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Synthesis, Crystal Structure and Magnetic Property of a Sandwich-Like Cyanide-Bridged Fe(III)-Mn(II) Complex
Corresponding Author(s) : Daopeng Zhang
Asian Journal of Chemistry,
Vol. 25 No. 6 (2013): Vol 25 Issue 6
Abstract
A trinuclear cyanide-bridged Fe(III)-Mn(II) complex has been synthesized with pyridine carboxamide trans-dicyanide iron building block and structurally characterized as trinuclear sandwich-like, in which the two cyanide-containing building blocks acting as a monodentate ligand were coordinated face to face to central Mn(II) ion. Investigation over its magnetic property reveals the antiferromagnetic magnetic coupling between the cyanide-bridged neighboring Fe(III) and Mn(II) ions.
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- J.N. Rebilly and T. Mallah, Struct. Bond, 122, 103 (2006).
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References
J.N. Rebilly and T. Mallah, Struct. Bond, 122, 103 (2006).
R. Lescouezec, L.M. Toma, J. Vaissermann, M. Verdaguer, F.S. Delgado, C. Ruiz-Perez, F. Lloret and M. Julve, Coord. Chem. Rev., 249, 2691 (2005).
H. Miyasaka,A. Saitoh and S. Abe, Coord. Chem. Rev., 251, 2622 (2007).
Z.H. Ni, H.Z. Kou, L.F. Zhang, C. Ge, A.L. Cui, R.J. Wang, Y. Li and O. Sato, Angew. Chem. Int. Ed., 44, 7742 (2005).
Z.H. Ni, H.Z. Kou, Y.H. Zhao, L. Zheng, R.J. Wang, A.L. Cui and O. Sato, Inorg. Chem., 44, 2050 (2005).
Z.H. Ni, L.F. Zhang, V. Tangoulis, W. Wernsdorfer, A.L. Cui, O. Sato and H.Z. Kou, Inorg. Chem., 46, 6029 (2007).
D.P. Zhang, H.L. Wang, Y.T. Chen, Z.H. Ni, L.J. Tian and J.Z. Jiang, Inorg. Chem., 48, 5488 (2009).
G.M. Sheldrick, SHELXTL97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany (1997).