Kinetic Study of Cr(III) and Cr(VI) Biosorption Using Rosa damascena Phytomass: A Rose Waste Biomass

M. Jamshaid Iqbal; Farhan Cecil; Khalil Ahmad; Munawar Iqbal; M. Mustaq; M.A. Naeem; T.H. Bukhari

doi:10.14233/ajchem.2013.13345

Issue

Vol. 25 No. 4 (2013): Vol 25 Issue 4

Issue Published : November 1, 2012

This work is licensed under a Creative Commons Attribution 4.0 International License.

Kinetic Study of Cr(III) and Cr(VI) Biosorption Using Rosa damascena Phytomass: A Rose Waste Biomass

https://doi.org/10.14233/ajchem.2013.13345

M. Jamshaid Iqbal

Department of Chemistry and Biochemistry, University of Agriculture, Faisalabad-38040, Pakistan

Farhan Cecil

Department of Chemistry and Biochemistry, University of Agriculture, Faisalabad-38040, Pakistan

Khalil Ahmad

Department of Chemistry, The University of Faisalabad, Faisalabad, Pakistan

Munawar Iqbal

Department of Chemistry and Biochemistry, University of Agriculture, Faisalabad-38040, Pakistan

M. Mustaq

Department of Chemistry and Biochemistry, University of Agriculture, Faisalabad-38040, Pakistan

M.A. Naeem

Department of Physics, University of Agriculture, Faisalabad-38040, Pakistan

T.H. Bukhari

Department of Chemistry, Government College University, Faisalabad, Pakistan

Corresponding Author(s) : M. Jamshaid Iqbal

jimychemist@hotmail.com

Asian Journal of Chemistry, Vol. 25 No. 4 (2013): Vol 25 Issue 4
Article Published : November 1, 2012

Abstract

In present study, Cr(III) and Cr(VI) sorption capacity of Rosa damascena phytomass from aqueous solution was evaluated. The R. damascena phytomass biosorption revealed that smaller biosorbent size (< 0.4 g), dose (< 0.1 g), pH (2 and 5 for Cr VI and III) and 100 mg L^-1 initial metal concentration were more suitable for better biosorption from aqueous medium. The Langmuir isotherm model and pseudo second order kinetic model fitted well to the data of Cr(III) and Cr(VI) biosorption. The negative value of Gibbs free energy (DGº) indicated the spontaneous absorption process. The R. damascena biomass pre-treatment enhanced biosorption considerably and it is concluded that the R. damascena biomass (waste material) might be used for biosorption of Cr(III) and Cr(VI) from aqueous solution.

Keywords

Chromium removal Langmuir isotherm Absorption kinetic damascena phytomass R

Jamshaid Iqbal, M., Cecil, F., Ahmad, K., Iqbal, M., Mustaq, M., Naeem, M., & Bukhari, T. (2012). Kinetic Study of Cr(III) and Cr(VI) Biosorption Using Rosa damascena Phytomass: A Rose Waste Biomass. Asian Journal of Chemistry, 25(4), 2099–2103. https://doi.org/10.14233/ajchem.2013.13345

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References

M. Riaz, R. Nadeem, M.A. Hanif, T.M. Ansari and K. Rehman, J. Hazard. Mater., 161, 88 (2010).
F. Akbal and S. Camci, Desalination, 269, 214 (2011).
K.C. Sekhar, C.T. Kamala, N.S. Chary and Y. Anjaneyulu, Int. J. Miner. Process., 68, 37 (2003).
G. Bayramoglu, I. Tuzun, G. Celik, M. Yilmaz and M.Y. Arica, Int. J. Miner. Process., 81, 35 (2006).
T. Chaisuwan, T. Komalwanich, S. Luangsukrerk and S. Wongkasemjit, Desalination, 256, 108 (2010).
M. Kilic, M.E. Keskin, S. Mazlum and N. Mazlum, Int. J. Miner. Process., 87, 1 (2008).
A. Nasreen, I. Muhammad, Z.S. Iqbal and I. Javed, J. Environ. Sci., 20, 231 (2010).
S. Sohrabnezhad and A. Pourahmad, Desalination, 256, 84 (2010).
R. Vinodh, R. Padmavathi and D. Sangeetha,Desalination, 267, 267 (2011).
A. Witek-Krowiak, R.G. Szafran and S. Modelski, Desalination, 265, 126 (2011).
K.H. Chu and M.A. Hashim, Acta Biotechnol., 2, 295 (2001).
T. Srinath, S.K. Garg and P.W. Ramteke, Ind. J. Exp. Biol., 41, 986 (2003).
M. Horsfall and A. Spiff, Afr. J. Biotechnol., 4, 191 (2005).
M.A. Hanif, R. Nadeem, M.N. Zafar, K. Akthar and H.N. Bhatti, J. Hazard. Mater., 145, 501 (2007).
N. Ahalya, R.D. Kanamadi and T.V. Ramachandra, Eur. J. Biotechnol., 8, 258 (2003).
D.M. Manohar, K.A. Krishnan and T.S. Anirudhan, Water Res., 36, 1609 (2002).
G. Yan and T. Viraraghavan, Bioresour. Technol., 78, 243 (2001).
H.N. Bhatti, B. Mumtaz, M.A. Hanif and R. Nadeem, Process Biochem., 42, 547 (2007).
M. Loaec, R. Olier and J. Guezennec, Water Res., 31, 1171 (1997).
E. Fourest, C. Canal and J.C. Roux, FEMS Microbiol. Rev., 14, 325 (1994).
M.T.K. Tsui, K.C. Cheung, N.F.Y. Tam and M.H. Wong, Chemosphere, 65, 51 (2006).
F. Veglio, F. Beolchini, F. Pagnanelli and A.P. Reverberi, Ind. Eng. Chem. Res., 42, 4881 (2003).
R. Gong, Y. Sun, J. Chen, H. Liu and C. Yang, Dyes Pigments, 67, 175 (2005).
K.C. Sekhar, C.T. Kamala, N.S.A. Chary, R.K. Sastry, T.N. Rao and M. Vairamani, J. Hazard. Mater., 108, 111 (2004).

