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Electrochromic Properties of WO3 Thin Film with Various Heat-Treatment Temperature
Corresponding Author(s) : Chang-Yeoul Kim
Asian Journal of Chemistry,
Vol. 25 No. 10 (2013): Vol 25 Issue 10
Abstract
Tungsten oxide is a representative electrochromic material which has widely researched as an active electrochromic electrode. The electrochromic properties are related with ion intercalation and deintercaltion like lithium or proton ions. So, it is thought that amorphous or crystalline phase of tungsten oxide is very important for the capability and reversiblility of ion intercalation or deintercalaton. In this study, we analyzed the relationships between heat-treatment temperature and electrochromic properties of tungsten oxide film prepared by sol-gel coating method. It is concluded that amorphous phase shows superior intercalation or deintercalation capability to crystalline phase.
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- S.K. Deb, Appl. Opt., 3, 192 (1969).
- C.G. Granquvist, Handbook of Inorganic Electrochromic Materials, Elsevier, New York (1995).
- H.R. Zeller and H.U. Beyler, Appl. Phys., 13, 231 (1977).
- C.G. Granqvist, Electrochim. Acta, 44, 3005 (1999).
- W.B. Cross, I.P. Parkin and S.A. O'Neill, Chem. Mater., 15, 2786 (2003).
- E. Ozkan, S.H. Lee, C.E. Tracy, J.R. Pitts and S.K. Deb, Solar Energy Mater. Solar Cells, 79, 439 (2003).
- S.H. Lee, M.J. Seong, H.M. Cheong, E. Ozkan, E.C. Tracy, S.K. Deb, Solid State Ionics, 156, 447 (2003).
- N. Janke, A. Bieberle and R. Weismann, Thin Solid Films, 392, 134 (2001).
- S.H. Lee, R. Deshpande, P.A. Parilla, K.M. Jones, B.T. To and H. Mahan, Adv. Mater., 18, 763 (2006).
- J.H. Choy, Y.I. Kim, J.B. Yoon and S.H. Choy, J. Mater. Chem., 11, 1506 (2001).
- K. Yamanka, H. Akamoto, H. Kidou and T. Kudo, Jap. J. Appl. Phys., 25, 1420 (1986).
- A. Cremonesi, D. Bersani, P.P. Lottici, Y. Djaoued and P.V. Ashirit, Thin Solid Films, 516, 4128 (2008).
- C.Y. Kim, J.W. Choi, T.Y. Lim and D.K. Choi, Key Eng. Mater., 318, 807 (2006).
- C.-Y. Kim, S.-G. Choa, S. Park and T.-Y. Lim, J. Ceram. Process. Res., 9, 1 (2008).
- C.-Y. Kim, S.-H. Huh and D.-H. Riu, Mater. Chem. Phys., 116, 527 (2009).
- C.-Y. Kim, M. Lee, S.-H. Huh and E.-K. Kim, J. Sol-Gel Sci. Technol., 53, 176 (2010).
- C.-Y. Kim, S.-G. Cho and T.-Y. Lim, Solar Energy Mater. Solar Cells, 93, 2056 (2009).
- P.R. Patil and P.S. Patil, Thin Solid Films, 382, 13 (2001).
- R. Sivakumar, M. Jyachandran and C. Sanjeeviraja, Mater. Res. Bull., 39, 1479 (2004).
- A. Enesca, C. Enache, A. Duta and J. Schoonman, J. Eur. Ceram. Soc., 26, 571 (2006)
References
S.K. Deb, Appl. Opt., 3, 192 (1969).
C.G. Granquvist, Handbook of Inorganic Electrochromic Materials, Elsevier, New York (1995).
H.R. Zeller and H.U. Beyler, Appl. Phys., 13, 231 (1977).
C.G. Granqvist, Electrochim. Acta, 44, 3005 (1999).
W.B. Cross, I.P. Parkin and S.A. O'Neill, Chem. Mater., 15, 2786 (2003).
E. Ozkan, S.H. Lee, C.E. Tracy, J.R. Pitts and S.K. Deb, Solar Energy Mater. Solar Cells, 79, 439 (2003).
S.H. Lee, M.J. Seong, H.M. Cheong, E. Ozkan, E.C. Tracy, S.K. Deb, Solid State Ionics, 156, 447 (2003).
N. Janke, A. Bieberle and R. Weismann, Thin Solid Films, 392, 134 (2001).
S.H. Lee, R. Deshpande, P.A. Parilla, K.M. Jones, B.T. To and H. Mahan, Adv. Mater., 18, 763 (2006).
J.H. Choy, Y.I. Kim, J.B. Yoon and S.H. Choy, J. Mater. Chem., 11, 1506 (2001).
K. Yamanka, H. Akamoto, H. Kidou and T. Kudo, Jap. J. Appl. Phys., 25, 1420 (1986).
A. Cremonesi, D. Bersani, P.P. Lottici, Y. Djaoued and P.V. Ashirit, Thin Solid Films, 516, 4128 (2008).
C.Y. Kim, J.W. Choi, T.Y. Lim and D.K. Choi, Key Eng. Mater., 318, 807 (2006).
C.-Y. Kim, S.-G. Choa, S. Park and T.-Y. Lim, J. Ceram. Process. Res., 9, 1 (2008).
C.-Y. Kim, S.-H. Huh and D.-H. Riu, Mater. Chem. Phys., 116, 527 (2009).
C.-Y. Kim, M. Lee, S.-H. Huh and E.-K. Kim, J. Sol-Gel Sci. Technol., 53, 176 (2010).
C.-Y. Kim, S.-G. Cho and T.-Y. Lim, Solar Energy Mater. Solar Cells, 93, 2056 (2009).
P.R. Patil and P.S. Patil, Thin Solid Films, 382, 13 (2001).
R. Sivakumar, M. Jyachandran and C. Sanjeeviraja, Mater. Res. Bull., 39, 1479 (2004).
A. Enesca, C. Enache, A. Duta and J. Schoonman, J. Eur. Ceram. Soc., 26, 571 (2006)