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Vol. 25 No. 9 (2013): Vol 25 Issue 9

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A Novel Inorganic-Organic Hybrid Material Based on Monosubstituted Keggin-Type Polyoxometalates by a Metal-Nitrogen of Covalent Bonding

https://doi.org/10.14233/ajchem.2013.14137
Yingxue Xue
College of Chemistry, Jilin University, Changchun 130023, P.R. China
Xiaohong Guo
Changchun No. 2 High School, Changchun 130061, P.R. China
Chao Li
College of Chemistry, Jilin University, Changchun 130023, P.R. China
Jing Li
College of Chemistry, Jilin University, Changchun 130023, P.R. China
Xiaozhen Ren
College of Chemistry, Jilin University, Changchun 130023, P.R. China
Guangdong Zhou
College of Chemistry, Jilin University, Changchun 130023, P.R. China

Corresponding Author(s) : Guangdong Zhou

zhougd@jlu.edu.cn; xxyyxx0129@126.com

Asian Journal of Chemistry, Vol. 25 No. 9 (2013): Vol 25 Issue 9

Abstract

A new inorganic-organic hybrid material Na(ANIH)4ANI[PW11Ni(ANI)O39]·12H2O (ANI = aniline) was prepared based on transition-metal monosubstituted keggin type polyoxometalates [PW11Ni(H2O)O39]5- as inorganic species and aniline as organic ligand by a covalent bonding of Ni-N. The as-prepared hybrid material was characterized by elemental analysis, IR spectroscopy, TG-DTA analyses, UV-visible spectra and X-ray photoelectron spectroscopy (XPS). Elemental analysis and TG-DTA results confirm the formula of the hybrid material. Experimental results of UV-VIS, IR and XPS approve that the Ni-N covalent bond is formed between the transition-metal in the Keggin-type anion [PW11Ni(H2O)O39]5- and the nitrogen atom of ANI and the ANIH+ exists as counter ion. Moreover, photocatalytic activity of the as-prepared hybrid material was investigated by photodegradation of dye rhodamine B under UV irradiation and the results showed that the hybrid material exhibited high photocatalytic activity for treatment of dye-containing wastewater.

Keywords

Hybrid material Keggin type Polyoxometalates Photocatalytic activity
Xue, Y., Guo, X., Li, C., Li, J., Ren, X., & Zhou, G. (2013). A Novel Inorganic-Organic Hybrid Material Based on Monosubstituted Keggin-Type Polyoxometalates by a Metal-Nitrogen of Covalent Bonding. Asian Journal of Chemistry, 25(9), 4893–4896. https://doi.org/10.14233/ajchem.2013.14137
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