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Comparison of Steam Explosion and Ferric Chloride Solution Pretreatment of Corn Stover: Composition Content, Structural and Enzymatic Hydrolysis
Corresponding Author(s) : Y.L. Wang
Asian Journal of Chemistry,
Vol. 25 No. 5 (2013): Vol 25 Issue 5
Abstract
The efficiency of two lignocellulose pretreatment technologies, steam explosion and ferric chloride solution pretreatment, are compared in terms of composition, structural and enzymatic efficiency with corn stover. Ferric chloride solution pretreatment could easily remove almost all of the hemicelluloses and gain high enzymatic hydrolysis compared with steam explosion, but they both have no effect on delignification and reduced cellulose crystalline. Pretreated material was investigated by X-ray diffraction, scanning electron microscopy and Fourier transform infrared spectroscopy. These results suggested that ferric chloride solution pretreatment may own huge advantages compared to the steam explosion pretreatment process for corn stover. However, the recovery of the ferric chloride solution should also be paid more attention.
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- A.V. Bridgwater amd G. Grassi, Biomass Pyrolysis Liquids Upgrading and Utilization, Elsevier Applied Science, London (1991).
- G. Grassi, G. Gosse and G. dos Santos, Biomass for Energy and Industry, Elsevier Applied Science, London (1990).
- IEA, World Energy Outlook, OECD/IEA (2008).
- J.D. Broder, J.W. Barrier, K.P. Lee and M.M. Bulls, World Resour. Rev., 7, 560 (1995).
- R.D. Perlack, L.L. Wright, A. Turhollow, R.L. Graham, B. Stokes and D.C. Erbach, Biomass as Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply, Oar Ridge National Laboratory, ORNL/TM-2005/66, US Dept. of Energy, Oak Ridge (2005).
- G. Garrote, H. Dominguez and J.C. Parajó, J. Chem. Technol. Biotechnol., 74, 1101 (1999).
- K. Grohmann, R. Torget and M. Himmel, Biotechnol. Bioeng. Symp., 15, 59 (1985).
- T.A. Lloyd and C.E. Wyman, Bioresour. Technol., 96, 1967 (2005).
- D. Schell, J. Farmer, M. Newman and J. McMillan, Appl. Biochem. Biotechnol., 105-108, 69 (2003).
- V.S. Chang, B. Burr and M.T. Holtzapple, Appl. Biochem. Biotechnol., 63-65, 3 (1997).
- S. Singh, B.A. Simmons and K.P. Vogel, Biotechnol. Bioeng., 104, 68 (2009).
- D. Ben-Ghedalia and J. Miron, Biotechnol. Bioeng., 23, 823 (1981).
- W.J. Connors, L.N. Johanson, K.V. Sarkanen and P. Winslow, Holzforschung, 34, 29 (1980).
- Y.H.P. Zhang, S.Y. Ding, J.R. Mielenz, J.B. Cui, R.T. Elander, M. Laser, M.E. Himmel, J.R. McMillan and L.R. Lynd, Biotechnol. Bioeng., 97, 214 (2007).
- B.M. Cherian, L.A. Pothan, T.N. Chung, G. Mennig, M. Kottaisamy and S. Thomas, J. Agric. Food Chem., 56, 5617 (2008).
- S. Fischer, W. Voigt and K. Fischer, Cellulose, 6, 213 (1999).
- H. Leipner, S. Fischer, E. Brendler and W. Voigt, Macromol. Chem. Phys., 201, 2041 (2000).
- S. Fischer, H. Leipner, E. Brendler, W. Voigt and K. Fischer, ACS Symp. Ser., 737, 143 (1999).
- G.L. Miller, Anal. Chem., 31, 426 (1959).
- L. Segal, J.J. Creely, A.E. Martin Jr. and C.M. Conrad, Textile Res. J., 29, 786 (1959).
- R. Kumar, G. Mago, V. Balan and C.E. Wyman, Bioresour. Technol., 100, 3948 (2009).
- A.P. Dadi, C.A. Schall and S. Varanasi, Appl. Biochem. Biotechnol., 137, 407 (2007).
- R. Kumar, G. Mago, V. Balan and C.E. Wyman, Bioresour. Technol., 100, 3948 (2009).
References
A.V. Bridgwater amd G. Grassi, Biomass Pyrolysis Liquids Upgrading and Utilization, Elsevier Applied Science, London (1991).
G. Grassi, G. Gosse and G. dos Santos, Biomass for Energy and Industry, Elsevier Applied Science, London (1990).
IEA, World Energy Outlook, OECD/IEA (2008).
J.D. Broder, J.W. Barrier, K.P. Lee and M.M. Bulls, World Resour. Rev., 7, 560 (1995).
R.D. Perlack, L.L. Wright, A. Turhollow, R.L. Graham, B. Stokes and D.C. Erbach, Biomass as Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply, Oar Ridge National Laboratory, ORNL/TM-2005/66, US Dept. of Energy, Oak Ridge (2005).
G. Garrote, H. Dominguez and J.C. Parajó, J. Chem. Technol. Biotechnol., 74, 1101 (1999).
K. Grohmann, R. Torget and M. Himmel, Biotechnol. Bioeng. Symp., 15, 59 (1985).
T.A. Lloyd and C.E. Wyman, Bioresour. Technol., 96, 1967 (2005).
D. Schell, J. Farmer, M. Newman and J. McMillan, Appl. Biochem. Biotechnol., 105-108, 69 (2003).
V.S. Chang, B. Burr and M.T. Holtzapple, Appl. Biochem. Biotechnol., 63-65, 3 (1997).
S. Singh, B.A. Simmons and K.P. Vogel, Biotechnol. Bioeng., 104, 68 (2009).
D. Ben-Ghedalia and J. Miron, Biotechnol. Bioeng., 23, 823 (1981).
W.J. Connors, L.N. Johanson, K.V. Sarkanen and P. Winslow, Holzforschung, 34, 29 (1980).
Y.H.P. Zhang, S.Y. Ding, J.R. Mielenz, J.B. Cui, R.T. Elander, M. Laser, M.E. Himmel, J.R. McMillan and L.R. Lynd, Biotechnol. Bioeng., 97, 214 (2007).
B.M. Cherian, L.A. Pothan, T.N. Chung, G. Mennig, M. Kottaisamy and S. Thomas, J. Agric. Food Chem., 56, 5617 (2008).
S. Fischer, W. Voigt and K. Fischer, Cellulose, 6, 213 (1999).
H. Leipner, S. Fischer, E. Brendler and W. Voigt, Macromol. Chem. Phys., 201, 2041 (2000).
S. Fischer, H. Leipner, E. Brendler, W. Voigt and K. Fischer, ACS Symp. Ser., 737, 143 (1999).
G.L. Miller, Anal. Chem., 31, 426 (1959).
L. Segal, J.J. Creely, A.E. Martin Jr. and C.M. Conrad, Textile Res. J., 29, 786 (1959).
R. Kumar, G. Mago, V. Balan and C.E. Wyman, Bioresour. Technol., 100, 3948 (2009).
A.P. Dadi, C.A. Schall and S. Varanasi, Appl. Biochem. Biotechnol., 137, 407 (2007).
R. Kumar, G. Mago, V. Balan and C.E. Wyman, Bioresour. Technol., 100, 3948 (2009).