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Vol. 28 No. 4 (2016): Vol 28 Issue 4

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Hydrothermal Synthesis of Birnessite-Type Potassium Manganese Oxide and its Application as Lubricant in Liquid Paraffin

https://doi.org/10.14233/ajchem.2016.19544
Lijun Cheng
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi Province, P.R. China
Yihua Wang
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi Province, P.R. China
Hong Xu
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi Province, P.R. China
Lei Liu
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi Province, P.R. China
Jinxiang Dong
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi Province, P.R. China

Corresponding Author(s) : Jinxiang Dong

dongjinxiangwork@hotmail.com

Asian Journal of Chemistry, Vol. 28 No. 4 (2016): Vol 28 Issue 4

Abstract

Potassium manganese oxide materials with high purity was directly synthesized in KOH-H2O2-Mn(OAc)2-H2O system under hydrothermal conditions. The optimum synthetic condition for K-birnessite (KOH/H2O2/Mn(OAc)2 = 12:10:1, 150 °C, 48 h) was confirmed by investigating the synthesis processes. K-birnessite samples have been characterized by XRD, SEM, TG and FT-IR. Moreover, the lubrication of K-birnessite, as an additive, was evaluated in a four ball test. Adding K-birnessite in liquid paraffin, the PB value can be improved from 431 N to 510 N with 1.0 wt % K-birnessite in liquid paraffin.

Keywords

Birnessite Hydrothermal Synthesis Manganese oxide Lubrication
Cheng, L., Wang, Y., Xu, H., Liu, L., & Dong, J. (2015). Hydrothermal Synthesis of Birnessite-Type Potassium Manganese Oxide and its Application as Lubricant in Liquid Paraffin. Asian Journal of Chemistry, 28(4), 883–887. https://doi.org/10.14233/ajchem.2016.19544
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