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Major and Trace Element Geochemistry of Bauxites of Ayranci, Karaman, Central Bolkardag, Turkey
Corresponding Author(s) : M. Gurhan Yalcin
Asian Journal of Chemistry,
Vol. 25 No. 5 (2013): Vol 25 Issue 5
Abstract
Central Bolkardag (Ayranci, Kucukkoras-Karaman) bauxites are one of the most important bauxite sources of the central Taurus zone. The aim of this study was to determine geological features and major and trace elements of Kucukkoras bauxites based on geochemical data from the bauxite deposits and rocks. To this aim, geochemical features of the region were investigated, a detailed map of the bauxite sites was drawn and chemical analyses of the collected specimens were made with inductively coupled plasma/mass spectrometry (ICP-MS). Kucukkoras diasporic bauxite deposits were located in Jurassicu-upper cretaceous aged uctepeler formation, were formed in the upper cretaceous period, extended in the NW-SE direction and were composed of three types of ores; i.e. lenses, karstic fills (sinkhole fills) and veins. Bauxites were found to have the following major oxides: SiO2 of 3.2005 %, Al2O3 of 57.7080 %, Fe2O3 of 23.365 %, MgO of 0.1035 %, CaO of 0.3290 %, Na2O of 0.0800 %, K2O of 0.0960 %, TiO2 of 3.1385 %, P2O5 of 0.0580 %, MnO of 0.1445 % and CrO3 of 0.5430 %. Based on the Al2O3/SiO2 ratio of bauxites, the mean module value was found to be 18.04, which indicates that Kucukkoras bauxites were the highest quality bauxites. Geochemical data showed that the bauxites were formed as a result of conversion of limestone into terra rossa and then conversion of terra rossa into bauxite.
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- H. Helke, Maden Tetkik Arama, 398 (1929) (In Turkish).
- M.M. Blumenthal, Maden Tetkik Arama, 7, 179 (1956) (In Turkish).
- N. Ozgul, Turkiye Jeol. Kur. Bult., 14, 85 (1971) (In Turkish).
- N. Ozgul, Turkiye Jeol. Kur. Bult., 19, 65 (1976) (In Turkish).
- N. Ozgul, Maden Tetkik Arama, 119, 113 (1997) (In Turkish).
- E. Demirtasli, A.Z. Bilgin, M. Selim and N. Turhan, Maden Tetkik Arama, Geol. Taurus Belt Symp., pp. 125-143 (1983) (In Turkish).
- E. Demirtasli, A.Z. Bilgin and N. Turhan, Maden Tetkik Arama, 8097, 1 (1986) (In Turkish).
- S. Pampal, Gazi Univ. Muh. Mim. Fak. Derg., 2, 99 (1987) (In Turkish).
- G. Ralli, Maden Tetkik Arama, 386, 1 (1938) (In Turkish).
- F. Calapkulu, TUBITAK IV. Bilim Kong., Temel Bil. Seksiyonu, pp. 99-110 (1977) (In Turkish).
- E. Gunalay, Maden Tetkik ve Arama Enst. Rap., 3865, 1 (1966) (In Turkish).
- B. Sevgil, Maden Tetkik Arama, 514, 1 (1984) (In Turkish).
- J. Wippern, Maden Tetkik Arama, 58, 47 (1962) (In Turkish).
- O. Baysal and A.N. Engin, Yerbilimleri Derg., Hacettepe Univ., 2, 140 (1976).
- A. Cagatay and B. Arman, Jeol. Muh. Oda., 14, 23 (1982).
- S. Koc and M.A. Deger, Maden Tetkik Arama, 113, 115 (1991).
- M.M. 1991 and E. Goksu, Maden Tetkik Arama, 14, 59 (1949).
- E. Goksu, Turkiye Jeol. Kur. Bult., 4, 79 (1953).
- S. Temur, Nobel Tayin Dagitim, Ankara, pp. 1-285 (2001).
- F. Broviczeny, Maden Tetkik Arama, 1124, 1 (1962).
- S. Temur, M.M. Karadag, F. Arik and A. Ozturk, Selcuk Univ. Aras. Fonu. Projesi., 2000/075, 1 (2002).
- M.G. Yalcin, S. Temur and I. Copuroglu, Nigde Univ. Arastirma Fonu Projesi., FEB 2004/06, pp. 1-130 (2005).
- G. Kansun, S. Temur, I. Copuroglu and M.G. Yalcin, KTU 40. Yil Jeoloji Sempozyumu, Bildiri Ozleri, pp. 124-125 (2005).
- S. Ilhan, Nigde Universitesi, Fenbilimleri Ens., Yuksek Lisans Tezi, pp. 1-96 (2006).
- M. Selim and E. Demirtasli, Maden Tetkik Arama, 60, 1 (1984).
- R.L. Folk, Petrology of sedimentary rocks; Hemphill's Austin, Texas, pp. 1-325 (1968).
- E. Demirtasli, A.Z. Bilgin, F. Erenler, S. Isiklar, D.Y. Sanli, M. Selim and N. Turhan, Maden Tetkik Arama, 12, 42 (1973).
- A. Gumus, Icolaylara Bagli Maden Yataklari; Bilim Pfts, Izmir, pp. 1-481 (1998).
