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Utilizing of 2-Amino-3-hydroxypyridine Modified Glassy Carbon Electrode to Detect Copper(II) Ions
Corresponding Author(s) : Aysen Demir Mülazimoglu
Asian Journal of Chemistry,
Vol. 25 No. 6 (2013): Vol 25 Issue 6
Abstract
In this paper, 2-amino-3-hydroxypyridine modified glassy carbon electrode was used for the electrochemical analysis of trace copper(II) ions by square wave voltammetry technique. The modification of the glassy carbon electrode by 2-amino-3-hydroxypyridine solution was performed in the potential range between -150 mV and +600 mV by 30 cycles at 100 mV s-1 potential scan rate in non-aqueous media by cyclic voltammetry. The surface characterizations of this sensor electrode were performed by cyclic voltammetry. A lower detection limit would be reached in the presence of Britton-Robinson buffer solution at pH 5 for determination of Cu(II) ions by square wave voltammetry. The voltammetric response of the electrode was linear within the Cu(II) ion concentration range from 1.0 ×10-12 M to 1.0 × 10-6 M and the detection limit of 1.0 × 10-12 M. The modified electrode offered an excellent way, with a high stability, simple, rapid, low cost and reusability, for selective determination of Cu(II) ions in Acigöl lake (in Afyonkarahisar, Turkey) water sample.
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- W. Yang, J.J. Gooding and D.B. Hibbert, J. Electroanal. Chem., 516, 10 (2001).
- A. Zouaoui, O. Ste´phan, A. Ourari and J.C. Moutet, Electrochim. Acta, 46, 49 (2000).
- G.M.R. van Dutren, E. Labbe, V. Paul-Boncour, J. Perichon and A. Percheron-Guegan, J. Electroanal. Chem., 487, 31 (2000).
- A.D. Mülazimoglu and I.E. Mülazimoglu, Food Anal. Methods, DOI: 10.1007/s12161-012-9426-2 (2012).
- I.E. Mülazimoglu, A.D. Mülazimoglu and E. Yilmaz, Desalination, 268, 227 (2011).
- E. Yilmaz and A.D. Mülazimoglu, Energy Educ. Sci. Technol. Part A, 29, 1167 (2012).
- I.E. Mülazimoglu and A.O. Solak, Anal. Methods, 3, 2534 (2011).
- R.L. McCreery, in ed.: A. Wieckowski, Interfacial Electrochemistry: Theory, Experiment and Applications, Marcel Dekker, New York (1999).
- A.J. Downard, Electroanalysis, 12, 1085 (2000).
- P. Allongue, M. Delamar, B. Desbat, O. Fagebaume, R. Hitmi, J. Pinson and J.-M. Saveant, J. Am. Chem. Soc.,119, 201 (1997).
- C.P. Andrieux, F. Gonzalez and J.-M. Saveant, J. Am. Chem. Soc., 119, 4292 (1997).
- A.A. Ensafi, T. Khayamian,A. Benvidi and E. Mirmomtaz, Anal. Chim. Acta, 561, 225 (2006).
- M.A. Nolan and S.P. Kounaves, Anal. Chem., 71, 3567 (1999).
- A.D. Mülazimoglu, I.E. Mülazimoglu and E. Yilmaz, Rev. Anal. Chem., 31, 131 (2012).
- A.D. Mülazimoglu and I.E. Mülazimoglu, Food Anal. Methods, DOI: 10.1007/s12161-012-9492-5 (2012)
References
W. Yang, J.J. Gooding and D.B. Hibbert, J. Electroanal. Chem., 516, 10 (2001).
A. Zouaoui, O. Ste´phan, A. Ourari and J.C. Moutet, Electrochim. Acta, 46, 49 (2000).
G.M.R. van Dutren, E. Labbe, V. Paul-Boncour, J. Perichon and A. Percheron-Guegan, J. Electroanal. Chem., 487, 31 (2000).
A.D. Mülazimoglu and I.E. Mülazimoglu, Food Anal. Methods, DOI: 10.1007/s12161-012-9426-2 (2012).
I.E. Mülazimoglu, A.D. Mülazimoglu and E. Yilmaz, Desalination, 268, 227 (2011).
E. Yilmaz and A.D. Mülazimoglu, Energy Educ. Sci. Technol. Part A, 29, 1167 (2012).
I.E. Mülazimoglu and A.O. Solak, Anal. Methods, 3, 2534 (2011).
R.L. McCreery, in ed.: A. Wieckowski, Interfacial Electrochemistry: Theory, Experiment and Applications, Marcel Dekker, New York (1999).
A.J. Downard, Electroanalysis, 12, 1085 (2000).
P. Allongue, M. Delamar, B. Desbat, O. Fagebaume, R. Hitmi, J. Pinson and J.-M. Saveant, J. Am. Chem. Soc.,119, 201 (1997).
C.P. Andrieux, F. Gonzalez and J.-M. Saveant, J. Am. Chem. Soc., 119, 4292 (1997).
A.A. Ensafi, T. Khayamian,A. Benvidi and E. Mirmomtaz, Anal. Chim. Acta, 561, 225 (2006).
M.A. Nolan and S.P. Kounaves, Anal. Chem., 71, 3567 (1999).
A.D. Mülazimoglu, I.E. Mülazimoglu and E. Yilmaz, Rev. Anal. Chem., 31, 131 (2012).
A.D. Mülazimoglu and I.E. Mülazimoglu, Food Anal. Methods, DOI: 10.1007/s12161-012-9492-5 (2012)