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Vol. 25 No. 8 (2013): Vol 25 Issue 8

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Electrochemical and Fluorescent Investigation of Inorganic-organic Hybrid from Butylrhodamine B and Keggin-Type Polyoxometalates

https://doi.org/10.14233/ajchem.2013.14039
Xiaoying Zeng
Research and Development Center, Hongyun Honghe Tobacco (Group) Co. Ltd., Kunming 650202, P.R. China
Juxing Jiang
Research and Development Center, Hongyun Honghe Tobacco (Group) Co. Ltd., Kunming 650202, P.R. China
Haiyun Zhang
Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Shandong Provincial Key Laboratory of Coastal Zone Environmental Processes, YICCAS, Yantai Shandong 264003, P.R. China
Wenjing Lu
Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Shandong Provincial Key Laboratory of Coastal Zone Environmental Processes, YICCAS, Yantai Shandong 264003, P.R. China
Dawei Pan
Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Shandong Provincial Key Laboratory of Coastal Zone Environmental Processes, YICCAS, Yantai Shandong 264003, P.R. China

Corresponding Author(s) : Dawei Pan

dwpan@yic.ac.cn

Asian Journal of Chemistry, Vol. 25 No. 8 (2013): Vol 25 Issue 8

Abstract

A new inorganic-organic hybrid composed of butylrhodamine B (BRB) and Keggin-type polyoxometalates (PMo12) was introduced. The UV-visible and FTIR results indicate the formation of hybrid is caused by the interaction of butylrhodamine B and polyoxometallate. The BRB-PMo12 hybrid modified electrode shows the good electrochemical properites and catalysis to the reduction of bromate. Additionally, at the same condition, the fluorescence intensity of BRB-PMo12 hybrid is almost 1.3 times than that of butylrhodamine B. The corresponding results have important implications for the design of multi-functional hybrid materials, which could be used widely in chemo/biosensing and catalysis.

Keywords

Butylrhodamine B Polyoxometalates Hybrid material Electrochemistry Fluorescence
Zeng, X., Jiang, J., Zhang, H., Lu, W., & Pan, D. (2013). Electrochemical and Fluorescent Investigation of Inorganic-organic Hybrid from Butylrhodamine B and Keggin-Type Polyoxometalates. Asian Journal of Chemistry, 25(8), 4517–4519. https://doi.org/10.14233/ajchem.2013.14039
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