- Acme, 2005, www.acmelab.com
- A.W. Rose, H.E. Hawkes and J.S. Web, Geochemistry in Mineral Exploration, Academic Pr, New York, pp. 1-657 (1979).
- A. Evans, An Introduction to Oregeology; Blackwell Sci. Publ., Oxford, edn. 2, 1-358 (1987).
- K. Bloomfield, J.H. Reedman and J. Tether, Toronto Symposium, 85, 102 (1971).
- W.B. Clarke and G. Kugler, Econ. Geol., 68, 243 (1973).
- R.B. Ferguson and V. Price, J. Geochem. Explor., 6, 103 (1976).
- I. Voros, Definition of Bauxites; Prinnciples and Methods of Bauxite Prospecting, Aluteru-Fki's, Printig Slop, pp. 1-7 (1979).
- S. Temur and G. Kansun, J. Asian Earth Sci., 27, 1 (2006).
References
H. Helke, Maden Tetkik Arama, 398 (1929) (In Turkish).
M.M. Blumenthal, Maden Tetkik Arama, 7, 179 (1956) (In Turkish).
N. Ozgul, Turkiye Jeol. Kur. Bult., 14, 85 (1971) (In Turkish).
N. Ozgul, Turkiye Jeol. Kur. Bult., 19, 65 (1976) (In Turkish).
N. Ozgul, Maden Tetkik Arama, 119, 113 (1997) (In Turkish).
E. Demirtasli, A.Z. Bilgin, M. Selim and N. Turhan, Maden Tetkik Arama, Geol. Taurus Belt Symp., pp. 125-143 (1983) (In Turkish).
E. Demirtasli, A.Z. Bilgin and N. Turhan, Maden Tetkik Arama, 8097, 1 (1986) (In Turkish).
S. Pampal, Gazi Univ. Muh. Mim. Fak. Derg., 2, 99 (1987) (In Turkish).
G. Ralli, Maden Tetkik Arama, 386, 1 (1938) (In Turkish).
F. Calapkulu, TUBITAK IV. Bilim Kong., Temel Bil. Seksiyonu, pp. 99-110 (1977) (In Turkish).
E. Gunalay, Maden Tetkik ve Arama Enst. Rap., 3865, 1 (1966) (In Turkish).
B. Sevgil, Maden Tetkik Arama, 514, 1 (1984) (In Turkish).
J. Wippern, Maden Tetkik Arama, 58, 47 (1962) (In Turkish).
O. Baysal and A.N. Engin, Yerbilimleri Derg., Hacettepe Univ., 2, 140 (1976).
A. Cagatay and B. Arman, Jeol. Muh. Oda., 14, 23 (1982).
S. Koc and M.A. Deger, Maden Tetkik Arama, 113, 115 (1991).
M.M. 1991 and E. Goksu, Maden Tetkik Arama, 14, 59 (1949).
E. Goksu, Turkiye Jeol. Kur. Bult., 4, 79 (1953).
S. Temur, Nobel Tayin Dagitim, Ankara, pp. 1-285 (2001).
F. Broviczeny, Maden Tetkik Arama, 1124, 1 (1962).
S. Temur, M.M. Karadag, F. Arik and A. Ozturk, Selcuk Univ. Aras. Fonu. Projesi., 2000/075, 1 (2002).
M.G. Yalcin, S. Temur and I. Copuroglu, Nigde Univ. Arastirma Fonu Projesi., FEB 2004/06, pp. 1-130 (2005).
G. Kansun, S. Temur, I. Copuroglu and M.G. Yalcin, KTU 40. Yil Jeoloji Sempozyumu, Bildiri Ozleri, pp. 124-125 (2005).
S. Ilhan, Nigde Universitesi, Fenbilimleri Ens., Yuksek Lisans Tezi, pp. 1-96 (2006).
M. Selim and E. Demirtasli, Maden Tetkik Arama, 60, 1 (1984).
R.L. Folk, Petrology of sedimentary rocks; Hemphill's Austin, Texas, pp. 1-325 (1968).
E. Demirtasli, A.Z. Bilgin, F. Erenler, S. Isiklar, D.Y. Sanli, M. Selim and N. Turhan, Maden Tetkik Arama, 12, 42 (1973).
A. Gumus, Icolaylara Bagli Maden Yataklari; Bilim Pfts, Izmir, pp. 1-481 (1998).
Acme, 2005, www.acmelab.com
A.W. Rose, H.E. Hawkes and J.S. Web, Geochemistry in Mineral Exploration, Academic Pr, New York, pp. 1-657 (1979).
A. Evans, An Introduction to Oregeology; Blackwell Sci. Publ., Oxford, edn. 2, 1-358 (1987).
K. Bloomfield, J.H. Reedman and J. Tether, Toronto Symposium, 85, 102 (1971).
W.B. Clarke and G. Kugler, Econ. Geol., 68, 243 (1973).
R.B. Ferguson and V. Price, J. Geochem. Explor., 6, 103 (1976).
I. Voros, Definition of Bauxites; Prinnciples and Methods of Bauxite Prospecting, Aluteru-Fki's, Printig Slop, pp. 1-7 (1979).
S. Temur and G. Kansun, J. Asian Earth Sci., 27, 1 (2006).