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New Routes for Preparation and Characterization of [Au2(CºN)2P(Ph)2CH2P(Ph)2] Complex
Corresponding Author(s) : Mohammed H. Jaafar
Asian Journal of Chemistry,
Vol. 25 No. 2 (2013): Vol 25 Issue 2
Abstract
The gold complex i.e., [Au2(CºN)2P(Ph)2CH2P(Ph)2] has been successfully produced by three reactions, the reaction of polymeric gold cyanide [Au(CN)]n with a suspension of bis(diphenylphosphino)methane (dppm), in acetone in a 2:1, pure ammonia (NH3), [Au(CºN)]n and (Ph)2PCH2P(Ph)2 in acetone in a 2:2:1 or that of [Au(CºN)(NH3)2] with (Ph)2PCH2P(Ph)2 in acetone in a 1:0.5 giving a white precipitate collected as Au2(CºN)2P(Ph)2CH2P(Ph)2. The complex was characterized by elemental analysis, FT-IR and NMR spectroscopy and found in agreement with the proposed formula C27H22N2P2Au2.
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- C.A. McAuliffe and W. Levason, Phosphine Arsine Stibine Complexes of the Transition Metal, Elsevier, Amsterdam (1979).
- S. Irisli and F. Tiryaki, Asian J. Chem., 21, 355 (2009).
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- S.M. Frankiss, J. Mol. Struct., 31, 1 (1976).
- D.M. Adams and P.A. Fletcher, Spectrochim. Acta A, 44, 437 (1987).
- J.J. Bour, P.P.J. Schlebos, R.P.F. Kanters, W.P. Bosman, J.M.M. Smits, P.T. Beurskens and J.J. Steggerda, Inorg. Chim. Acta, 171, 177 (1990).
- M.D. Adams, Hydrometallurgy, 31, 121 (1992).
- P. Gans, J.B. Gill and L.H. Johnson, J. Chem. Soc. Dalton Trans, 345 (1993).
- D. Li, X. Hong, C.-M. Che, W.-C. Lo and S.-M. Peng , J. Chem. Soc. Dalton Trans, 2929 (1993).
- M.A. Rawashdeh-Omary, M.A. Omary, H.H. Patterson and J.P. Fackler Jr., J. Am. Chem. Soc., 123, 11237 (2001).
- P. Aslanidis, P.J. Cox, S. Divavanidis and P. Karagiannidis, Inorg. Chim. Acta, 357, 2677 (2004).
- J. Charissa, F. Colis, C. Larochelle, R. Staples, R. Herbst-Irmer and H. Patterson, Dalton Trans, 675 (2005).
- J.-D. Lin, Z.-H. Li, J.-R. Li and S.-W. Du, Polyhedron, 26, 107 (2007).
- A.A. Isab, M.I.M. Wazeer, M. Fettouhi, B.A. Al-Maythalony, A.R. AlArfaj and N.O. Al-Zamil, Inorg. Chim. Acta, 360, 3719 (2007).
- M.A. Rawashdeh-Omary, M.A. Omary and H.H. Patterson, J. Am. Chem. Soc., 122, 1037 (2000).
- M.A. Omary and H.H. Patterson, J. Am. Chem. Soc., 120, 7696 (1998).
- S.M. Kanan, C.P. Tripp, R.N. Austin and H.H. Patterson, J. Phys. Chem. B, 105, 9441 (2001).
- R.J. Puddenphatt, The Chemistry of Gold, Elsevier, Oxford (1978).
- R. Nast, Coord. Chem. Rev., 47, 89 (1982).
- F.A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, Wiley InterScience.
- A.-R.A. Al-Ohaly, J. Chem. Res., 38 (1993).
- E.J. Fernandez, M.C. Gimeno, P.G. Jones, A. Laguna, M. Laguna and J.M. Lopez-de-Luzriaga, J. Chem. Soc. Dalton Trans, 3365 (1992).
- R. Uson and A. Laguna, Chem. Soc. Dalton Trans, 2127 (1989).
