Issue

Vol. 25 No. 2 (2013): Vol 25 Issue 2

Copyright (c) 2013 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Determination of Polycyclic Aromatic Hydrocarbons in Soil Sample Using Matrix Solid Phase Dispersion-Stable Isotope Dilution Technique-Gas Chromatography Mass Spectrometry

https://doi.org/10.14233/ajchem.2013.13659
Y.T. Zhang
Institute of Hydrogeology and Environmental Geology, CAGS, Zhengding 50803, P.R. China
L. Zhang
Institute of Hydrogeology and Environmental Geology, CAGS, Zhengding 50803, P.R. China
G.X. Zhao
Institute of Hydrogeology and Environmental Geology, CAGS, Zhengding 50803, P.R. China
G.Q. Zhang
Weichai Power Co., Ltd. Weifang 261001, P.R. China
H.Y. Zuo
Institute of Hydrogeology and Environmental Geology, CAGS, Zhengding 50803, P.R. China
X.Y. Li
Institute of Hydrogeology and Environmental Geology, CAGS, Zhengding 50803, P.R. China
J.Y. Gui
Institute of Hydrogeology and Environmental Geology, CAGS, Zhengding 50803, P.R. China

Corresponding Author(s) : G.X. Zhao

icpzytws@126.com; zhaoGuoxing65@163.com

Asian Journal of Chemistry, Vol. 25 No. 2 (2013): Vol 25 Issue 2

Abstract

A method was developed for the determination of polycyclic aromatic hydrocarbons (PAHs) in soil sample by measuring stable isotope dilution technique of matrix solid-phase dispersion extraction-gas chromatography mass spectrometry. The sample adopted silica with bonded C18 as solid supports, used dichloromethane-acetone to elute and realized cleaning and recovery. The research verified the similar physicochemical properties and the consistency of chromatographic behaviour between target compounds and compounds containing deuterium, confirmed that isotope fractionation was not obvious during the sample pretreatment in this experiment. The recovery of standard addition was between 97.5 to 109.2 %, the precision was between 0.89 and 3.06 % and achieved satisfactory recovery.

Keywords

Matrix solid phase dispersion Isotope dilution technique Polycyclic aromatic hydrocarbons Gas chromatography mass spectrometry
Zhang, Y., Zhang, L., Zhao, G., Zhang, G., Zuo, H., Li, X., & Gui, J. (2012). Determination of Polycyclic Aromatic Hydrocarbons in Soil Sample Using Matrix Solid Phase Dispersion-Stable Isotope Dilution Technique-Gas Chromatography Mass Spectrometry. Asian Journal of Chemistry, 25(2), 1129–1132. https://doi.org/10.14233/ajchem.2013.13659
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. X.M. Zhang, Z.Q. Zhang and W.P. Huang, Environ. Sci. Manag., 7, 124 (2010).
  2. L.L. Tang, X.Y. Tang, Y.G. Zhu and Q.L. Miao, J. PLA Univ. Sci. Technol., 2, 95 (2004).
  3. H. Zeng, H. Tang, D.Z. Chen, G.N. Wang, J. Feng, J.Y. Wang and L. Li, Chin. J. Anal. Lab., 9, 11 (2011).
  4. F.Q. Fan, J.F. Dou, A.Z. Ding, H.Y. Chen and Y.C. Du, J. Beijing Normal Univ. (Nat. Sci.), 3, 296 (2011).
  5. Y.M. Jiang, S.Z. Wei, B.D. Xi, H.Y. Zhang and H.J. Li, Ecol. Environ. Sci., 3, 1176 (2009).
  6. G.Y. Yang, T.B. Zhang, S.T. Gao, Z.X. Guo, H.F. Wan and Y.X. Gao, Environ. Sci., 10, 2350 (2007).
  7. L.F. Zhang, X.J. Li, C.X. Liu and Z.R. Zeng, Chin. J. Anal. Chem., 9, 1269 (2007).
  8. L.L. Ma, W.J. Lao, X.T. Wang, H. Liu, S.G. Chu and X.B. Xu, Chin. J. Anal. Chem., 9, 1025 (2003).
  9. Z. Rao, S. Li, M. He and J. Su, Chin. J. Anal. Chem., 7, 954 (2007).
  10. Q.L. Li, X.Q. Xu, X.C. Li and X.R. Wang, Science In China Ser. B Chemistry, 3, 202 (2006).
  11. S.C. Zou, S. Shuai, T.G. Luan, H.Q. Zhang and Q. Shen, Chin. J. Anal. Chem., 6, 889 (2006).
  12. Q. Zhang, X.W. Liu, M. Luo, L. Wang, H. Li, D. Wang and Y.P. Xu, Environ. Chem., 4, 771 (2011).
  13. X.Z. Zhang, F.J. Luo, G.M. Liu, Z.Y. Lou and Z.M. Chen, Chin. J. Anal. Chem., 9, 1131 (2011).
  14. S.X. Guan, Z.J. Yu, H.N. Yu, C.H. Song, Z.Q. Song and Z. Qin, Chromatographia, 73, 33 (2011).
  15. P.C. Abhilash and N. Singh, Bull. Environ. Contam. Toxicol., 81, 604 (2008).
  16. Y.-H. Wang, X. Li, X.-M. Zhou and L.-Y. Bai, Asian J. Chem., 24, 2042 (2012).
  17. J. Shi, W. Gong, Y.S. Cheng, H.M. Liu and J.L. Cai, Chem. Online, 6, 467 (2007).
  18. X.M. Li, Q.H. Zhang, P. Wang, Y.M. Li and G.B. Jiang, Chin. J. Anal. Chem., 11, 1641 (2011).
  19. H. Zeng, H. Tang, D.Z. Chen, G.N. Wang, J. Feng, J.Y. Wang and L. Li, Chin. J. Anal. Lab., 9, 11 (2011).
  20. X.C. Jiao, G. Wang, C.Y. Ye, X.D. Liu, Y.L. Yang and X.C. Wang, Rock Miner. Anal., 3, 207 (2011).
  21. L.S. Wang and L. Zhang, J. Miner. Petrol., 23, 44 (2003).
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 1 Download : 0