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Synthesis and Characterization of Mixed Ligand Complexes of Cu(II)-Oxalate-Amino Acids (Aspartic acid and Cysteine)
Corresponding Author(s) : Saeedeh Hashemian
Asian Journal of Chemistry,
Vol. 25 No. 5 (2013): Vol 25 Issue 5
Abstract
The mixed ligand complexes of Cu(II) with oxalate as primary ligand and amino acids (aspartic acid and cysteine) as secondary ligands have been synthesized. The structures of complexes have been characterized on the basis of elemental analysis, conductivity measurements, UV-visible and IR spectroscopy. Electronic spectral data for the complexes were in accordance with an octahedral environment around the central Cu(II) ion. The oxalate group acts as bidentate chelating ligand.
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- P.G. Cozzi, Chem. Soc. Rev., 33, 410 (2004).
- P.K. Singh and D.N. Kumar, Spectrochim. Acta A, 64, 853 (2006).
- E.C. Constable and J.M. Holmes, Inorg. Chim. Acta, 126, 195 (1987).
- M.K. Singh,A. Das and B. Paul, Transition Met. Chem., 30, 655 (2005).
- B.S. Garg, P.K. Singh and J.L. Sharma, Synth. React. Inorg. Met. Org. Chem., 30, 803 (2000).
- J.E. Sprietsma, Med. Hypotheses, 52, 529 (1999).
- F.A. Cary, Organic Chemistry, University of Virginia, Tata McGraw Hill, p. 1109 (2003).
- L. Martinez, R.F. Farias and C. Airoldi, Thermchim. Acta, 395, 21 (2003).
- B.D. Berezin and G.M. Mamardashvili, Russ. J. Coord. Chem., 28, 771 (2002).
- A.S.A. Zidan, J. Thermal Anal. Calorim., 68, 1045 (2002).
- O.P. Slyudkin and A.A. Tulupov, Russ. J. Coord. Chem., 31, 77 (2005).
- N.P. Kryukova, F.A. Kolokolov, S.V. Bolotin and V.T. Panyushkin, Russ. J. Gen. Chem., 75, 503 (2005).
- A. Stanila, A. Marcu, D. Rusu, M. Rusu and L. David, J. Mol. Struct., 834-836, 364 (2007).
References
P.G. Cozzi, Chem. Soc. Rev., 33, 410 (2004).
P.K. Singh and D.N. Kumar, Spectrochim. Acta A, 64, 853 (2006).
E.C. Constable and J.M. Holmes, Inorg. Chim. Acta, 126, 195 (1987).
M.K. Singh,A. Das and B. Paul, Transition Met. Chem., 30, 655 (2005).
B.S. Garg, P.K. Singh and J.L. Sharma, Synth. React. Inorg. Met. Org. Chem., 30, 803 (2000).
J.E. Sprietsma, Med. Hypotheses, 52, 529 (1999).
F.A. Cary, Organic Chemistry, University of Virginia, Tata McGraw Hill, p. 1109 (2003).
L. Martinez, R.F. Farias and C. Airoldi, Thermchim. Acta, 395, 21 (2003).
B.D. Berezin and G.M. Mamardashvili, Russ. J. Coord. Chem., 28, 771 (2002).
A.S.A. Zidan, J. Thermal Anal. Calorim., 68, 1045 (2002).
O.P. Slyudkin and A.A. Tulupov, Russ. J. Coord. Chem., 31, 77 (2005).
N.P. Kryukova, F.A. Kolokolov, S.V. Bolotin and V.T. Panyushkin, Russ. J. Gen. Chem., 75, 503 (2005).
A. Stanila, A. Marcu, D. Rusu, M. Rusu and L. David, J. Mol. Struct., 834-836, 364 (2007).