References

M. Riaz, R. Nadeem, M.A. Hanif, T.M. Ansari and K. Rehman, J. Hazard. Mater., 161, 88 (2010).

F. Akbal and S. Camci, Desalination, 269, 214 (2011).

K.C. Sekhar, C.T. Kamala, N.S. Chary and Y. Anjaneyulu, Int. J. Miner. Process., 68, 37 (2003).

G. Bayramoglu, I. Tuzun, G. Celik, M. Yilmaz and M.Y. Arica, Int. J. Miner. Process., 81, 35 (2006).

T. Chaisuwan, T. Komalwanich, S. Luangsukrerk and S. Wongkasemjit, Desalination, 256, 108 (2010).

M. Kilic, M.E. Keskin, S. Mazlum and N. Mazlum, Int. J. Miner. Process., 87, 1 (2008).

A. Nasreen, I. Muhammad, Z.S. Iqbal and I. Javed, J. Environ. Sci., 20, 231 (2010).

S. Sohrabnezhad and A. Pourahmad, Desalination, 256, 84 (2010).

R. Vinodh, R. Padmavathi and D. Sangeetha,Desalination, 267, 267 (2011).

A. Witek-Krowiak, R.G. Szafran and S. Modelski, Desalination, 265, 126 (2011).

K.H. Chu and M.A. Hashim, Acta Biotechnol., 2, 295 (2001).

T. Srinath, S.K. Garg and P.W. Ramteke, Ind. J. Exp. Biol., 41, 986 (2003).

M. Horsfall and A. Spiff, Afr. J. Biotechnol., 4, 191 (2005).

M.A. Hanif, R. Nadeem, M.N. Zafar, K. Akthar and H.N. Bhatti, J. Hazard. Mater., 145, 501 (2007).

N. Ahalya, R.D. Kanamadi and T.V. Ramachandra, Eur. J. Biotechnol., 8, 258 (2003).

D.M. Manohar, K.A. Krishnan and T.S. Anirudhan, Water Res., 36, 1609 (2002).

G. Yan and T. Viraraghavan, Bioresour. Technol., 78, 243 (2001).

H.N. Bhatti, B. Mumtaz, M.A. Hanif and R. Nadeem, Process Biochem., 42, 547 (2007).

M. Loaec, R. Olier and J. Guezennec, Water Res., 31, 1171 (1997).

E. Fourest, C. Canal and J.C. Roux, FEMS Microbiol. Rev., 14, 325 (1994).

M.T.K. Tsui, K.C. Cheung, N.F.Y. Tam and M.H. Wong, Chemosphere, 65, 51 (2006).

F. Veglio, F. Beolchini, F. Pagnanelli and A.P. Reverberi, Ind. Eng. Chem. Res., 42, 4881 (2003).

R. Gong, Y. Sun, J. Chen, H. Liu and C. Yang, Dyes Pigments, 67, 175 (2005).

K.C. Sekhar, C.T. Kamala, N.S.A. Chary, R.K. Sastry, T.N. Rao and M. Vairamani, J. Hazard. Mater., 108, 111 (2004).

Issue

Vol. 25 No. 4 (2013): Vol 25 Issue 4

Kinetic Study of Cr(III) and Cr(VI) Biosorption Using Rosa damascena Phytomass: A Rose Waste Biomass

Corresponding Author(s) : M. Jamshaid Iqbal

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