040.
  18. K. Güngör, A. Jürgensen and K.G. Karthikeyan, J. Environ. Qual., 36, 1856 (2007); doi:10.2134/jeq2006.0563.
  19. Y. Ma, Q. Wang, X. Sun and X. Wang, Biomass Conv. Bioref., 5, 339 (2014); doi:10.1007/s13399-014-0147-1.
  20. S. Ramola, T. Mishra, G. Rana and R.K. Srivastava, Environ. Monit. Assess., 186, 9023 (2014); doi:10.1007/s10661-014-4062-5.
  21. M. Song, M. Chen and Z. Zhang, Mater. Charact., 59, 514 (2008); doi:10.1016/j.matchar.2007.03.008.
  22. S.K. Sahoo, K. Agarwal, A.K. Singh, B.G. Polke and K.C. Raha, Int. J. Eng. Sci. Technol., 2, 118 (2010).
  23. M.R. Joya, J.B. Jaimez and J.B. Ortega, J. Phys.; Conference Series, 466, 012023 (2013); doi:10.1088/1742-6596/466/1/012023.
  24. N. Du, Y. Xu, H. Zhang, C. Zhai and D. Yang, Nano. Res. Lett., 5, 1295 (2010); doi:10.1007/s11671-010-9641-y.
  25. H.E. Ghandoor, H.M. Zidan, M.M. H.Khalil and M. Ismail, Int. J. Electrochem. Sci., 7, 5734 (2012).
  26. M. Goswami, L. Borah, D. Mahanta and P. Phukan, J. Porous Matter., 21, 1025 (2014); doi:10.1007/s10934-014-9852-1.
  27. IUPAC, Pure Appl. Chem., 57, 603 (1985); doi:10.1351/pac198557040603.
  28. O.D. Nartey and B. Zhao, Adv. Mater. Sci. Eng., Article ID 715398 (2014); doi:10.1155/2014/715398.
  29. M. Francisco, A.N. Mlinar, B. Yoo, A.T. Bell and J.M. Prausnitz, Chem. Eng. J., 172, 184 (2011); doi:10.1016/j.cej.2011.05.087.
  30. A.M.D. Jesus, L.P.C. Romão, B.R. Araújo, A.S. Costa and J.J. Marques, Desalination, 274, 13 (2011); doi:10.1016/j.desal.2011.01.063.
  31. M. Antonietti, Department of Colloid Chemistry, Max Planck Institute of Colloids and Interface, Postdam Personal Communication, pp. 12-22 (2006).
  32. S. Lagergren, Vetenskapsakad. Handl., 24, 1 (1898).
  33. Y.S. Ho and G. McKay, Process Biochem., 34, 451 (1999); doi:10.1016/S0032-9592(98)00112-5.
  34. P. Bai, J.I. Siepmann and M.W. Deem, AlChE J., 59, 3526 (2013); doi:1002/aic.14104.
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