Comparative Study of Ethylene Catalytic Aromatization and Adsorption Onto Two Kinds of Molecular Sieves

Xiaodong Ma; Feng Ouyang; Dongmei Shen; Xiaokai Cao

doi:10.14233/ajchem.2013.14156

Issue

Vol. 25 No. 5 (2013): Vol 25 Issue 5

Issue Published : November 26, 2012

This work is licensed under a Creative Commons Attribution 4.0 International License.

Comparative Study of Ethylene Catalytic Aromatization and Adsorption Onto Two Kinds of Molecular Sieves

https://doi.org/10.14233/ajchem.2013.14156

Xiaodong Ma

Environmental Science and Engineering Research Center, Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, P.R. China

Feng Ouyang

Environmental Science and Engineering Research Center, Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, P.R. China

Dongmei Shen

Environmental Science and Engineering Research Center, Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, P.R. China

Xiaokai Cao

Environmental Science and Engineering Research Center, Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, P.R. China

Corresponding Author(s) : Feng Ouyang

ouyangfh@hit.edu.cn; mxdxz@foxmail.com

Asian Journal of Chemistry, Vol. 25 No. 5 (2013): Vol 25 Issue 5
Article Published : December 11, 2012

Abstract

The catalytic aromatization and adsorption of ethylene onto two kinds of molecular sieves was investigated at different temperatures. The adsorption amount of ethylene did not decrease with the increasing temperature all the time. By in situ FTIR of pyridine adsorption, NH₃-TPD and GC-MS a possible mechanism was proposed. The acid sites of molecular sieves would become the active sites for aromatization of ethylene to improve the adsorption capacity under high temperature. The maximum adsorption amount was proportional to the number of the acid sites activated by high temperature. Final adsorbates were mainly aromatics. The sizes of final products were limited to the diameters of pores.

Keywords

Ethylene MCM-41 MCM-22 Catalytic aromatization Adsorption

Ma, X., Ouyang, F., Shen, D., & Cao, X. (2012). Comparative Study of Ethylene Catalytic Aromatization and Adsorption Onto Two Kinds of Molecular Sieves. Asian Journal of Chemistry, 25(5), 2869–2874. https://doi.org/10.14233/ajchem.2013.14156

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References

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References

W. Malisoff and G. Egloff, J. Phys. Chem., 23, 65 (1919).

Chem. Eng. News, 84, 59 (2006).

M. Ruth, A.D. Amato and B. Davidsdottir, Environ. Sci. Technol., 36, 119 (2002).

D.-R. Park, J.-L. Zhang, K. Ikeue, H. Yamashita and M. Anpo, J. Catal., 185, 114 (1999).

J.M. Alonso and A.N. Stepanova, Science, 306, 1513 (2004).

A.R. Albunia, T. Minucci and G. Guerra, J. Mater. Chem., 18, 1046 (2008).

J.-J. Li, C.-Y. Ma, X.-Y. Xu, J.-J. Yu, Z.-P. Hao and S.-Z. Qiao, Environ. Sci. Technol., 42, 8947 (2008).

A.E. Blidi, L. Rigal, G. Malmary, J. Molinier and L. Torres, Food Qual. Prefer., 4, 119 (1993).

J. Kim, J. Hazard. Mater., B131, 131 (2006).

A.R. Albunia, T. Minucci and G. Guerra, J. Mater. Chem., 18, 1046 (2008).

B. Hauchecorne, T. Tytgat, S.W. Verbruggen, D. Hauchecorne, D. Terrens, M. Smits, K. Vinken and S. Lenaerts, Appl. Catal., B, 105, 111 (2011).

Y.-M. Fu, L.-Z. Shao, L. Tong and H. Liu, Bioresour. Technol., 102, 576 (2011).

S.A. Al-Muhtaseb, J. Chem. Eng. Data, 22, 313 (2010).

P.-C. Ye, Z.-H. Fang, B.-G. Su, H.-B. Xing, Y.-W. Yang, Y. Su and Q.- L. Ren, J. Chem. Eng. Data, 22, 5669 (2010).

N. Patdhanagul, T. Srithanratana, K. Rangsriwatananon and S. Hengrasmee, Microporous Mesoporous Mater., 131, 97 (2010).

N. Sue-Aok, T. Srithanratana, K. Rangsriwatananon and S. Hengrasmee, Appl. Surf. Sci., 256, 3997 (2010).

B. Erdogan, M. Sakizci and E. Yörükogullari, Appl. Surf. Sci., 254, 2450 (2008).

J.-Y. Shen, J.M. Hill, R.M. Watwe, S.G. Podkolzin and J.A. Dumesic, Catal. Lett., 60, 1 (1999).

I.R. Subbotina and V.B. Kazanskii, Kinet. Catal., 43, 115 (2002).

J. Yang, Y. Zhou, J.-Y. Yang, W.-G. Lin, Y.-J. Wu, N. Lin, J. Wang and J.-H. Zhu, J. Phys. Chem. C., 114, 9588 (2010).

C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli and J.S. Beck, Nature, 359, 710 (1992).

S.L. Lawton, A.S. Fung, G.J. Kennedy, L.B. Alemany, C.D. Chang, G.H. Hatzikos, D.N. Lissy, M.K. Rubin, H.-K. C. Timken, S. Steuernagel and D.E. Woessner, J. Phys. Chem., 100, 3788 (1996).

J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.-W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins and J.L. Schlenker, J. Am. Chem. Soc., 114, 10834 (1992).

B. Chakraborty and B. Viswanathan, Catal. Today, 49, 253 (1999).

A.G. Evans, M. Polanyi, H.S. Lilley, L.B. Morgan, H.A. Skinner, P.H. Plesch, M.G. Evans, H.W. Melville, G.B.B.M. Sutherland, W. Cooper, J.H. Baxendale, G. Gee, H.W. Thompson, J.L. Stoves, F. Brown, C.W. Burn, D.J. Crisp and I. MacArthur, J. Chem. Soc., 252 (1947).

A. Ogata, D. Ito, K. Mizuno, S. Kushiyama and T. Yamamoto, IEEE Trans. Ind. Appl., 37, 959 (2001).

Issue

Vol. 25 No. 5 (2013): Vol 25 Issue 5

Comparative Study of Ethylene Catalytic Aromatization and Adsorption Onto Two Kinds of Molecular Sieves

Corresponding Author(s) : Feng Ouyang

Abstract

Keywords

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