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Vol. 25 No. 7 (2013): Vol 25 Issue 7

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Synthesis and Supramolecular Structure of Bis-zinc(II) Tetraformate Tetrahydrate Polymer [Zn2(HCOO–)4(H2O)4]n

https://doi.org/10.14233/ajchem.2013.13980
Li Wang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Xiu-Yan Dong
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Li Zhao
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Yu-Hua Yang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Corresponding Author(s) : Li Wang

wangli_78@126.com

Asian Journal of Chemistry, Vol. 25 No. 7 (2013): Vol 25 Issue 7

Abstract

The polymeric compound bis-zinc(II) tetraformate tetrahydrate with the m.f. [Zn2(HCOO–)4(H2O)4]n, was synthesized unexpectively by the reaction of zinc(II) acetate dihydrate with 2,2'-[1,1'-(propane-1,3-diyldioxy)bis(nitrilomethylidyne)]di-1-naphthol (H2L) in ethanol. The molecule crystallizes in the monoclinic system, adopts a polymer conformation. The crystal structure indicates that it is an infinite three-dimension supramolecular network complex.

Keywords

Monooxime compound Synthesis Crystal structure Supramolecular interaction
Wang, L., Dong, X.-Y., Zhao, L., & Yang, Y.-H. (2013). Synthesis and Supramolecular Structure of Bis-zinc(II) Tetraformate Tetrahydrate Polymer [Zn2(HCOO–)4(H2O)4]n. Asian Journal of Chemistry, 25(7), 4055–4057. https://doi.org/10.14233/ajchem.2013.13980
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