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Vol. 25 No. 7 (2013): Vol 25 Issue 7

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Chemical Constituents of Heliotropium hirsitutissimum Grauer (Heliotrope) (Sigil otu, Bambil) (Sonnenwende) and Ecotype

https://doi.org/10.14233/ajchem.2013.13729
Hatice Demiray
Department of Biology, Faculty of Science, University of Ege, Section of Botany, 35100 Bornova, Izmir, Turkey
Meliha Gemici
Department of Biology, Faculty of Science, University of Ege, Section of Botany, 35100 Bornova, Izmir, Turkey
Isin Yazici
Department of Biology, Faculty of Science, University of Ege, Section of Botany, 35100 Bornova, Izmir, Turkey
Fatih Karabey
Department of Biology, Faculty of Science, University of Ege, Section of Botany, 35100 Bornova, Izmir, Turkey

Corresponding Author(s) : Hatice Demiray

haticedemus@yahoo.com

Asian Journal of Chemistry, Vol. 25 No. 7 (2013): Vol 25 Issue 7

Abstract

The aim of this study is to examine the chemical constituents of Heliotropium hirsitutissimum GRAUER naturally spreaded in Denizli and its ecotype spreaded a hotter region in Izmir (Bornova-campus) and to identify them by GC-MS. After the extraction of fresh leaves, one alkaloid and a mixture of phenols, essential oils: 2,3- butanediol, 2-3- dimethyl- (CAS) pinacol (other name: tetramethylethylene glycol), phenol, 4-(3-hydroxy-1-propenyl-2-methyl-(CAS) coniferyl alcohol (other name 4-hydroxy-3-methoxycinnamyl alcohol), 1H-pyrrolizine-7-methanol-2,3,5,7,a-tetrahydro-1-hydroxy-(IS-Cis)- (CAS)=heliotridine, Xycaine$ Aceteamide, 2-(diethylamino)-N-(2,6-dimethylphenyl) and 2,6,10,14,18,22-tetracosahexaene (other name: squalene) were identified in the species spreaded naturally in Denizli. Izmir ecotype gave a mixture of essential oils and phenol 1-hexadecanol; tetracosane acid, butyl 2-methylpropyl ester, phenol: phenol, 4,4¢-(1-methylethylidene)bis-(CAS) 2,2-bis(p-hydroxyphenyl)propane, ethanol, 2-2¢-(1-2-ethanediol bis(oxy))bis-(CAS)triethylene glycol, octadecanoic acid (other name stearic acid), 2-hydroxy-1-(hydroxymethyl) ethyl ester (CAS) and 2-Monostearin. The main components of the two ecotypes was 1,2-benzene dicarboxylic acid and hexadecanol. The presence of triethylene glycol was found to be as the significant structural difference of Izmir ecotype. These results indicated that the composition of heliotrops highly dependent on the climate conditions.

Keywords

Heliotropium hirsitutissimum Ecotype Chemical constituents
Demiray, H., Gemici, M., Yazici, I., & Karabey, F. (2013). Chemical Constituents of Heliotropium hirsitutissimum Grauer (Heliotrope) (Sigil otu, Bambil) (Sonnenwende) and Ecotype. Asian Journal of Chemistry, 25(7), 3725–3730. https://doi.org/10.14233/ajchem.2013.13729
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