A Composite Based on {VO3}nn- Chain Containing Two Different Types of Organic Ligands

Xinfang Wang; Guiling Guo; Yanqing Xu; Changwen Hu

doi:10.14233/ajchem.2013.13505

Issue

Vol. 25 No. 6 (2013): Vol 25 Issue 6

Issue Published : December 26, 2012

This work is licensed under a Creative Commons Attribution 4.0 International License.

A Composite Based on {VO3}nn- Chain Containing Two Different Types of Organic Ligands

https://doi.org/10.14233/ajchem.2013.13505

Xinfang Wang

Department of Chemistry, Key Laboratory of Cluster Science, Ministry of Education of China, Beijing Institute of Technology, Beijing 100081, P.R. China ; Department of Chemistry, Dezhou University, Dezhou 253023, Shandong Province, P.R. China

Guiling Guo

Department of Chemistry, Key Laboratory of Cluster Science, Ministry of Education of China, Beijing Institute of Technology, Beijing 100081, P.R. China

Yanqing Xu

Department of Chemistry, Key Laboratory of Cluster Science, Ministry of Education of China, Beijing Institute of Technology, Beijing 100081, P.R. China

Changwen Hu

Department of Chemistry, Key Laboratory of Cluster Science, Ministry of Education of China, Beijing Institute of Technology, Beijing 100081, P.R. China

Corresponding Author(s) : Changwen Hu

cwhu@bit.edu.cn

Asian Journal of Chemistry, Vol. 25 No. 6 (2013): Vol 25 Issue 6
Article Published : January 8, 2013

Abstract

The composite compound, [Cu(1,10-phen)(en)H₂O][Cu(en)₂]_0.5[V₃O₉] (1,10-phen = 1,10- phenanthroline, en = ethylenediamine) (1) has been prepared by solution diffusion method. Compound 1 consists of one 1D {VO₃}_n^n- chain formed by corner-sharing VO₄ tetrahedra and two different types of cations [Cu(1,10-phen)(en)H₂O]²⁺ and [Cu(en)₂]²⁺. The adjacent 1D {VO₃}_n nchain are further bridged by [Cu(en)₂]²⁺ complexes through Cu···O weak interactions to form a 2D network.

Keywords

Polyoxometalates Polyoxovanadates Network Cluster

Wang, X., Guo, G., Xu, Y., & Hu, C. (2013). A Composite Based on {VO3}nn- Chain Containing Two Different Types of Organic Ligands. Asian Journal of Chemistry, 25(6), 3033–3035. https://doi.org/10.14233/ajchem.2013.13505

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References

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References

M.T. Pope, Heteropoly and Isoply Oxometalates, Springer, Berlin (1983).

C.L. Hill, Chem. Rev., 98, 1 (1998).

L.F. Zhu, B. Guo, D.Y. Tang, X.K. Hu, G.Y. Li and C.W. Hu, J. Catal., 245, 446 (2007).

M.R. Pai, B.N. Wani and N.M. Gupta, J. Phys. Chem. Solids, 67, 1502 (2006).

M.S. Whittingham, Y. Song, S. Lutta, P.Y. Zavalij and N.A. Chernova, J. Mater. Chem., 15, 3362 (2005).

W. Li, J.R. Dahn and D.S. Wainright, Science, 264, 1115 (1994).

T.H. Hu, Q. Wang, W.S. You, D.W. Song, C.Y. Huang, Y. Xu and Z.G. Sun, Inorg. Chem. Commun., 11, 470 (2008).

P.J. Hagrman and J. Zubieta, Inorg. Chem., 40, 2800 (2001).

P.J. Hagrman, C. Bridges, J.E. Greedan and J. Zubieta, J. Chem. Soc. Dalton Trans., 2901 (1999).

L.M. Zheng, X.Q. Wang, Y.S. Wang and A.J. Jacobson, J. Mater. Chem., 11, 1100 (2001).

L.M. Zheng, J.S. Zhao, K.H. Lii, L.Y. Zhang, Y. Liu and X.Q. Xin, J. Chem. Soc. Dalton Trans., 939 (1999).

J.R.D. DeBord, Y. Zhang, R.C. Haushalter, J. Zubieta and C.J. O'Connor, J. Solid State Chem., 122, 251 (1996).

C.M. Liu, S. Gao, H.M. Hu, X.L. Jin and H.Z. Kou, J. Chem. Soc. Dalton Trans., 598 (2002).

M. Filowitz, R.K.C. Ho, W.G. Klemperer and W. Shum, Inorg. Chem., 18, 93 (1979).

G.M. Sheldrick, SHELXL 97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany (1997).

G.M. Sheldrick, SHELXL 97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, Germany (1997).

T.H. Hu, X. Zhang, Q. Wang , W.S. You, C.Y. Huang and Y. Fang, J. Chem. Crystallogr., 41, 64 (2011).

A. Wutkowski, C. Näther and W. Bensch, Z. Anorg. Allg. Chem., 635, 753 (2009).

H. Jin, Y.F. Qi, E.B. Wang, Y.G. Li, X.L. Wang, C. Qin and S. Chang, Cryst. Growth Des., 6, 2693 (2006).

W.W. Li, Q. Wang, W.S. You, L.J. Qi, L.M. Dai and Y. Fang, Inorg. Chem. Commun., 12, 1185 (2009).

Issue

Vol. 25 No. 6 (2013): Vol 25 Issue 6

A Composite Based on {VO3}nn- Chain Containing Two Different Types of Organic Ligands

Corresponding Author(s) : Changwen Hu

Abstract

Keywords

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