Issue

Vol. 25 No. 7 (2013): Vol 25 Issue 7

Copyright (c) 2013 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Linear Solvation Energy Relationship of Some Aromatic Compounds in RP-HPLC

https://doi.org/10.14233/ajchem.2013.13682
Y. Jin
College of Food Science and Technology, Shanghai Ocean University, Shanghai, 201-306, P.R. China ; Department of Chemical Engineering, Inha University, Incheon, 402-751, South Korea
L.H. Yan
Department of Mathematics, Inha University, Incheon, 402-751, South Korea
M.J. Jin
Department of Forestry Science, Agricultural College of Yanbian University, Yanji, Jilin, 133-002, P.R. China
Y.D. Cheng
College of Food Science and Technology, Shanghai Ocean University, Shanghai, 201-306, P.R. China
K.H. Row
Department of Chemical Engineering, Inha University, Incheon, 402-751, South Korea

Corresponding Author(s) : K.H. Row

rowkho@inha.ac.kr

Asian Journal of Chemistry, Vol. 25 No. 7 (2013): Vol 25 Issue 7

Abstract

The fundamental chemical interactions governing the retention of 5 aromatic compounds such as benzene, toluene, chlorobenzene, o-xylene and 1,2-dichlorobenzene were investigated in methanol/water mobile phase on a C18 column using linear solvation energy relationship (LSER) model. The ability of the linear solvation energy relationship to account for the chemical interactions underlying solute retention was shown. A comparison of predicted and experimental retention factors suggests that linear solvation energy relationship formalism is able to reproduce adequately the experimental retention factors of the solutes studied in the different experimental conditions investigated. The predicted retention factors by the linear solvation energy relationship model have good agreement with experimental data in the employed mobile phase conditions.

Keywords

Linear solvation energy relationship Aromatic compounds Retention factor Reverse phase High performance liquid chromatography
Jin, Y., Yan, L., Jin, M., Cheng, Y., & Row, K. (2013). Linear Solvation Energy Relationship of Some Aromatic Compounds in RP-HPLC. Asian Journal of Chemistry, 25(7), 3621–3624. https://doi.org/10.14233/ajchem.2013.13682
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. Y. Jin, J.W. Lee, C.H. Jin and K.H. Row, Sep. Sci. Technol., 43, 331 (2008).
  2. Y. Wang, D. Han, M. Tian and K.H. Row, Korean J. Chem. Eng., 26, 812 (2009).
  3. M.J. Kamlet, R.M. Doherty, M.H. Abraham, Y. Marcus and R.W. Taft, J. Phys. Chem., 92, 5244 (1988).
  4. M.J. Kamlet, R.M. Doherty, P.W. Carr, D. Mackay, M.H. Abraham and R.W. Taft, Environ. Sci. Technol., 22, 503 (1988).
  5. T. Wang, X. Wang and R.L. Smith Jr., J. Supercrit. Fluids, 35, 18 (2005).
  6. Y. Jin and K.H. Row, J. Liq. Chromatogr. Rel. Technol., 30, 335 (2007).
  7. C.H. Lochmüller, C. Reese, A.J. Aschman and S.J. Breiner, J. Chromatogr. A, 656, 3 (1993).
  8. M.H. Abraham, J. Andonian-Haftvan, G.S. Whiting, A. Leo and R.S. Taft, J. Chem. Soc., 8, 1777 (1994).
  9. B.W. Gung, X.W. Xue and W.R. Roush, J. Am. Chem. Soc., 125, 3668 (2003).
  10. P.W. Carr, R.M. Doherty, M.J. Kamlet, R.W. Taft, W. Melander and C. Horvath, Anal. Chem., 58, 2674 (1986).
  11. L.C. Tan and P.W. Carr, J. Chromatogr. A, 799, 1 (1998).
  12. M.H. Abraham, H.S. Chadha and A.J. Leo, J. Chromatogr. A, 685, 203 (1994).
  13. J.H. Park, J.J. Chae, T.H. Nah and M.D. Jang, J. Chromatogr. A, 664, 149 (1994).
  14. M. Tian, S. Li and K.H. Row, Korean J. Chem. Eng., 28, 357 (2011).
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0