Study on Cobalt Metal Organic Framework Material as Adsorbent for Lead Ions Removal in Aqueous Solution

N.D. Shooto; N. Ayawei; D. Wankasi; L. Sikhwivhilu; E.D. Dikio

doi:10.14233/ajchem.2016.19202

Issue

Vol. 28 No. 2 (2016): Vol 28 Issue 2

Issue Published : November 3, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Study on Cobalt Metal Organic Framework Material as Adsorbent for Lead Ions Removal in Aqueous Solution

https://doi.org/10.14233/ajchem.2016.19202

N.D. Shooto

Applied Chemistry and Nano-Science Laboratory, Department of Chemistry, Vaal University of Technology P.O. Box X021, Vanderbijlpark 1900, South Africa

N. Ayawei

Niger Delta University, Wilberforce Island, P.M.B. 071 Yenagoa Bayelsa State, Nigeria

D. Wankasi

Applied Chemistry and Nano-Science Laboratory, Department of Chemistry, Vaal University of Technology P.O. Box X021, Vanderbijlpark 1900, South Africa

L. Sikhwivhilu

Advanced Materials Division, Mintek, Nanotechnology Innovation Centre, Private Bag X3015, Randburg 2125, South Africa

E.D. Dikio

Applied Chemistry and Nano-Science Laboratory, Department of Chemistry, Vaal University of Technology P.O. Box X021, Vanderbijlpark 1900, South Africa

Corresponding Author(s) : N.D. Shooto

davidshooto12@gmail.com; ezekield@vut.ac.za

Asian Journal of Chemistry, Vol. 28 No. 2 (2016): Vol 28 Issue 2
Article Published : November 3, 2015

Abstract

Cobalt-metal-organic frameworks (Co-MOFs) were synthesized and their morphological features studied using thermalgravimetric analysis, Raman spectroscopy, energy dispersive spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction spectroscopy and Fourier transformed infrared spectroscopy. Equilibrium and thermodynamic batch adsorption experiments were carried out to determine concentration, time and temperature effects respectively. The morphological images showed Co-MOFs of irregular sized highly crystalline regions. It also showed the presence of C, O, Co and OH which may create charges and functionalities on the surface of the Co-MOF for adsorption. The adsorption studies recorded a rapid uptake of Pb²⁺ by the Co-MOFs. The equilibrium, kinetic and thermodynamic studies suggested relatively low temperature (low energy) favoured sorption which was exothermic with a physisorption mechanism.

Keywords

Cobalt Metal-organic frameworks Solvothermal method Adsorption

Shooto, N., Ayawei, N., Wankasi, D., Sikhwivhilu, L., & Dikio, E. (2015). Study on Cobalt Metal Organic Framework Material as Adsorbent for Lead Ions Removal in Aqueous Solution. Asian Journal of Chemistry, 28(2), 277–281. https://doi.org/10.14233/ajchem.2016.19202

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References

A. Azizullah, M.N.K. Khattak, P. Richter and D.H. Hader, Environ. Int., 37, 479 (2011); doi:10.1016/j.envint.2010.10.007.

R. Jalali, H. Ghafourian, Y. Asef, S.J. Davarpanah and S. Sepehr, J. Hazard. Mater., 92, 253 (2002); doi:10.1016/S0304-3894(02)00021-3.

R.P. Suresh Jeyakumar and V. Chandrasekaran, Int. J. Ind. Chem., 5, 2 (2014); doi:10.1186/2228-5547-5-2.

D. Wankasi and E.D. Dikio, J. Chem., Article ID 817527 (2014); doi:10.1155/2014/817527.

D. Wankasi and E.D. Dikio, Asian J. Chem., 24, 8295 (2014).

D. Wankasi and E.D. Dikio, Asian J. Chem., 27, 690 (2015); doi:10.14233/ajchem.2015.17772.

R. Banerjee, H. Furukawa, D. Britt, C. Knobler, M. O’Keeffe and O.M. Yaghi, J. Am. Chem. Soc., 131, 3875 (2009); doi:10.1021/ja809459e.

H.K. Chae, D.Y. Siberio-Perez, J. Kim, Y. Go, M. Eddaoudi, A.J. Matzger, M. O’Keeffe and O.M. Yaghi, Nature, 427, 523 (2004); doi:10.1038/nature02311.

M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O’Keeffe and O.M. Yaghi, Science, 295, 469 (2002); doi:10.1126/science.1067208.

G. Ferey, Chem. Soc. Rev., 37, 191 (2008); doi:10.1039/B618320B.

G. Ferey, C. Mellot-Draznieks, C. Serre, F. Millange, J. Dutour, S. Surble and I. Margiolaki, Science, 309, 2040 (2005); doi:10.1126/science.1116275.

P. Horcajada, R. Gref, T. Baati, P.K. Allan, G. Maurin, P. Couvreur, G. Ferey, R.E. Morris and C. Serre, Chem. Rev., 112, 1232 (2012); doi:10.1021/cr200256v.

C. Lamberti, A. Zecchina, E. Groppo and S. Bordiga, Chem. Soc. Rev., 39, 4951 (2010); doi:10.1039/c0cs00117a.

K. Sumida, D.L. Rogow, J.A. Mason, T.M. McDonald, E.D. Bloch, Z.R. Herm, T.H. Bae and J.R. Long, Chem. Rev., 112, 724 (2012); doi:10.1021/cr2003272.

M.P. Suh, H.J. Park, T.K. Prasad and D.W. Lim, Chem. Rev., 112, 782 (2012); doi:10.1021/cr200274s.

D. Maspoch, D. Ruiz-Molina, K. Wurst, N. Domingo, M. Cavallini, F. Biscarini, J. Tejada, C. Rovira and J. Veciana, Nat. Mater., 2, 190 (2003); doi:10.1038/nmat834.

M. Kawano, T. Kawamichi, T. Haneda, T. Kojima and M. Fujita, J. Am. Chem. Soc., 129, 15418 (2007); doi:10.1021/ja0752540.

G. Férey, F. Millange, M. Morcrette, C. Serre, M.L. Doublet, J.M. Grenèche and J.M. Tarascon, Angew. Chem. Int. Ed. Engl., 46, 3259 (2007); doi:10.1002/anie.200605163.

P.D.C. Dietzel, V. Besikiotis and R. Blom, J. Mater. Chem., 19, 7362 (2009); doi:10.1039/b911242a.

K.K. Tanabe and S.M. Cohen, Inorg. Chem., 49, 6766 (2010); doi:10.1021/ic101125m.

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H. Wang, F. Yin, G. Li, B. Chen and Z. Wang, Int. J. Hydrogen Energy, 39, 16179 (2014); doi:10.1016/j.ijhydene.2013.12.120.

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R.A. Crowther, D.J. Derosier and A. Klug, Proc. R. Soc. Lond. A Math. Phys. Sci., 319, 40 (1970); doi:10.1098/rspa.1970.0119.

Issue

Vol. 28 No. 2 (2016): Vol 28 Issue 2

Study on Cobalt Metal Organic Framework Material as Adsorbent for Lead Ions Removal in Aqueous Solution

Corresponding Author(s) : N.D. Shooto

Abstract

Keywords

Full Article

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