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Synthesis and Structural Characterization of N-(4-Pyridyl)benzamide
Corresponding Author(s) : Xiu-Yan Dong
Asian Journal of Chemistry,
Vol. 25 No. 7 (2013): Vol 25 Issue 7
Abstract
Determination of the structure of N-(4-pyridyl)benzamide with the molecular formula C12H10N2O that the conformations of the N-H and C=O bonds are anti to each other, The -NH-C=O- group makes dihedral angles of 33.5(2)º and 17.1(2)º with the benzoyl and pyridyl rings, respectively, while the angle between the benzoyl and pyridine rings is 49.9(6)º. In the crystal structure, N-H···N hydrogen bonds link the molecules into a chain along the b axis. In addition, the structure is stabilized by p-p stacking interactions involving the benzene rings [centroid-to-centroid distance = 2.257(3) Å].
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References
A. Saeed, S. Hussain and U. Flörke, Acta Cryst., E64, o705 (2008).
B.T. Gowda, S. Foro, B.P. Sowmya and H. Fuess, Acta Cryst., E64, o1243 (2008).
B.T. Gowda, S. Foro, B.P. Sowmya and H. Fuess, Acta Cryst., E64, o861 (2008).
B.T. Gowda, S. Foro, B.P. Sowmya and H. Fuess, Acta Cryst., E64, o1300 (2008).
W.K. Dong, X.Q. Yang and J.H. Feng, Acta Cryst., E62, o3459 (2006).
W.K. Dong, X.Q. Yang, L. Xu, L. Wang, G.L. Liu and J.H. Feng, Z. Kristallogr. NCS, 222, 79 (2007).
W.K. Dong, X.Q. Yang, L.Q. Chai, Y.Q. Tian and J.H. Feng, Phosphorus Sulfur Silicon Rel Elem., 183, 1181 (2008).
W.K. Dong, H.B. Yan, L.Q. Chai, Z.W. Lv and C.Y. Zhao, Acta Cryst., E64, o1097 (2008).
Y.J. Ding, X.B. Chang, X.Q. Yang and W.K. Dong, Acta Cryst., E64, o658 (2008).
W.K. Dong, G. Wang, Y.X. Sun, X.Y. Dong and X.H. Gao, Z. Naturforsch., 67b, 17 (2012).
W.K. Dong, Y.X. Sun, Y.P. Zhang, L. Li, X.N. He and X.L. Tang, Inorg. Chim. Acta, 362, 117 (2009).