Synthesis and Characterization of a New Cyclophosphazene and Its Ruthenium Complex Derived from 1,10-Phenanthroline-5,6-diol

Gulnur Keser Karaoglan; Ibrahim Erden; Nebahat Demirhan

doi:10.14233/ajchem.2013.14142

Issue

Vol. 25 No. 9 (2013): Vol 25 Issue 9

Issue Published : March 25, 2013

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of a New Cyclophosphazene and Its Ruthenium Complex Derived from 1,10-Phenanthroline-5,6-diol

https://doi.org/10.14233/ajchem.2013.14142

Gulnur Keser Karaoglan

Department of Chemistry, Faculty of Arts and Sciences, Yildiz Technical University, 34210 Esenler, Istanbul, Turkey

Ibrahim Erden

Department of Chemistry, Faculty of Arts and Sciences, Yildiz Technical University, 34210 Esenler, Istanbul, Turkey

Nebahat Demirhan

Department of Chemistry, Faculty of Arts and Sciences, Yildiz Technical University, 34210 Esenler, Istanbul, Turkey

Corresponding Author(s) : Gulnur Keser Karaoglan

gulnurkeser@hotmail.com

Asian Journal of Chemistry, Vol. 25 No. 9 (2013): Vol 25 Issue 9
Article Published : April 9, 2013

Abstract

A new spirocyclic phosphazene derivative has been synthesized from the reaction of 1,10-phenanthroline-5,6-diol with hexachlorocyclotriphosphazatriene in suitable conditions and the Ru(II) complex of the ligand was prepared and characterized. Synthesized compounds have been investigated with the methods of FTIR, ¹H NMR, ³¹P NMR, UV-VIS, MS, fluorescence and elemental analysis.

Keywords

Spirocyclic phosphazene Ruthenium complex 1,10-Phenanthroline

Keser Karaoglan, G., Erden, I., & Demirhan, N. (2013). Synthesis and Characterization of a New Cyclophosphazene and Its Ruthenium Complex Derived from 1,10-Phenanthroline-5,6-diol. Asian Journal of Chemistry, 25(9), 4925–4928. https://doi.org/10.14233/ajchem.2013.14142

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References

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References

A. Uslu, S.J. Coles, D.B. Davies, R.J. Eaton, M.B. Hursthouse, A. Kilic and R.A. Shaw, Eur. J. Inorg. Chem., 1042 (2005).

S. Besli, S.J. Coles, D.B. Davies, R.J. Eaton, M.B. Hursthouse, A. Kilic, R.A. Shaw, G.Y. Ciftci and S. Yesilot, J. Am. Chem. Soc., 125, 4943 (2002).

S.J. Coles, D.B. Davies, R.J. Eaton, M.B. Hursthouse, A. Kilic, T.A. Mayer, R.A. Shaw and G. Yenilmez, J. Chem. Soc. Dalton Trans., 365 (2002).

H. Beak, Y. Cho, C. Lee and Y.S. Shon, Anti Cancer Drugs, 11, 715 (2000).

V. Konar, O. Yilmaz,A. Ozturk, S. Kirbag and M. Arslan, Bioorg. Chem., 28, 214 (2000).

K. Brandt, R. Kruszynski, T.J. Bartczak and I. Parwolik-Czomperlik, Inorg. Chim. Acta, 322, 138 (2001).

J.E. Mark, H.R. Allcock and R. West, Inorganic Polymers, Printence-Hall, Englewood Cliffs, NJ (1992).

P.M. Blonsky, D.F. Shriver, P. Austin and H.R. Allcock, Solid State Ion, 18, 258 (1986).

D.F. Shriver and G.C. Ferrington, Chem. Eng. News, 63, 42 (1985).

H.R. Allcock, R. Eric, L. Didier, A. Mireille and C. Jean-Pierre, Macromolecules, 29, 1951 (1996).

H.R. Allcock and S. Kwon, Macromolecules, 19, 1502 (1986).

V. Chandrasekhar, K. Vivekanandan, S. Nagendran, G.T.S. Andavan, N.R. Weathers, J.C. Yarbrough and A.W. Cordes, Inorg. Chem., 37, 6192 (1998).

R.A. Pelc, K. Brandt and Z. Jedlinski, Phosphorus Sulfur Silicion Rel. Elem., 47, 375 (1990).

W.F. Deutsch and R.A. Shaw, J. Chem. Soc. Dalton Trans., 1757 (1988).

D. Kumar and A.D. Gupta, Macromolecules, 28, 6323 (1995).

H.R. Allcock, Chem. Rev., 72, 315 (1972).

J.E. Dickeson and L.A. Summers, Aust. J. Chem., 23, 1023 (1970).

J.-Z. Wu, H. Li, J.-G. Zhang and J.-H. Xu, Inorg. Chem. Commun., 5, 71 (2002).

R. Ziessel, Coord. Chem. Rev., 216-217, 195 (2001).

D.S. Tyson, C.R. Luman, X. Zhou and F.N. Castellano, Inorg. Chem., 40, 4063 (2001)

Issue

Vol. 25 No. 9 (2013): Vol 25 Issue 9

Synthesis and Characterization of a New Cyclophosphazene and Its Ruthenium Complex Derived from 1,10-Phenanthroline-5,6-diol

Corresponding Author(s) : Gulnur Keser Karaoglan

Abstract

Keywords

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