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Vol. 25 No. 7 (2013): Vol 25 Issue 7

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Synthesis, Crystal Structure and Luminescene Spectrum of a Binuclear Complex [Eu2(HOC6H4CH2COO)6(C10H8N2)2(H2O)2]·H2O

https://doi.org/10.14233/ajchem.2013.13678
Hong-Xun Zhang
Xingzhi College, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, P.R. China
Quan-Yin Guan
Xingzhi College, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, P.R. China
Guo-Liang Zhao
Xingzhi College, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, P.R. China

Corresponding Author(s) : Guo-Liang Zhao

sky53@zjnu.cn

Asian Journal of Chemistry, Vol. 25 No. 7 (2013): Vol 25 Issue 7

Abstract

A binuclear complex [Eu2(HOC6H4CH2COO)6(C10H8N2)2(H2O)2]·H2O (1) was synthesized and characterized by X-ray diffraction single-crystal structure analysis. The synthesis was based on the reaction of p-hydroxyphenyl acetic acid, 4,4'-bipyridine and Eu(NO3)3·6H2O in mixed solution of water and ethanol. The complex C68H64N4O21Eu2, crystallizes in triclinic, space group Pn with a = 1.17504(2) nm, b = 1.62913(3) nm, c = 1.84424(4) nm, a = 83.599(1)º, b =72.054 (1)º, g = 71.038(1)º, V = 3.17614(11) nm3, Mr = 1577.15, μ(MoKa) = 2.039 mm-1, Dc = 1.649 g/cm3, F(000) = 1588, Z =2, the final R = 0.0255, wR = 0.0599 for 11865 observed reflections [I>2s(I)]. Each Eu(III) atom is in a distorted monomap square-antiprismatic environment, surrounded by eight oxygen atoms from carboxyl and water molecules, one nitrogen atom from 4,4'-bipyridine. The occurence of numerous O-H…O involving coordinated and non-coordinated water molecules build up an intricated three dimensionnal network.

Keywords

Europium complex p-Hydroxyphenylacetic acid Crystal structure Luminescene spectrum
Zhang, H.-X., Guan, Q.-Y., & Zhao, G.-L. (2013). Synthesis, Crystal Structure and Luminescene Spectrum of a Binuclear Complex [Eu2(HOC6H4CH2COO)6(C10H8N2)2(H2O)2]·H2O. Asian Journal of Chemistry, 25(7), 3613–3616. https://doi.org/10.14233/ajchem.2013.13678
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References
  1. S. Surble, C. Serre, F. Millange, F. Pellé and G. Férey, Solid State Sci., 7, 1074 (2005).
  2. S. Ferlay, T. Mallah, R. Ouahes, M. Verdaguer and P. Veillet, Nature, 378, 701 (1995).
  3. S. Kitagawa, R. Kitaura and S. Noro, Angew. Chem., Int. Ed., 43, 2334 (2004).
  4. N.E. Leadbeater and M. Marco, Chem. Rev., 102, 3217 (2002).
  5. L. Yi, X. Yang and P. Cheng, Cryst. Growth Des., 5, 1215 (2005).
  6. K. Mitsurs, M. Shimamura and S.L. Noro, Chem. Mater., 12, 1288 (2000).
  7. J.M. Sheng, Asian J. Chem., 22, 6622 (2010).
  8. C.-B. Liu, C.-Y. Sun and L.-P. Jin, New. J. Chem., 28, 1019 (2004).
  9. Y. Li, F.-K. Zheng and X. Liu, Inorg. Chem., 45, 6308 (2006).
  10. T. Fiedler, M. Hilder and P.C. Junk, Eur. J. Inorg. Chem., 291 (2007).
  11. Y. Rodriguez-Martin, C. Ruiz-Perez, J. Sanchiz, F. Lloret and M. Julve, Inorg. Chim. Acta, 318, 159 (2001).
  12. J. Tao, Y. Zhang, M.-L. Tong, X.-M. Chen, T. Yuen, C.-L. Lin and X.- Y. Huang, J. Li. Chem. Commun., 1342 (2002).
  13. S. Dalai, P.S. Mukherjee, E. Zangrando, F. Lloret and N.R. Chaudhuri, J. Chem. Soc., Dalton Trans., 822 (2002).
  14. R. Carballo, A. Castineiras, B. Covelo and E.M. Vazquez-Lopez, Polyhedron, 20, 899 (2001).
  15. K. Seki, Phys. Chem. Chem. Phys., 4, 1968 (2002).
  16. X.J. Zheng, L. Li C, S. Gao and L.P. Jin, Polyhedron, 23, 1257 (2003).
  17. G.M. Sheldrick, SHELXS-97, Program for the Solution of Crystal Structures, University of Götingen, Germany (1997).
  18. G.M. Sheldrick, SHELXL-97. Program for the Refinement of Crystal Structures. University of Götingen, Germany (1997).
  19. X.-J. Zhang, L.-P. Jin, S. Gao and S.-Z. Lu, New J. Chem., 29, 798 (2005).
  20. N. Sabbatini, M. Guardigli and J.M. Lehn, Coord. Chem. Rev., 123, 201 (1993).
  21. A. Thirumurugan and S. Natarajan, J. Mater. Chem., 15, 4588 (2005)
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