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Synthesis and Characterization of Partially Hydrolyzed Hydrogel Based on Kappa-Carrageenan
Corresponding Author(s) : Mohammad Sadeghi
Asian Journal of Chemistry,
Vol. 25 No. 3 (2013): Vol 25 Issue 3
Abstract
The polysaccharide, kappa-carrageenan (kC) was chemically modified to achieve a novel super absorbent hydrogel via graft copolymeri-zation of methacrylamide (MAM) onto the substrate followed by alkaline hydrolysis. Ammonium persulfate (APS) and N,N'-methylene bisacrylamide (MBA) were used as a free-radical initiator and a crosslinker, respectively. The saponification reaction was carried out using aqueous solution of sodium hydroxide. Either kC-g-PMAM or hydrolyzed kC-g-PMAM was characterized by FTIR and SEM spectroscopies.
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- F.L. Buchholz and A.T. Graham, Modern Super Absorbent Polymer Technology, Wiley, New York (1997).
- L.B. Peppas and R.S. Harland, Absorbent Polymer Technology, Elsevier, Amsterdam (1990).
- R. Po, J. Macromol. Sci-Rev. Macromol. Chem. Phys., C34, 607 (1994).
- A.S. Hoffman, In ed.: J.C. Salamone, Polymeric Materials Encyclopedia, CRC Press: Boca Raton, FL, Vol. 5, p. 3282 (1996).
- G.F. Fanta, In ed.: J.C. Salamone, Polymeric Materials Encyclopedia, RC Press: Boca Raton, FL, Vol. 10, pp. 7901, 8051 (1996).
- G.M. Patel, C.P. Patel and H.C. Trivedi, Eur. Polym. J., 35, 201 (1999).
- S. Silong and L. Rahman, J. Appl. Polym. Sci., 76, 516 (2000).
- J. Kost, In ed.: E. Mathiowitz, Encyclopedia of Controlled Drug Delivery, Wiley: New York, Vol. 1, p. 445 (1999).
- N.A. Peppas and A.G. Mikes, Hydrogels in Medicine and Pharmacy, CRC Press: Boca Raton, FL, Vol. 1 (1986).
- R.E. Kirk and D.F. Othmer, In eds.: J.I. Kroschwitz and M. Howe-Grant, Encyclopedia of Chemical Technology, John Wiley & Sons: New York, Vol. 4, p. 942 (1992).
- A. Pourjavadi, A.M. Harzandi and H. Hosseinzadeh, Eur. Polym. J., 40, 1363 (2004).
- A. Pourjavadi, H. Ghasemzadeh and H. Hosseinzadeh, Preparation and Swelling Behavior of a Novel Anti-Salt Super absorbent Hydrogel Based on Kappa-Carrageenan and Sodium Alginate Grafted with Polyacrylamide,e-Polymers, No. 027 (2004).
- R.M. Silverstein and F.X. Webster, Spectrometric Identification of Organic Compounds, Wiley, New York, edn. 6 (1998).
- P.J. Flory, Principles of Polymer Chemistry, Ithaca, Cornell University Press, New York (1953).
- W.F. Lee and G.H. Lin, J. Appl. Polym. Sci., 79, 1665 (2001).
- V.D. Athawale and V. Lele, Carbohydr. Polym., 35, 21 (1998).
- V.D. Athawale and V. Lele, Starch/Starke, 50, 426 (1998).
References
F.L. Buchholz and A.T. Graham, Modern Super Absorbent Polymer Technology, Wiley, New York (1997).
L.B. Peppas and R.S. Harland, Absorbent Polymer Technology, Elsevier, Amsterdam (1990).
R. Po, J. Macromol. Sci-Rev. Macromol. Chem. Phys., C34, 607 (1994).
A.S. Hoffman, In ed.: J.C. Salamone, Polymeric Materials Encyclopedia, CRC Press: Boca Raton, FL, Vol. 5, p. 3282 (1996).
G.F. Fanta, In ed.: J.C. Salamone, Polymeric Materials Encyclopedia, RC Press: Boca Raton, FL, Vol. 10, pp. 7901, 8051 (1996).
G.M. Patel, C.P. Patel and H.C. Trivedi, Eur. Polym. J., 35, 201 (1999).
S. Silong and L. Rahman, J. Appl. Polym. Sci., 76, 516 (2000).
J. Kost, In ed.: E. Mathiowitz, Encyclopedia of Controlled Drug Delivery, Wiley: New York, Vol. 1, p. 445 (1999).
N.A. Peppas and A.G. Mikes, Hydrogels in Medicine and Pharmacy, CRC Press: Boca Raton, FL, Vol. 1 (1986).
R.E. Kirk and D.F. Othmer, In eds.: J.I. Kroschwitz and M. Howe-Grant, Encyclopedia of Chemical Technology, John Wiley & Sons: New York, Vol. 4, p. 942 (1992).
A. Pourjavadi, A.M. Harzandi and H. Hosseinzadeh, Eur. Polym. J., 40, 1363 (2004).
A. Pourjavadi, H. Ghasemzadeh and H. Hosseinzadeh, Preparation and Swelling Behavior of a Novel Anti-Salt Super absorbent Hydrogel Based on Kappa-Carrageenan and Sodium Alginate Grafted with Polyacrylamide,e-Polymers, No. 027 (2004).
R.M. Silverstein and F.X. Webster, Spectrometric Identification of Organic Compounds, Wiley, New York, edn. 6 (1998).
P.J. Flory, Principles of Polymer Chemistry, Ithaca, Cornell University Press, New York (1953).
W.F. Lee and G.H. Lin, J. Appl. Polym. Sci., 79, 1665 (2001).
V.D. Athawale and V. Lele, Carbohydr. Polym., 35, 21 (1998).
V.D. Athawale and V. Lele, Starch/Starke, 50, 426 (1998).