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A New Approach to Synthesize Zinc(II) Coordination Polymer
Corresponding Author(s) : Huiming Zhang
Asian Journal of Chemistry,
Vol. 28 No. 2 (2016): Vol 28 Issue 2
Abstract
A new Zn(II) coordination polymer with benzophenone-4,4'-dicarboxylic acid (H2bpdc) and 1,4-bis(imidazol-1-yl)benzene (bib) has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, infrared and elemental analysis. Complex, {[Zn(bpdc)(bib)]·2H2O}n (1), is triclinic, space group P-1 with a = 8.958(5), b = 11.336(5), c = 14.150(5) Å, a = 111.109(5), b = 95.077 (5)°, g = 98.504(5), V = 1310.0 (10) Å3, Z = 2, Mr = 579.86, Dc = 1.470 g/cm3, F(000) = 596 and μ = 0.991 mm-1. The final refinement gave R = 0.0352 and wR = 0.0964 for 5191 reflections with I > 2s(I). X-ray diffraction analysis reveals that complex 1 displays a 2D + 2D ® 3D polycatenated structure.
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P.Q. Liao, D.D. Zhou, A.X. Zhu, L. Jiang, R.B. Lin, J.P. Zhang and X.M. Chen, J. Am. Chem. Soc., 134, 17380 (2012); doi:10.1021/ja3073512.
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M. Clemente-León, E. Coronado, C. Martí-Gastaldo and F.M. Romero, Chem. Soc. Rev., 40, 473 (2011); doi:10.1039/c0cs00111b.
Q.X. Jia, H. Tian, J.Y. Zhang and E.Q. Gao, Chem. Eur. J., 17, 1040 (2011); doi:10.1002/chem.201001151.
J. Li, J. Tao, R.B. Huang and L.S. Zheng, Inorg. Chem., 51, 5988 (2012); doi:10.1021/ic300487a.
Y.J. Cui, Y.F. Yue, G.D. Qian and B.L. Chen, Chem. Rev., 112, 1126 (2012); doi:10.1021/cr200101d.
L.H. Wei, Z.L. Wang, M.X. Li and J.P. Wang, Chinese J. Struct. Chem., 30, 486 (2011).
Q.X. Yang, X.Q. Chen, Z.J. Chen, Y. Hao and Y.Z. Li, Q.Y. Lu and H.G. Zheng, Chem. Commun., 48, 10016 (2012); doi:10.1039/C2CC35340G.
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