- D. Michael, P. Mingos, J. Yau, S. Menzer and D.J. Williams, J. Chem. Soc. Dalton Trans, 319 (1995).
- D.A.V. Morton and A.G. Orpen, J. Chem. Soc. Dalton Trans, 641 (1992).
- P. Gans, J.B. Gill and L.H. Johnson, J. Chem. Soc. Dalton Trans, 673 (1987).
- L.J. Bellamy, Advances in Infrared Group Frequencies. Methuen, London (1969).
References
C.A. McAuliffe and W. Levason, Phosphine Arsine Stibine Complexes of the Transition Metal, Elsevier, Amsterdam (1979).
S. Irisli and F. Tiryaki, Asian J. Chem., 21, 355 (2009).
R.J. Puddenphatt, Chem. Soc. Rev., 12, 99 (1983); B. Chaudret, B. Delaur and R. Poilblanc, Coord. Chem. Rev., 86, 191 (1988).
S.M. Frankiss, J. Mol. Struct., 31, 1 (1976).
D.M. Adams and P.A. Fletcher, Spectrochim. Acta A, 44, 437 (1987).
J.J. Bour, P.P.J. Schlebos, R.P.F. Kanters, W.P. Bosman, J.M.M. Smits, P.T. Beurskens and J.J. Steggerda, Inorg. Chim. Acta, 171, 177 (1990).
M.D. Adams, Hydrometallurgy, 31, 121 (1992).
P. Gans, J.B. Gill and L.H. Johnson, J. Chem. Soc. Dalton Trans, 345 (1993).
D. Li, X. Hong, C.-M. Che, W.-C. Lo and S.-M. Peng , J. Chem. Soc. Dalton Trans, 2929 (1993).
M.A. Rawashdeh-Omary, M.A. Omary, H.H. Patterson and J.P. Fackler Jr., J. Am. Chem. Soc., 123, 11237 (2001).
P. Aslanidis, P.J. Cox, S. Divavanidis and P. Karagiannidis, Inorg. Chim. Acta, 357, 2677 (2004).
J. Charissa, F. Colis, C. Larochelle, R. Staples, R. Herbst-Irmer and H. Patterson, Dalton Trans, 675 (2005).
J.-D. Lin, Z.-H. Li, J.-R. Li and S.-W. Du, Polyhedron, 26, 107 (2007).
A.A. Isab, M.I.M. Wazeer, M. Fettouhi, B.A. Al-Maythalony, A.R. AlArfaj and N.O. Al-Zamil, Inorg. Chim. Acta, 360, 3719 (2007).
M.A. Rawashdeh-Omary, M.A. Omary and H.H. Patterson, J. Am. Chem. Soc., 122, 1037 (2000).
M.A. Omary and H.H. Patterson, J. Am. Chem. Soc., 120, 7696 (1998).
S.M. Kanan, C.P. Tripp, R.N. Austin and H.H. Patterson, J. Phys. Chem. B, 105, 9441 (2001).
R.J. Puddenphatt, The Chemistry of Gold, Elsevier, Oxford (1978).
R. Nast, Coord. Chem. Rev., 47, 89 (1982).
F.A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, Wiley InterScience.
A.-R.A. Al-Ohaly, J. Chem. Res., 38 (1993).
E.J. Fernandez, M.C. Gimeno, P.G. Jones, A. Laguna, M. Laguna and J.M. Lopez-de-Luzriaga, J. Chem. Soc. Dalton Trans, 3365 (1992).
R. Uson and A. Laguna, Chem. Soc. Dalton Trans, 2127 (1989).
D. Michael, P. Mingos, J. Yau, S. Menzer and D.J. Williams, J. Chem. Soc. Dalton Trans, 319 (1995).
D.A.V. Morton and A.G. Orpen, J. Chem. Soc. Dalton Trans, 641 (1992).
P. Gans, J.B. Gill and L.H. Johnson, J. Chem. Soc. Dalton Trans, 673 (1987).
L.J. Bellamy, Advances in Infrared Group Frequencies. Methuen, London (1969).