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Vol. 25 No. 3 (2013): Vol 25 Issue 3

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Synthesis and Crystal Structure of Bis-(μ2-(4-Carboxybenzyl)-methylene-4-pyridine-O,O')-dibromo-cadmium Complex

https://doi.org/10.14233/ajchem.2013.13082
Xiuli You
Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, P.R. China
Tao Hu
Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, P.R. China

Corresponding Author(s) : Xiuli You

xlyouzhhwei@163.com

Asian Journal of Chemistry, Vol. 25 No. 3 (2013): Vol 25 Issue 3

Abstract

Reaction of one equivalence of CdBr2 and two equivalence of zwitter ionic carboxylate (4-carboxybenzyl)-methylene-4-pyridine ligand in water give rise to the complex [C26H22N2O4CdBr2] (I), in which the central Cd atom adopts a distorted octahedral coordination geometry that is formed from four O atoms of two bidentate (4-carboxybenzyl)-methylene-4-pyridine ligands and two Br atoms.

Keywords

Crystal structure Cadmium complex Zwitterionic carboxylate ligand Pyridyl ligand
You, X., & Hu, T. (2012). Synthesis and Crystal Structure of Bis-(μ2-(4-Carboxybenzyl)-methylene-4-pyridine-O,O’)-dibromo-cadmium Complex. Asian Journal of Chemistry, 25(3), 1471–1473. https://doi.org/10.14233/ajchem.2013.13082
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