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Vol. 25 No. 4 (2013): Vol 25 Issue 4

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Synthesis of Controllable Imidazole Based Partly Ionic-Liquid Polymers

https://doi.org/10.14233/ajchem.2013.13363
Zhen Jiao
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, Jiangsu Province, P.R. China
Xinglong Fang
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, Jiangsu Province, P.R. China

Corresponding Author(s) : Zhen Jiao

jiao.zh@gmail.com

Asian Journal of Chemistry, Vol. 25 No. 4 (2013): Vol 25 Issue 4

Abstract

The ionic-liquid polymers, p[vbim][PF6], based on the conventional ionic liquid and the ones, p[vpNH2im][PF6], based on the task-specific ionic liquid have been synthesized. The ionic-liquid-structure segment mole fraction of the polymers could be controlled by adjusting the reactants' mole fraction. The ionized segment fractions in p[vmim]PF6 were 19.7, 38.5 and 85.0 % at the condition of the mole fractions of 1-bromobutane to imidazole unit in the reaction mixture were 0.2, 0.5 and 1.2, respectively. And the latter was 78.1 % at 3-bromopropylamine hydrobromide to imidazole unit in the reaction mixture was 1.2. Thermal analysis indicated that the polymers had good thermal stability and the grafted chain had little effects on the polymer's glass transition temperatures.

Keywords

Ionic-liquided polymer Synthesis Carbon dioxide
Jiao, Z., & Fang, X. (2012). Synthesis of Controllable Imidazole Based Partly Ionic-Liquid Polymers. Asian Journal of Chemistry, 25(4), 2143–2145. https://doi.org/10.14233/ajchem.2013.13363
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References
  1. T. Welton, Chem. Rev., 99, 2071 (1999).
  2. P. Wasserscheid and W. Keim, Angew. Chem.-Int. Ed., 39, 3772 (2000).
  3. M. Watanabe, S. Yamada and N. Ogata, Electrochim. Acta, 40, 2285 (1995).
  4. R. Marcilla, J.A. Blazquez, J. Rodriguez, J.A. Pomposo and D. Mecerreyes, J. Polym. Sci. Part A, 42, 208 (2004).
  5. H. Ohno and K. Ito, Chem. Lett., 751-752 (1998).
  6. M. Yoshizawa and H. Ohno, Chem. Lett., 889-890 (1999).
  7. H. Ohno, Electrochimica Acta, 46, 1407 (2001).
  8. M. Yoshizawa and H. Ohno, Electrochimica Acta, 46, 1723 (2001).
  9. W. Ogihara, S. Washiro, H. Nakajima and H. Ohno, Electrochim. Acta, 51, 2614 (2006).
  10. J.B. Tang, H.D. Tang, W.L. Sun, M. Radosz and Y.Q. Shen, Polymer, 46, 12460 (2005).
  11. J.B. Tang, W.L. Sun, H.D. Tang, M. Radosz and Y.Q. Shen, Macromolecules, 38, 2037 (2005).
  12. J.B. Tang, H.D. Tang, W.L. Sun, H. Plancher, M. Radosz and Y.Q. Shen, Chem. Commun., 3325-3327 (2005).
  13. X. Hu, J. Tang, A. Blasig, Y. Shen and M. Radosz, J. Memb. Sci., 281, 130 (2006).
  14. Y.-Y. Jiang, G.-N. Wang, Z. Zhou, Y.-T. Wu, J. Geng and Z.-B. Zhang, Chem. Commun., 505-507 (2008).
  15. H. Yu, Y.-T. Wu, Y.-Y. Jiang, Z. Zhou and Z.-B. Zhang, New J. Chem., 33, 2385 (2009).
  16. G. Wang, W. Hou, F. Xiao, J. Geng, Y. Wu and Z. Zhang, J. Chem. Engg. Data, 56, 1125 (2011).
  17. A. Chapiro and Z. Mankowski, Eur. Polym. J., 24, 1019 (1988).
  18. N.P. Sen, Can. J. Chem., 40, 2189 (1962).
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