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Synthesis and Structure of a Three-Dimensional Mn(COO)3 Anionic Framework
Corresponding Author(s) : Zhiqiang Jiang
Asian Journal of Chemistry,
Vol. 25 No. 4 (2013): Vol 25 Issue 4
Abstract
Manganese-crystallization of formic acid from the decomposition of N,N-dimethylformamide solvent was synthesized and characterized by single-crystal X-ray diffraction. This compound crystallized in a hexagonal space group of R-3c with a = b = 8.3319(5) Å, c = 22.851(2) Å, a = b = 90.00º, l = 120.00º, V = 1373.81(17) Å3 and Z = 2. This compound possessed 6-connected three-dimensional Mn(COO)3 anionic framework.
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References
B.F. Hoskins and R. Robson, J. Am. Chem. Soc., 111, 5962 (1989).
O.M. Yaghi, M. O'Keeffe, N.W. Ockwig, H.K. Chae, M. Eddaoudi and J. Kim, Nature, 423, 705 (2003).
S. Kitagawa, R. Kitaura and S. Noro, Angew. Chem. Int. Ed., 43, 2334 (2004).
M.J. Rosseinsky, Micropor. Mesopor. Mater., 73, 15 (2004).
G. Ferey, C. Mellot-Draznieks, C. Serre and F. Millange, Acc. Chem. Res., 38, 217 (2005).
K.O. Kongshaug and H. Fjellvag, Polyhedron, 26, 5113 (2007).
X.M. Lu, P.Z. Li, X.T. Wang, S. Gao, X.J. Wang, S. Wang, Y.H. Deng, Y.J. Zhang and L. Zhou, Polyhedron, 27, 2402 (2008).
C.B. Tian, Z.Z. He, Z.H. Li, P. Lin and S.W. Du, Cryst. Eng. Comm., 13, 3080 (2011).
G.M. Sheldrick, SADABS, Program for Area Detector Adsorption Correction; Institute for Inorganic Chemistry, University of Göttingen: Göttingen, Germany (1996).
G.M. Sheldrick, SHELXL-97, Program for Solution of Crystal Structures; University of Göttingen: Göttingen, Germany (1997).