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Effect of Temperature and Naproxen Sodium Over the Micellization Behaviour of N-Cetyl N,N,N-trimethyl ammonium bromide
Corresponding Author(s) : Gulrez Fatima Durrani
Asian Journal of Chemistry,
Vol. 25 No. 7 (2013): Vol 25 Issue 7
Abstract
Critical micelle concentration of N-cetyl N,N,N-trimethyl ammonium bromide (CTAB) and its mixture with drug naproxen sodium were determined at different temperature by using surface tension technique. Naproxen sodium, a non-steroidal anti-inflammatory drug, which has been found to exhibit typical amphiphilic behaviour in aqueous solution in that they accumulate at interface, depressing the surface tension and form aggregate in solution at sufficiently high concentration. So critical micelle concentration of N-cetyl N,N,N-trimethyl ammonium bromide decreased as the concentration of drug increases and same is the case with temperature. Thermodynamic parameters like DGmic, DHmic and DSmic of micellization of N-cetyl N,N,Ntrimethyl ammonium bromide were also determined in the presence of naproxen sodium salt at different temperature, which shows that free energy of micellization, is favoured in the presence of drug and become more favourable with the temperature.
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- M.-R. Porter, Hand Book of Surfactant Blackie, Glasgow (1991).
- Th.-F. Tadros, Surfactants, Academic Press, London (1984).
- D. Myers, Surfaces, Interfaces and Colloids, VCH, New York (1991).
- B. Mohamed, B. Barney and R. Zana, J. Colloid Interf Sci., 267, 519 (2003).
- E.-D. Goddard and K.-P. Ananthapadmanabhan, Interactions of Surfactants with Polymers and Proteins; CRC Press: Boca Raton, Florida (1993).
- D. Langevin, Adv. Colloid Interf. Sci., 467, 89 (2002).
- J. Funjin and W. Brown, Macromolecules, 27, 5024 (1994).
- G.-F. Durrani, M.K. Baloch and G. Hameed, J. Chem. Soc. Pak., 3, 26 (2004).
- J. Taber, J. Pure Appl. Chem., 52, 1323 (1980).
- P. Bahadur and G. Reiss, Tenside Surf. Deterg., 28, 173 (1991).
- P.-N. Hurter and T.-A. Hatton, Langmuir, 8, 1291 (1992).
- P. Alexandridis, Curr. Opin. Colloid Interf. Sci., 1, 490 (1996).
- K. Suzuki, Y. Saito, Y. Tokuoka, M. Abe and T. Sato, J. Am. Oil. Chem. Soc., 74, 55 (1997).
- M.-K. Baloch, G. Hameed and A. Bano, J. Chem. Soc. Pak., 24, 77 (2002).
- M.-R. Porter, Hand Book of Surfactant, pp. 129-33 (1999).
- G.S. Hartley, Aqueous Solution of Paraffin Chain Salts, A Study in Micelle Formation, Hermann et Cie, Paris (1936).
- D. Attwood and A.-T. Florence, Surfactant Systems, Chapman and Hall Ltd, London (1983).
- A. Khan, G. Fatima, M. Usman, W. Harrison and M. Siddiq, J. Chem. Soc. Pak., 31, 534 (2009).
- M.-K. Baloch, A. Farzana, A. Rauf and G. Fatima, J. Appl. Polym. Sci., 114, 1444 (2009).
- C.-O. Rangel-Yagui, H.-W.-L. Hsu, A. Pessoa-Jr. and L.-C. Tavares, J. Pharm. Pharm. Sci., 41, 237 (2005).
- M.-J. Rosen, Surfactants and Interfacial Phenomena. Wiley-Interscience Publication (1978).
- P.C. Heimenz and R. Rajagopalan, Principles of Colloid and Surface Chemistry, edn. 3.
- C.-O. Rangel-Yagui, H.-W.-L. Hsu, A. Pessoa-Jr. and L.-C. Tavares, J. Pharm. Pharma. Sci., 41, 237 (2005).
References
M.-R. Porter, Hand Book of Surfactant Blackie, Glasgow (1991).
Th.-F. Tadros, Surfactants, Academic Press, London (1984).
D. Myers, Surfaces, Interfaces and Colloids, VCH, New York (1991).
B. Mohamed, B. Barney and R. Zana, J. Colloid Interf Sci., 267, 519 (2003).
E.-D. Goddard and K.-P. Ananthapadmanabhan, Interactions of Surfactants with Polymers and Proteins; CRC Press: Boca Raton, Florida (1993).
D. Langevin, Adv. Colloid Interf. Sci., 467, 89 (2002).
J. Funjin and W. Brown, Macromolecules, 27, 5024 (1994).
G.-F. Durrani, M.K. Baloch and G. Hameed, J. Chem. Soc. Pak., 3, 26 (2004).
J. Taber, J. Pure Appl. Chem., 52, 1323 (1980).
P. Bahadur and G. Reiss, Tenside Surf. Deterg., 28, 173 (1991).
P.-N. Hurter and T.-A. Hatton, Langmuir, 8, 1291 (1992).
P. Alexandridis, Curr. Opin. Colloid Interf. Sci., 1, 490 (1996).
K. Suzuki, Y. Saito, Y. Tokuoka, M. Abe and T. Sato, J. Am. Oil. Chem. Soc., 74, 55 (1997).
M.-K. Baloch, G. Hameed and A. Bano, J. Chem. Soc. Pak., 24, 77 (2002).
M.-R. Porter, Hand Book of Surfactant, pp. 129-33 (1999).
G.S. Hartley, Aqueous Solution of Paraffin Chain Salts, A Study in Micelle Formation, Hermann et Cie, Paris (1936).
D. Attwood and A.-T. Florence, Surfactant Systems, Chapman and Hall Ltd, London (1983).
A. Khan, G. Fatima, M. Usman, W. Harrison and M. Siddiq, J. Chem. Soc. Pak., 31, 534 (2009).
M.-K. Baloch, A. Farzana, A. Rauf and G. Fatima, J. Appl. Polym. Sci., 114, 1444 (2009).
C.-O. Rangel-Yagui, H.-W.-L. Hsu, A. Pessoa-Jr. and L.-C. Tavares, J. Pharm. Pharm. Sci., 41, 237 (2005).
M.-J. Rosen, Surfactants and Interfacial Phenomena. Wiley-Interscience Publication (1978).
P.C. Heimenz and R. Rajagopalan, Principles of Colloid and Surface Chemistry, edn. 3.
C.-O. Rangel-Yagui, H.-W.-L. Hsu, A. Pessoa-Jr. and L.-C. Tavares, J. Pharm. Pharma. Sci., 41, 237 (2005).