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Vol. 25 No. 8 (2013): Vol 25 Issue 8

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Synthesis of Carboxymethyl Calix[4]arene Intercalated Layered Double Hydroxides

https://doi.org/10.14233/ajchem.2013.14014
Xiao Lei Liu
Chemical Engineering Department, Zibo Vocational Institute, Zibo 255314, P.R. China

Corresponding Author(s) : Xiao Lei Liu

lxl5233@163.com

Asian Journal of Chemistry, Vol. 25 No. 8 (2013): Vol 25 Issue 8

Abstract

The intercalation of water-soluble carboxymethyl calix[4]arene (CMCS) in the interlayer of the Zn-Al layered double hydroxides powder and film by the anion exchange and in situ crystallization methods have been investigated. The XRD results confirm the intercalation of carboxymethyl calix[4]arene in the interlayer galleries of layered double hydroxides. In both powder and film samples, carboxymethyl calix[4]arene molecules adopt a monolayer arrangement, with the axis of the cavity perpendicular to the layered double hydroxides sheets. The SEM images indicate that the ab-face of layered double hydroxides microcrystals is predominantly perpendicular with respect to the porous anodic alumina substrate. Compared with the CMCS-LDHs powder sample, the structured CMCS-LDHs film exhibits the advantages of more convenient operation. This carboxymethyl calix[4]arene functionalized inorganic layered film may have potential application in the field of industrial adsorption, separation and inclusion.

Keywords

Layered double hydroxides Calix[4]arene In situ crystallization Film
Lei Liu, X. (2013). Synthesis of Carboxymethyl Calix[4]arene Intercalated Layered Double Hydroxides. Asian Journal of Chemistry, 25(8), 4449–4452. https://doi.org/10.14233/ajchem.2013.14014
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