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Vol. 25 No. 9 (2013): Vol 25 Issue 9

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Effective Parameters onto Graft Copolymer Based on Carboxymethyl with Acrylic Monomer

https://doi.org/10.14233/ajchem.2013.14311B
Mohammad Sadeghi
Department of Chemistry, Science Faculty, Arak Branch, Islamic Azad University, Arak, Iran
Soudeh Safari
Department of Chemistry, Science Faculty, Arak Branch, Islamic Azad University, Arak, Iran
Hadis Shahsavari
Department of Chemistry, Science Faculty, Arak Branch, Islamic Azad University, Arak, Iran
Hossein Sadeghi
Department of Chemistry, Science Faculty, Arak Branch, Islamic Azad University, Arak, Iran
Fatemeh Soleimani
Department of Chemistry, Science Faculty, Arak Branch, Islamic Azad University, Arak, Iran

Corresponding Author(s) : Mohammad Sadeghi

m-sadeghi@iau-arak.ac.ir

Asian Journal of Chemistry, Vol. 25 No. 9 (2013): Vol 25 Issue 9

Abstract

The effective parameters onto graft copolymer sodium carboxymethyl celloluse with acrylic monomers were performed. The graft copolymerization reaction was carried out in a homogeneous medium and by reaction of N-isopropylacrylamide (NIPAAm) and methacrylamide (MAAm) with carboxymethyl cellulose backbones. A mechanism for the graft copolymer formation was also suggested. Finally, the effect of ammonium persulfate, carboxymethyl cellulose concentration and MAAm/NIPAAm weight ratio and reaction temperature on the per cent grafting has been investigated.

Keywords

CMC Grafting Methacrylamide N-Isopropylacrylamide
Sadeghi, M., Safari, S., Shahsavari, H., Sadeghi, H., & Soleimani, F. (2013). Effective Parameters onto Graft Copolymer Based on Carboxymethyl with Acrylic Monomer. Asian Journal of Chemistry, 25(9), 5029–5032. https://doi.org/10.14233/ajchem.2013.14311B
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References
  1. F.L. Buchholz and A.T. Graham, Modern Superabsorbent polymer Technology, Wiley, New York (1997).
  2. V.D. Athawale and V. Lele, Carbohydr. Polym., 35, 21 (1998).
  3. D. Castal,A. Ricard and R. Audebert, J. Appl. Polym. Sci., 39, 11 (1990).
  4. P.J. Flory, Principles of Polymer Chemistry, Cornell University Press, Ithaca, New York (1953).
  5. L.H. Gan, G.R. Deen, Y.Y. Gan and K.C. Tam, Eur. Polym. J., 37, 1473 (2001).
  6. S. Hua and A. Wang, Carbohydr. Polym., 75, 79 (2009).
  7. J. Kost, Encyclopedia of Controlled Drug Delivery, Intelligent Drug Delivery Systems, Wiley, New York, Vol. 1 (1999).
  8. W.F. Lee and W.Y. Yuan, J. Appl. Polym. Sci., 77, 1760 (2000).
  9. G.R. Mahdavinia, A. Pourjavadi, H. Hosseinzadeh and M.J. Zohuriaan, Eur. Polym. J., 40, 1399 (2004).
  10. N.A. Peppas and A.G. Mikes, Hydrogels in Medicine and Pharmacy, CRC Press, Boca Raton, Florida (1986).
  11. L.B. Peppas and R.S. Harland, Absorbent Polymer Technology, Elsevier, Amsterdam 1990 (1994).
  12. G.F. Fanta, In ed.: J.C. Salamone, in Polymeric Materials Encyclopedia, CRC Press: Boca Raton, FL, pp. 7901, 8051, Vol. 10 (1996).
  13. R. Po, J. Macromol. Sci-Rev. Macromol. Chem. Phys., C34, 607.
  14. M.J. Zohuriaan-Mehr and A. Pourjavadi, J. Polym. Mater., 20, 113 (2003).
  15. A. Pourjavadi, A.M. Harzandi and H. Hosseinzadeh, Eur. Polym. J., 40, 1363 (2004).
  16. A. Pourjavadi and M. Kurdtabar, Eur. Polym. J., 43, 877 (2007).
  17. G.V.N. Rathna and S. Damodaran, J. Appl. Polym. Sci., 85, 45 (2002).
  18. A. Richter, A. Bund, M. Keller and K. Arndt, Sens. Actuators B, 99, 579 (2004).
  19. H. Yan, A. Saiani, J.E. Gough and A.F. Miller, Biomacromolecules, 7, 2776 (2006).
  20. J. Chen and Y. Zhao, J. Appl. Polym. Sci., 75, 808 (2000).
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