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Vol. 25 No. 6 (2013): Vol 25 Issue 6

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A Facile Synthesis of Poly(acrylanilide-co-acrylic Acid)

https://doi.org/10.14233/ajchem.2013.13608
Xiaoming Zhou
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, P.R. China
Bingtao Tang
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, P.R. China
Shufen Zhang
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, P.R. China

Corresponding Author(s) : Shufen Zhang

zhangshf@dlut.edu.cn

Asian Journal of Chemistry, Vol. 25 No. 6 (2013): Vol 25 Issue 6

Abstract

A range of poly(acrylanilide-co-acrylic acid) was synthesized through a facile one-pot condensation of poly(acrylic acid) with aromatic amines. Thionyl chloride was added in a stepwise manner to N,N-dimethyl acetamide and poly(acryloyl chloride) need not be isolated during the reaction. Compared with conventional methods, the condensation of poly(acryloyl chloride) with aromatic amines could perform without the addition of other bases (such as triethylamine, pyridine, etc.). Regardless of electron-withdrawing or electron-donating groups the aromatic amines contain, the reaction was carried out smoothly. Different molar ratios of poly(acrylic acid) (acrylic acid units) to aromatic amines were investigated and moderate yields were obtained. The products were characterized by nuclear magnetic resonance spectroscopy and Fourier-transform infrared spectroscopy.

Keywords

One-pot synthesis Poly(acrylanilide-co-acrylic acid) Thionyl chloride
Zhou, X., Tang, B., & Zhang, S. (2013). A Facile Synthesis of Poly(acrylanilide-co-acrylic Acid). Asian Journal of Chemistry, 25(6), 3247–3251. https://doi.org/10.14233/ajchem.2013.13608
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