Synthesis and Supramolecular Structure of 6,6'-Diethoxy-2,2'-[1,1'-(hexane-1,6-diyldioxy)bis(nitrilomethylidyne)]diphenol

Wen-Kui Dong; Cheng-Juan Yang; Sen-Hua Liu; Li Wang; Xiu-Yan Dong

doi:10.14233/ajchem.2013.13979

Issue

Vol. 25 No. 8 (2013): Vol 25 Issue 8

Issue Published : March 7, 2013

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Supramolecular Structure of 6,6'-Diethoxy-2,2'-[1,1'-(hexane-1,6-diyldioxy)bis(nitrilomethylidyne)]diphenol

https://doi.org/10.14233/ajchem.2013.13979

Wen-Kui Dong

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Cheng-Juan Yang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Sen-Hua Liu

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Li Wang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Xiu-Yan Dong

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Corresponding Author(s) : Wen-Kui Dong

dongwk@126.com; 13919173885@126.com

Asian Journal of Chemistry, Vol. 25 No. 8 (2013): Vol 25 Issue 8
Article Published : March 18, 2013

Abstract

The compound, 6,6'-diethoxy-2,2'-[1,1'-(hexane-1,6-diyldioxy)bis(nitrilomethylidyne)]diphenol, was synthesized by the reaction of 3-ethoxysalicylaldehyde with 1,6-bis(aminooxy)hexane in ethanol. The molecule lies across a crystallographic inversion centre (symmetry code: -x, -y, -z) and adopts an E configuration with respect to the azomethine C=N bond. Within the molecule, the two benzene rings are parallel to each other and with the distance of 3.976(4) Å. Intramolecular O-H···N hydrogen bonds are formed between the hydroxyl groups and the oxime nitrogen atoms. The distances between the hydroxyl groups and the oxime nitrogen atoms d(O2···N1) = 2.626(3) Å. Intermolecular C-H···O hydrogen bonds link the title molecules into an infinite 3D supramolecular network structure.

Keywords

Bisoxime compound Synthesis Supramolecular structure

Dong, W.-K., Yang, C.-J., Liu, S.-H., Wang, L., & Dong, X.-Y. (2013). Synthesis and Supramolecular Structure of 6,6’-Diethoxy-2,2’-[1,1’-(hexane-1,6-diyldioxy)bis(nitrilomethylidyne)]diphenol. Asian Journal of Chemistry, 25(8), 4372–4374. https://doi.org/10.14233/ajchem.2013.13979

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References

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W.K. Dong, J.G. Duan, H.L. Wu, J.Y. Shi and T.Z. Yu, Z. Kristallogr. NCS, 221, 555 (2006).
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W.K. Dong, G. Wang, S.S. Gong, J.F. Tong, Y.X. Sun and X.H. Gao, Transition Met. Chem., 37, 271 (2012).
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References

W.K. Dong, X.N. He, C.M. Dong, L.Wang, J.K. Zhong, X. Chen and T.Z. Yu, Z. Kristallogr. NCS, 222, 289 (2007).

W.K. Dong, J.G. Duan, H.L. Wu, J.Y. Shi and T.Z. Yu, Z. Kristallogr. NCS, 221, 555 (2006).

S. Akine, W.K. Dong and T. Nabeshima, Inorg. Chem., 45, 4677 (2006).

W.K. Dong, Y.X. Sun, Y.P. Zhang, L. Li, X.N. He and X.L. Tang, Inorg. Chim. Acta, 362, 117 (2009).

W.K. Dong, Y.X. Sun, C.Y. Zhao, X.Y. Dong and L. Xu, Polyhedron, 29, 2087 (2010).

W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009).

S. Akine, T. Taniguchi, W.K. Dong, S. Masubuchi and T. Nabeshima, J. Org. Chem., 70, 1704 (2005).

W.K. Dong, J.Y. Shi, J.K. Zhong, Y.Q. Tian and J.G. Duan, Chin. J. Inorg. Chem., 24, 10 (2008).

H.L. Wu, K. Li, T. Sun, F. Kou, F. Jia, J.K. Yuan, B. Liu and B.L. Qi, Transition Met. Chem., 36, 21 (2011).

H.L. Wu, X.C. Huang, J.K. Yuan, F. Kou, F. Jia, B. Liu and Y. Bai, Z.Naturforsch., 66b, 1049 (2011).

W.K. Dong, G. Wang, S.S. Gong, J.F. Tong, Y.X. Sun and X.H. Gao, Transition Met. Chem., 37, 271 (2012).

H.L. Wu, X.C. Huang, J.K. Yuan, F. Kou, F. Jia, B. Liu and K.T. Wang,Eur. J. Med. Chem., 45, 5324 (2010).

H.L. Wu, K.T. Wang, F. Kou, F. Jia, B. Liu, J.K. Yuan and Y. Bai, J. Coord. Chem., 64, 2676 (2010).

H.L. Wu, J.K. Yuan, Y. Bai, F. Jia, B. Liu, F. Kou and J. Kong, Transition Met. Chem., 36, 819 (2011).

W.K. Dong, J.G. Duan, Y.H. Guan, J.Y. Shi and C.Y. Zhao, Inorg. Chim. Acta, 362, 1129 (2009).

H.L. Wu, F. Jia, F. Kou, B. Liu, J.K. Yuan and Y. Bai, Transition Met. Chem., 36, 847 (2011).

Issue

Vol. 25 No. 8 (2013): Vol 25 Issue 8

Synthesis and Supramolecular Structure of 6,6'-Diethoxy-2,2'-[1,1'-(hexane-1,6-diyldioxy)bis(nitrilomethylidyne)]diphenol

Corresponding Author(s) : Wen-Kui Dong

Abstract

Keywords

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