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Linear and Third Order Non-Linear Optical Properties of Urea Salicylic Acid Crystal
Corresponding Author(s) : P. Murugakoothan
Asian Journal of Chemistry,
Vol. 28 No. 4 (2016): Vol 28 Issue 4
Abstract
An organic non-linear optical crystal urea salicylic acid was grown by slow evaporation method using the mixed solvent of ethanol and water in equal ratio. The lattice parameters of urea salicylic acid crystal were obtained by single X-ray diffraction study. The optical transmittance study revealed the good transmission window of the urea-salicylic acid and its suitability for optical applications. The non-linear refractive index, n2, absorption coefficient, b and third order susceptibility, c(3) have been measured through the Z-scan technique with He-Ne laser at 632.8 nm. The grown urea salicylic acid crystal exhibits two photon absorption and self-defocussing performance.
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- D.S. Chemla and J. Zyss, Nonlinear Optical Properties of Organic Molecules and Crystals, Academic Press, New York, pp. 23-27 (1987).
- H.S. Nalwa and S. Miyata, Nonlinear Optics of Organic Molecules and Polymers, CRC Press, Boca Raton, p. 129 (1997).
- P.N. Prasad and D. Williams, Introduction to Nonlinear Effects in Molecules and Polymers, Wiley, New York (1991).
- J.T.J. Prakash, J.F. Vimala and M. Lawrence, J. Comp. Appl., 8, 18 (2010); doi:10.5120/1214-1743.
- A. Selvam, S. Pandi, S. Selvakumar and S. Srinivasan, J. Appl. Sci. Res., 4, 2474 (2012).
- V. Natarajan, T. Sivanesan and S. Pandi, Ind. J. Sci. Technol., 3, 897 (2010).
- M. Sheik-Bahae, A.A. Said, T.H. Wei, D.J. Hagan and E.W. Van Stryland, IEEE J. Quantum Electron., 26, 760 (1990); doi:10.1109/3.53394.
- M. Sheik-Bahae, A.A. Said and E.W. Van Stryland, Opt. Lett., 14, 17 (1990); doi:10.1364/OL.14.000955.
- R.K. Choubey, S. Medhekar, R. Kumar, S. Mukherjee and S. Kumar, J. Mat. Sci. Elect. Mat., 25, 1410 (2014); doi:10.1007/s10854-014-1743-3.
- I.N. Hsu and R.W. Gellert, J. Cryst. Spect. Res., 13, 43 (1983); doi:10.1007/BF01666795.
- V. Krishnakumar and R. Nagalakshmi, Spectrochim. Acta A, 61, 499 (2005); doi:10.1016/j.saa.2004.04.014.
- V. Krishnakumar and R. Nagalakshmi, Spectrochim. Acta A, 60, 2733 (2004); doi:10.1016/j.saa.2004.01.012.
- K. Rajesh and P. Praveen Kumar, Int. J. Sci. Res., 3, 799 (2014).
- V. Siva Shankar, R. Siddheswaran, T. Bharthasarathi and P. Murugakoothan, J. Cryst. Growth, 311, 2709 (2009); doi:10.1016/j.jcrysgro.2009.03.001.
- Y.S. Zhou, E.B. Wang, J. Peng, J. Liu, C. Hu, R. Huang and X. You, J. Polyhedron, 18, 1419 (1999); doi:10.1016/S0277-5387(98)00448-3.
- S. Girisun and S. Dhanuskodi, J. Cryst. Res. Technol., 44, 1297 (2009); doi:10.1002/crat.200900351.
References
D.S. Chemla and J. Zyss, Nonlinear Optical Properties of Organic Molecules and Crystals, Academic Press, New York, pp. 23-27 (1987).
H.S. Nalwa and S. Miyata, Nonlinear Optics of Organic Molecules and Polymers, CRC Press, Boca Raton, p. 129 (1997).
P.N. Prasad and D. Williams, Introduction to Nonlinear Effects in Molecules and Polymers, Wiley, New York (1991).
J.T.J. Prakash, J.F. Vimala and M. Lawrence, J. Comp. Appl., 8, 18 (2010); doi:10.5120/1214-1743.
A. Selvam, S. Pandi, S. Selvakumar and S. Srinivasan, J. Appl. Sci. Res., 4, 2474 (2012).
V. Natarajan, T. Sivanesan and S. Pandi, Ind. J. Sci. Technol., 3, 897 (2010).
M. Sheik-Bahae, A.A. Said, T.H. Wei, D.J. Hagan and E.W. Van Stryland, IEEE J. Quantum Electron., 26, 760 (1990); doi:10.1109/3.53394.
M. Sheik-Bahae, A.A. Said and E.W. Van Stryland, Opt. Lett., 14, 17 (1990); doi:10.1364/OL.14.000955.
R.K. Choubey, S. Medhekar, R. Kumar, S. Mukherjee and S. Kumar, J. Mat. Sci. Elect. Mat., 25, 1410 (2014); doi:10.1007/s10854-014-1743-3.
I.N. Hsu and R.W. Gellert, J. Cryst. Spect. Res., 13, 43 (1983); doi:10.1007/BF01666795.
V. Krishnakumar and R. Nagalakshmi, Spectrochim. Acta A, 61, 499 (2005); doi:10.1016/j.saa.2004.04.014.
V. Krishnakumar and R. Nagalakshmi, Spectrochim. Acta A, 60, 2733 (2004); doi:10.1016/j.saa.2004.01.012.
K. Rajesh and P. Praveen Kumar, Int. J. Sci. Res., 3, 799 (2014).
V. Siva Shankar, R. Siddheswaran, T. Bharthasarathi and P. Murugakoothan, J. Cryst. Growth, 311, 2709 (2009); doi:10.1016/j.jcrysgro.2009.03.001.
Y.S. Zhou, E.B. Wang, J. Peng, J. Liu, C. Hu, R. Huang and X. You, J. Polyhedron, 18, 1419 (1999); doi:10.1016/S0277-5387(98)00448-3.
S. Girisun and S. Dhanuskodi, J. Cryst. Res. Technol., 44, 1297 (2009); doi:10.1002/crat.200900351.