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Vol. 25 No. 9 (2013): Vol 25 Issue 9

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Synthesis and Crystal Structure of 5,5'-Dimethoxy-2,2'-[(hexane-1,6-diyldioxy)bis(nitrilomethylidyne)]diphenol

https://doi.org/10.14233/ajchem.2013.14312
Xin-Wen Liu
School of Biological Science and Chemistry, Tianshui Normal University, Tianshui 741001, P.R. China
Yang Zhang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Yu-Jie Zhang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Gang Li
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Li Wang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Xiu-Yan Dong
School of Biological Science and Chemistry, Tianshui Normal University, Tianshui 741001, P.R. China

Corresponding Author(s) : Xin-Wen Liu

liuxwts@126.com

Asian Journal of Chemistry, Vol. 25 No. 9 (2013): Vol 25 Issue 9

Abstract

The chelating bis-oxime compound i.e., 5,5'-dimethoxy-2,2'-[(hexane-1,6-diyldioxy)bis(nitrilomethylidyne)]diphenol with the molecular formula C22H28N2O6, assumes an E configuration with respect to the azomethine C=N bond and the two phenyl rings are parallel to each other. There are two fairly strong intramolecular O2-H2···N1 and O5-H5···N2 hydrogen bonds. Each compound molecule links four other neighboring molecules through three pairs of intermolecular C11-H11C···O5 and C18-H18···O6 hydrogen-bonding interactions into an infinite wave-like 2D-layer supramolecular structure.

Keywords

Salen-type bisoxime Synthesis Crystal structure
Liu, X.-W., Zhang, Y., Zhang, Y.-J., Li, G., Wang, L., & Dong, X.-Y. (2013). Synthesis and Crystal Structure of 5,5’-Dimethoxy-2,2’-[(hexane-1,6-diyldioxy)bis(nitrilomethylidyne)]diphenol. Asian Journal of Chemistry, 25(9), 5022–5024. https://doi.org/10.14233/ajchem.2013.14312
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