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Synthesis and Antimicrobial Activity of Aluminium(III), Nickel(II) and Zinc(II) Schiff base Complexes Derived from o-Phenylenediamine and Salicylaldehyde
Corresponding Author(s) : Reda M. El-Shishtawy
Asian Journal of Chemistry,
Vol. 25 No. 5 (2013): Vol 25 Issue 5
Abstract
N2O2 tetradentate Schiff base ligand was synthesized from salicylaldehyde and o-phenylenediamine. This ligand was reacted with Al(III), Ni(II) and Zn(II) ions to yield the corresponding complexes. The ligand and its complexes have been characterized by IR, 1H NMR and elemental analysis. The spectral data of these compounds are discussed in connection with the structural changes due to complexation. The complexes prepared showed good antibacterial activities. The activity data show that the Al(III), Ni(II) and Zn(II) complexe are more potent antibacterial than the parent Schiff base ligand and among all Al(III) complex was the highest.
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- X.-G. Zhou, J.-S. Huang, Z.-Y. Zhou, K.-K. Cheung and Ch-.M. Che, Inorg. Chim. Acta, 331, 194 (2002).
- D.M. Boghael and S. Mohebi, J. Mol. Catal. A, 179, 41 (2002).
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- L.A. Kovbasyuk, I.O. Fritzky, V.N. Kokozay and T.S. Iskenderov, Polyhedron, 16, 1723 (1997).
- M.R. Bermejo, A. Sousa, A. García-Deibe, M. Maneiro, J. Sanmartín and M. Fondo, Polyhedron, 18, 511 (1999).
- F. Tuna, L. Patron and M. Andruh, Inorg. Chem. Commun., 6, 30 (2003).
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- L. Deng and E.N. Jacobsen, J. Org. Chem., 57, 4320 (1992); E.N. Jacobsen, L. Deng, Y. Furukawa and L.E. Martinez, Tetrahedron, 50, 4323 (1994).
- K. Imagawa, T. Negata, T. Yamada and T. Mukaiyama, Chem. Lett., 527, (1994); C. Bolm, Angew. Chem., 103, 414 (1991); Angew. Chem. Ed. Engl., 30, 403 (1991).
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- N. Raman,A. Thangaraja and C. Kulandaisamy, Transition Met. Chem., 28, 29 (2003).
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- D. Greenwood, Antimicrobial Chemotherapy, Part II. Laboratory Aspects of Antimicrobial Therapy, Bailliere, Tindall, London, p. 71 (1983).
- M.R. Mahmoud, S.A. Ibrahim and N.M. Ismail, Monatsh. Chem., 116, 167 (1985).
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References
X.-G. Zhou, J.-S. Huang, Z.-Y. Zhou, K.-K. Cheung and Ch-.M. Che, Inorg. Chim. Acta, 331, 194 (2002).
D.M. Boghael and S. Mohebi, J. Mol. Catal. A, 179, 41 (2002).
A. Pui, I. Berdan, I. Morgenstern-Badarau,A. Gref and M. Peree-Fauvet, Inorg. Chim. Acta, 320, 167 (2001).
L.A. Kovbasyuk, I.O. Fritzky, V.N. Kokozay and T.S. Iskenderov, Polyhedron, 16, 1723 (1997).
M.R. Bermejo, A. Sousa, A. García-Deibe, M. Maneiro, J. Sanmartín and M. Fondo, Polyhedron, 18, 511 (1999).
F. Tuna, L. Patron and M. Andruh, Inorg. Chem. Commun., 6, 30 (2003).
G.B. Gill, G. Pattenden and S.J. Reynolds, J. Chem. Soc., Perkin Trans. I, 369 (1994); D.J. Coveney, V.F. Patel, G. Pattenden and D.M. Thompson, J. Chem. Soc., Perkin Trans. I, 2721 (1990).
R. Irie, K. Noda, Y. Ito, N. Matsumoto and T. Katsuki,Tetrahedron:Asymm., 2, 481 (1991).
L. Deng and E.N. Jacobsen, J. Org. Chem., 57, 4320 (1992); E.N. Jacobsen, L. Deng, Y. Furukawa and L.E. Martinez, Tetrahedron, 50, 4323 (1994).
K. Imagawa, T. Negata, T. Yamada and T. Mukaiyama, Chem. Lett., 527, (1994); C. Bolm, Angew. Chem., 103, 414 (1991); Angew. Chem. Ed. Engl., 30, 403 (1991).
S. Ren, R. Wang, K. Komatsu, P. Bonaz-Krause, Y. Zyrianov, C.F. Mckenna, C. Csipke, Z.A. Tokes and E.J. Lien, J. Med. Chem., 45, 410 (2002).
N. Raman,A. Thangaraja and C. Kulandaisamy, Transition Met. Chem., 28, 29 (2003).
J.-N. Liu, B.-W. Wu, B. Zhang and Y.C. Liu, Turk. J. Chem., 30, 41 (2006).
A.A.A. Aziz, J. Mol. Struct., 979, 77 (2010) and references cited therein.
D. Greenwood, Antimicrobial Chemotherapy, Part II. Laboratory Aspects of Antimicrobial Therapy, Bailliere, Tindall, London, p. 71 (1983).
M.R. Mahmoud, S.A. Ibrahim and N.M. Ismail, Monatsh. Chem., 116, 167 (1985).
M.M. Abd-Elzaher, Appl. Organometal. Chem., 18, 149 (2004) and references cited therein.