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Effect of Naphthyridine-Like Structure in Polyacrylonitrile Stabilized Fibers on the Modulus of Carbon Fibers
Corresponding Author(s) : Aijun Gao
Asian Journal of Chemistry,
Vol. 25 No. 9 (2013): Vol 25 Issue 9
Abstract
Correlation between naphthyridine-like structures of polyacrylonitrile stabilized fibers and modulus of carbon fibers was investigated. It was found that naphthyridine-like structures, which is a kind of characteristics structure in the polyacrylonitrile stabilized fibers, influence the modulus of carbon fibers. The naphthyriding-like structures can convert to graphite layers, which induce the degree of graphitization and crystallite size to improve, so the more the naphthyriding-like structures form in the polyacrylonitrile stabilized fibers, the higher the modulus of carbon fibers is.
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References
M.K. Jain and A.S. Abhiraman, J. Mater. Sci., 22, 278 (1987).
S.C. Martin, J.J. Liggat and C.E. Snape, Polym. Degrad. Stab., 74, 407 (2001).
E. Fitzer and D.J. Müller, Carbon, 13, 63 (1975).
W. Watt and W. Johnson, Nature, 257, 210 (1975).
M.M. Coleman, G.T. Sivy, P.C. Painter, R.W. Snyder and B. Gordon, Carbon, 21, 255 (1983).
I. Shimada, T. Takahagi, K. Morita and A. Ishitani, J. Polym. Sci., Polym. Chem., 24, 1989 (1986).
T.J. Xue, M.A. Mckinney and C.A. Wilkie, Polym. Degrad. Stab., 58, 193 (1997).
H. Kakida and K. Tashiro, Polym. J., 30, 463 (1998).
P. Bajaj, T.V. Sreekumar and K. Sen, Polymer, 42, 1707 (2001).
D.B. Jin, Y. Huang, X.L. Liu and Y.Z. Yu, J. Mater. Sci., 39, 3365 (2004).
M.S.A. Rahaman, A.F. Ismail and A. Mustafa, Polym. Degrad. Stab., 92, 1421 (2007).
D.X. He, C.G. Wang, Y.J. Bai, N. Lun, B. Zhu and Y.X. Wang, J. Mater. Sci., 42, 7402 (2007).
Q. OuYang, C. Lu, H.J. Wang and K.X. Li, Polym. Degrad. Stab., 93, 1415 (2008).
Q. Ouyang, L. Cheng, H.J. Wang and K.X. Li, J. Therm. Anal. Calorim., 94, 85 (2008).
Y.P. Hou, T.Q. Sun, H.J. Wang and D. Wu, J. Appl. Polym. Sci., 114, 3668 (2009).
C.S. Cui, L.N. Yu and C.G. Wang, J. Appl. Polym. Sci., 117, 1596 (2010).
S.J. Xiao, H.H. Lv, Y.J. Tong, L.H. Xu and B.H. Chen, J. Appl. Polym. Sci., 122, 480 (2011).
H.S. Fochler, J.R. Mooney, L.E. Ball, R.D. Boyer and J.G. Grasselli, Spectrochim. Acta A, 41, 271 (1985).
T. Usami, T. Itoh, H. Ohtani and S. Tsuge, Macromolecules, 23, 2460 (1990).
S.C. Martin, J.J. Liggat and C.E. Snape, Polym. Degrad. Stab., 74, 407 (2001).