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Synthesis and Characteristic of Organic-Inorganic Hybrid Materials Cu2(OH)(4-x)(C10H17O2)x·zH2O
Corresponding Author(s) : Deshan Zheng
Asian Journal of Chemistry,
Vol. 25 No. 5 (2013): Vol 25 Issue 5
Abstract
In this paper, the ligand 3,7-dimethyl-6-octenoic acid was grafted in the inorganic groups layered hydroxy copper acetate through an anion exchange reaction. Combination of XRD, elemental analysis and TGA, the structure of these hybrid materials have been studied and characterized. The infrared, ultraviolet properties and magnetic spectra of these hybrid materials also discussed.
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- B.C. Wu, C.C. Zhang and W.G. Zhang, Organic-Inorganic Hybrid Materials and Applications, Chemical Industry Press, Beijing, pp. 5-286 (2005).
- M.C. Hong, Chin. J. Inorg. Chem., 1, 24 (2002).
- A. Gabashvili, D.D. Medina,A. Gedanken and Y. Mastai, J. Phys. Chem. B, 111, 11105 (2007).
- B.F.G. Johnson, S.A. Raynor, D.S. Shephard, T. Mashmeyer, J.M. Thomas, G. Sankar, S. Bromley, R. Oldroyd, L. Gladden and M. D.. Mantle, Chem. Commun., 1167 (1999).
- S. Fireman-Shoresh, I. Popov, D. Avnir and S. Marx, J. Am. Chem. Soc., 127, 2650 (2005).
- I. Hodgkinson and Q.H. Wu, Adv. Mater., 13, 889 (2001).
- Z.H. Nie, A. Petukhova and E. Kumacheva, Nat. Nanotechnol., 5, 15 (2010).
- N.A. Kotov and F. Stellacci, Adv. Mater., 20, 4221 (2008).
- C.L. Chen and N.L. Rosi, Angew. Chem. Int. Ed., 49, 1924 (2010).
- A. Rujiwatra, C.J. Kepert, J.B. Claridge, M.J. Rosseinsky, H. Kumagai and M. Kurmoo, J. Am. Chem. Soc., 123, 10584 (2001).
- H. Shimizu, M. Okubo, A. Nakamoto, M. Enomoto, N. Kojima, Inorg. Chem., 45, 10240 (2006).
- G.L.J.A. Rikken and E. Raupach, Nature, 390, 493 (1997).
- G.L.J.A. Rikken and E. Raupach, Nature, 405, 932 (2000).
- L.D. Barron, Nature, 405, 895 (2000).
- N.S. Ovanesyan, V.D. Makhaev, S.M. Aldoshin, P. Gredin, K. Boubekeur, C. Train and M. Gruselle, Dalton Trans., 18, 3101 (2005).
- A. Beghidja, G. Rogez, P. Rabu, R. Welter and M. Drillon, J. Mater. Chem., 16, 2715 (2006).
- X. Meng, C. Qin, X. L. Wang, Z.M. Su, B. Li and Q.H. Yang, Dalton Trans., 40, 9964 (2011).
- M. Minguet, D. Luneau, E. Lhotel, V. Villar, C. Paulsen, D.B. Amabilino and J. Veciana, Angew. Chem. Int. Ed., 41, 586 (2002).
- K. Inoue, H. Imai, P.S. Ghalsasi, K. Kikuchi, M. Ohba, H. O-kawa and J.V. Yakhmi, Angew. Chem. Int. Ed., 40, 4242 (2001).
- V. Laget, M. Drillon, C. Hornick, P. Rabu, F. Romero, P. Turek, R. Ziessel, J. Alloys Comp., 262-263, 423 (1997).
- V. Laget, C. Hornick, P. Rabu and M. Drillon, J. Mater. Chem., 9, 169 (1999).
- V. Laget, C. Hornick, P. Rabu, M. Drillon and R. Ziessel, Coord. Chem. Rev., 178-180, 1533 (1998).
- C. Hornick, P. Rabu and M. Drillon, Polyhedron, 19, 259 (2000).
- J.M. Rueff, J.F. Nierengarten, P. Gilliot, A. Demessence, O. Cregut, M. Drillon and P. Rabu, Chem. Mater., 16, 2933 (2004).
- M. Dixit, G.N. Subbanna and P.V. Kamath, J. Mater. Chem., 6, 1429 (1996).
- F. Cavani and F. Trifiro, Catal. Today, 11, 173 (1991).
- R.S. Jayashree and P.V. Kamath, J. Mater. Chem., 9, 961 (1999).
- Y. Zhu, H. Li, Y. Koltypin and A. Gedanken, J. Mater. Chem., 12, 729 (2002).
- A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, edn. 2 (1984).
- K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons, New York, edn. 4, pp. 124-232 (1986).
