Copyright (c) 2013 AJC
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Direct Extraction of Palladium from Aqueous Solution with Ionic Liquid in Absence of Chelating Agent
Corresponding Author(s) : Xia-Shi Zhu
Asian Journal of Chemistry,
Vol. 25 No. 3 (2013): Vol 25 Issue 3
Abstract
The extraction of palladium(II) chloride by 1-alkyl-3-methylimidazolium hexafluorophosphate [C4MIM][PF6] ionic liquids in the absence of a chelating agent was evaluated over a wide range of acidity. Essentially quantitative extraction of trace and macro amounts of palladium is easily accomplished from the pH 4.0 Britton-Robinson buffer solutions by 1.50 g [C4MIM][PF6]. Optimum conditions such as shake time and centrifuging time, extraction temperature, aqueous phase acidity, sample volume, dosage of [C4MIM][PF6] were established for the extraction of palladium. The proposed method was applied to extract trace amounts of Pd(II) in synthetic samples and the waste water of catalyst of fuel cell with satisfactory results.
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- J. Kielhorn, C. Melber, D. Keller and I. Mangelsdorf, Int. J. Hyg. Environ. Health, 205, 417 (2002).
- A. Niazi, B. Jafarian and J. Ghasemi, Spectrochim. Acta A, 71, 841 (2008).
- S.F. Boulyga and K.G. Heumann, Anal. Bioanal. Chem., 383, 442 (2005).
- B. Sures, S. Zimmermann, J. Messerschmidt, A. Von Bohlen and F. Alt, Environ. Pollut., 113, 341 (2001).
- K.S. Patel, P.C. Sharma and P. Hoffmann, Fresenius J. Anal. Chem., 367, 738 (2000).
- S. Igarashi and K. Endo, Anal. Chim. Acta, 320, 133 (1996).
- J. Komarek, P. Krasensky, J. Balcar and P. Rehulka, Spectrochim. Acta B, 54, 739 (1999).
- B. Godlewska-Zylkiewicz and M. Zaleska, Anal. Chim. Acta, 462, 305 (2002).
- J. Messerschmidt, A. Von Bohlen, F. Alt and R. Klockenkamper, Analyst, 125, 397 (2000).
- M.B. Gomez, M.M. Gomez and A.M. Palacios, J. Anal. At. Spectrom., 18, 80 (2003).
- I. Jarvis, M.M. Totl and K.E. Jarvis, Analyst, 122, 19 (1997).
- B. Godlewska-Zylkiewicz, B. Lesniewska, U. Gasiewska and A. Hulanicki, Anal. Lett., 33, 2805 (2000).
- M. Schuster and M. Schwarzer, Anal. Chim. Acta, 328, 1 (1996).
- K. Boch, M. Schuster, G. Risse and M. Schwarzer, Anal. Chim. Acta, 59, 257 (2002).
- M. Mohamadi and A. Mostafavi, Talanta, 81, 309 (2010).
- J.S. Lee, J.Y. Bae, H. Lee, N.D. Quan, H.S. Kim and H. Kim, J. Ind. Eng. Chem., 10, 1086 (2004).
- P. Wasserscheid, J. Ind. Eng. Chem., 13, 325 (2007).
- D. Demberelnyamba, S.J. Yoon and H. Lee, Chem. Lett., 33, 560 (2004).
- S. Chun, S.V. Dzyuba and R.A. Bartsch, Anal. Chem., 73, 3737 (2001).
- M.L. Dietz, J.A. Dzielawa, I. Laszak, B.A. Young and M.P. Jensen, Green Chem., 5, 682 (2003).
- M.P. Jensen, J. Neuefeind, J.V. Beitz, S. Skanthakumar and L. Soderholm, J. Am. Chem. Soc., 125, 15466 (2003).
- K. Nakashima, F. Kubota, T. Maruyama and M. Goto, Ind. Eng. Chem. Res., 44, 4368 (2005).
- M. Srncik, D. Kogelnig, A. Stojanovic, W. Körner, R. Krachler and G. Wallner, Appl. Radiat. Isotopes, 67, 2146 (2009).
- R. Lertlapwasin, N. Bhawawet, A. Imyim and S. Fuangswasdi, Sep. Purif. Technol., 72, 70 (2010).
- Y.F. Shen Y.J. Zhang, D.X. Han, Z.J. Wang, D. Kuehner and L. Niu, Talanta, 78, 805 (2009).
References
J. Kielhorn, C. Melber, D. Keller and I. Mangelsdorf, Int. J. Hyg. Environ. Health, 205, 417 (2002).
A. Niazi, B. Jafarian and J. Ghasemi, Spectrochim. Acta A, 71, 841 (2008).
S.F. Boulyga and K.G. Heumann, Anal. Bioanal. Chem., 383, 442 (2005).
B. Sures, S. Zimmermann, J. Messerschmidt, A. Von Bohlen and F. Alt, Environ. Pollut., 113, 341 (2001).
K.S. Patel, P.C. Sharma and P. Hoffmann, Fresenius J. Anal. Chem., 367, 738 (2000).
S. Igarashi and K. Endo, Anal. Chim. Acta, 320, 133 (1996).
J. Komarek, P. Krasensky, J. Balcar and P. Rehulka, Spectrochim. Acta B, 54, 739 (1999).
B. Godlewska-Zylkiewicz and M. Zaleska, Anal. Chim. Acta, 462, 305 (2002).
J. Messerschmidt, A. Von Bohlen, F. Alt and R. Klockenkamper, Analyst, 125, 397 (2000).
M.B. Gomez, M.M. Gomez and A.M. Palacios, J. Anal. At. Spectrom., 18, 80 (2003).
I. Jarvis, M.M. Totl and K.E. Jarvis, Analyst, 122, 19 (1997).
B. Godlewska-Zylkiewicz, B. Lesniewska, U. Gasiewska and A. Hulanicki, Anal. Lett., 33, 2805 (2000).
M. Schuster and M. Schwarzer, Anal. Chim. Acta, 328, 1 (1996).
K. Boch, M. Schuster, G. Risse and M. Schwarzer, Anal. Chim. Acta, 59, 257 (2002).
M. Mohamadi and A. Mostafavi, Talanta, 81, 309 (2010).
J.S. Lee, J.Y. Bae, H. Lee, N.D. Quan, H.S. Kim and H. Kim, J. Ind. Eng. Chem., 10, 1086 (2004).
P. Wasserscheid, J. Ind. Eng. Chem., 13, 325 (2007).
D. Demberelnyamba, S.J. Yoon and H. Lee, Chem. Lett., 33, 560 (2004).
S. Chun, S.V. Dzyuba and R.A. Bartsch, Anal. Chem., 73, 3737 (2001).
M.L. Dietz, J.A. Dzielawa, I. Laszak, B.A. Young and M.P. Jensen, Green Chem., 5, 682 (2003).
M.P. Jensen, J. Neuefeind, J.V. Beitz, S. Skanthakumar and L. Soderholm, J. Am. Chem. Soc., 125, 15466 (2003).
K. Nakashima, F. Kubota, T. Maruyama and M. Goto, Ind. Eng. Chem. Res., 44, 4368 (2005).
M. Srncik, D. Kogelnig, A. Stojanovic, W. Körner, R. Krachler and G. Wallner, Appl. Radiat. Isotopes, 67, 2146 (2009).
R. Lertlapwasin, N. Bhawawet, A. Imyim and S. Fuangswasdi, Sep. Purif. Technol., 72, 70 (2010).
Y.F. Shen Y.J. Zhang, D.X. Han, Z.J. Wang, D. Kuehner and L. Niu, Talanta, 78, 805 (2009).