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Biosorption of Ranitidine Onto Live Activated Sludge
Corresponding Author(s) : Serpil Savci
Asian Journal of Chemistry,
Vol. 25 No. 6 (2013): Vol 25 Issue 6
Abstract
Ranitidine is a drug responsible for disturbing the microbial ecology of surface waters. The potential use of live activated sludge (0.5 g and 1.0 g) for removal of ranitidine, one of the most widely used H2-receptor antagonists, from aqueous solution was examined. The biosorption of ranitidine on live activated sludge was investigated in a batch system. The ranitidine biosorption was fast and equilibrium was attained within 10 min. Data obtained from batch studies applied to Langmuir, Freundlich, Tempkin isotherm models. Kinetic and equilibrium adsorption data show that the process obeys to the pseudo-second order kinetic equation, Freundlich and Tempkin adsorption models. Gibbs free energy values were found to be 4.588 kj/mol for 0.5 g adsorbent and 3.613 kj/mol for 1.0 g adsorbent and indicating the not spontaneity of the system. Octanol-water partition coefficient (Kow) and biosorption coefficient, Kd, which describes the solid liquid partitioning characteristics of a compound in biosorption mechanism were also calculated.
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- Pollutants In Urban Waste Water And Sewage Sludge Final Report, ICON, IC Consultants Ltd., London United Kingdom, February (2001).
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- E. Godfrey, W.W. Woessner and M.J. Benotti, Ground Water, 45, 263 (2007).
- J.B. Quntana, S. Weiss and T. Reemtsema, Water Res., 39, 2654 (2005).
- Z. Aksu and Ö. Tunç, Proc. Biochem., 40, 831 (2005).
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- Standard Methods,A.P.H.A.-A.W.W.A-W.P.C.F., Standart Methods For The Examination of Water and Wastewater. 19. Baski., Washington, DC (1998).
- E. Möhle, C. Kempter, A. Kern and J.W. Metzger, Acta Hydrochim. Hydrobiol., 27, 430 (1999).
- Y.S. Ho, C.T. Huang and Huang, Process. Biochem., 37, 1421 (2002).
- T. Robinson, B. Chadran and P. Nigam, Water Res., 36, 2824 (2002).
- Y.-S. Choi, and J.-H. Cho, Environ. Technol., 17, 1169 (1996).
- Y.S. Ho and A.E. Ofomaja, Proc. Biochem., 40, 3455 (2005).
- O.A.H. Jones, N. Voulvoulis and J.N. Lester, Environ. Pollut., 145, 738 (2007).
- R.A. Al-Bayati, Eur. J. Sci. Res., 40, 580 (2010).
- R.A.L. Dobbs, L. Wang and R. Govind, Environ. Sci. Tecnol., 23, 1092 (1989).
- C. Matter-Muller, W. Gujer, W. Giger and W. Stumm, Prog. Water Technol., 12, 299 (1980).
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References
Pollutants In Urban Waste Water And Sewage Sludge Final Report, ICON, IC Consultants Ltd., London United Kingdom, February (2001).
T. Heberer, Toxicol. Lett., 131, 5 (2002).
A.W. Garrison, J.D. Pope and F.R. Allen, in ed.: C.H. Keith, GC/MS Analysis of Organic Compounds in Domestic Wastewaters. Identification and Analysis of Organic Pollutants in Water. Ann. Arbor. Sci. Publishers, Ann. Arbor, Chapter 30, pp. 517-566 (1976).
P.H. Roberts and K.V. Thomas, Sci. Total Environ., 356, 143 (2006).
J.M. Gomez, M. Petrovic, A.R. Fernandez-Alba and D. Barcelo, J. Chromatogr. A., 1114, 224 (2006).
D.W. Kolpin, M. Skopec, M.T. Meyer, E.T. Furlong and S.D. Zaugg, Sci. Total Environ., 328, 119 (2004).
D. Bendz, N.A. Paxeus, T.R. Ginn and F.J. Loge, J. Hazard. Mater., 122, 195 (2005).
M. Farzadkia, M. Gholami, M. Kermani and K. Yaghmaeian, Asian J. Chem., 24, 5257 (2011).
E. Godfrey, W.W. Woessner and M.J. Benotti, Ground Water, 45, 263 (2007).
J.B. Quntana, S. Weiss and T. Reemtsema, Water Res., 39, 2654 (2005).
Z. Aksu and Ö. Tunç, Proc. Biochem., 40, 831 (2005).
J.L. Tabmobi, L.Y. Yamanaka, H. Jorge, J. Regina, F. Peralta and M. Oreira, Quim Nova, 33, 411 (2010).
Standard Methods,A.P.H.A.-A.W.W.A-W.P.C.F., Standart Methods For The Examination of Water and Wastewater. 19. Baski., Washington, DC (1998).
E. Möhle, C. Kempter, A. Kern and J.W. Metzger, Acta Hydrochim. Hydrobiol., 27, 430 (1999).
Y.S. Ho, C.T. Huang and Huang, Process. Biochem., 37, 1421 (2002).
T. Robinson, B. Chadran and P. Nigam, Water Res., 36, 2824 (2002).
Y.-S. Choi, and J.-H. Cho, Environ. Technol., 17, 1169 (1996).
Y.S. Ho and A.E. Ofomaja, Proc. Biochem., 40, 3455 (2005).
O.A.H. Jones, N. Voulvoulis and J.N. Lester, Environ. Pollut., 145, 738 (2007).
R.A. Al-Bayati, Eur. J. Sci. Res., 40, 580 (2010).
R.A.L. Dobbs, L. Wang and R. Govind, Environ. Sci. Tecnol., 23, 1092 (1989).
C. Matter-Muller, W. Gujer, W. Giger and W. Stumm, Prog. Water Technol., 12, 299 (1980).
S.W. Karichhoff, J. Hydraulic. Eng., 110, 6 (1984).
L.F. Stuer, M. Birkved, L.P. Hansen, H.-C. Holten-Lutzhoft and B. Halling-Sorensen, Chemosphere, 40, 783 (2000).