- H.C. Zeng, Z.P. Xu and M. Qian, Chem. Mater., 10, 2277 (1998).
- K. Suzuki, J. Haines, P. Rabu, K. Inoue and M. Drillon, J. Phys. Chem. C, 112, 19147 (2008).
- O. Kahn, Molecular Magnetism, VCH Publishers, Weinheim (1993).
References
B.C. Wu, C.C. Zhang and W.G. Zhang, Organic-Inorganic Hybrid Materials and Applications, Chemical Industry Press, Beijing, pp. 5-286 (2005).
M.C. Hong, Chin. J. Inorg. Chem., 1, 24 (2002).
A. Gabashvili, D.D. Medina,A. Gedanken and Y. Mastai, J. Phys. Chem. B, 111, 11105 (2007).
B.F.G. Johnson, S.A. Raynor, D.S. Shephard, T. Mashmeyer, J.M. Thomas, G. Sankar, S. Bromley, R. Oldroyd, L. Gladden and M. D.. Mantle, Chem. Commun., 1167 (1999).
S. Fireman-Shoresh, I. Popov, D. Avnir and S. Marx, J. Am. Chem. Soc., 127, 2650 (2005).
I. Hodgkinson and Q.H. Wu, Adv. Mater., 13, 889 (2001).
Z.H. Nie, A. Petukhova and E. Kumacheva, Nat. Nanotechnol., 5, 15 (2010).
N.A. Kotov and F. Stellacci, Adv. Mater., 20, 4221 (2008).
C.L. Chen and N.L. Rosi, Angew. Chem. Int. Ed., 49, 1924 (2010).
A. Rujiwatra, C.J. Kepert, J.B. Claridge, M.J. Rosseinsky, H. Kumagai and M. Kurmoo, J. Am. Chem. Soc., 123, 10584 (2001).
H. Shimizu, M. Okubo, A. Nakamoto, M. Enomoto, N. Kojima, Inorg. Chem., 45, 10240 (2006).
G.L.J.A. Rikken and E. Raupach, Nature, 390, 493 (1997).
G.L.J.A. Rikken and E. Raupach, Nature, 405, 932 (2000).
L.D. Barron, Nature, 405, 895 (2000).
N.S. Ovanesyan, V.D. Makhaev, S.M. Aldoshin, P. Gredin, K. Boubekeur, C. Train and M. Gruselle, Dalton Trans., 18, 3101 (2005).
A. Beghidja, G. Rogez, P. Rabu, R. Welter and M. Drillon, J. Mater. Chem., 16, 2715 (2006).
X. Meng, C. Qin, X. L. Wang, Z.M. Su, B. Li and Q.H. Yang, Dalton Trans., 40, 9964 (2011).
M. Minguet, D. Luneau, E. Lhotel, V. Villar, C. Paulsen, D.B. Amabilino and J. Veciana, Angew. Chem. Int. Ed., 41, 586 (2002).
K. Inoue, H. Imai, P.S. Ghalsasi, K. Kikuchi, M. Ohba, H. O-kawa and J.V. Yakhmi, Angew. Chem. Int. Ed., 40, 4242 (2001).
V. Laget, M. Drillon, C. Hornick, P. Rabu, F. Romero, P. Turek, R. Ziessel, J. Alloys Comp., 262-263, 423 (1997).
V. Laget, C. Hornick, P. Rabu and M. Drillon, J. Mater. Chem., 9, 169 (1999).
V. Laget, C. Hornick, P. Rabu, M. Drillon and R. Ziessel, Coord. Chem. Rev., 178-180, 1533 (1998).
C. Hornick, P. Rabu and M. Drillon, Polyhedron, 19, 259 (2000).
J.M. Rueff, J.F. Nierengarten, P. Gilliot, A. Demessence, O. Cregut, M. Drillon and P. Rabu, Chem. Mater., 16, 2933 (2004).
M. Dixit, G.N. Subbanna and P.V. Kamath, J. Mater. Chem., 6, 1429 (1996).
F. Cavani and F. Trifiro, Catal. Today, 11, 173 (1991).
R.S. Jayashree and P.V. Kamath, J. Mater. Chem., 9, 961 (1999).
Y. Zhu, H. Li, Y. Koltypin and A. Gedanken, J. Mater. Chem., 12, 729 (2002).
A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, edn. 2 (1984).
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons, New York, edn. 4, pp. 124-232 (1986).
H.C. Zeng, Z.P. Xu and M. Qian, Chem. Mater., 10, 2277 (1998).
K. Suzuki, J. Haines, P. Rabu, K. Inoue and M. Drillon, J. Phys. Chem. C, 112, 19147 (2008).
O. Kahn, Molecular Magnetism, VCH Publishers, Weinheim (1993).