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Vol. 25 No. 2 (2013): Vol 25 Issue 2

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Synthesis, Characterization and Crystal Structure of a Supramolecular Compound Diaquabis(1,10-phenanthroline-k2N,N')cobalt(II) 4,4'-Methylenebis(3-hydroxy-2-naphthoate) Tetrahydrate

https://doi.org/10.14233/ajchem.2013.13351
Min-Quan Dong
Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, P.R. China
Li Song
Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, P.R. China
Chun Ling
Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, P.R. China
Kai Xue
Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, P.R. China

Corresponding Author(s) : Li Song

songli_spring@yahoo.com.cn

Asian Journal of Chemistry, Vol. 25 No. 2 (2013): Vol 25 Issue 2

Abstract

In present study, the metal-organic coordinated polymers from pamonic acid, 4,4'-methylenebis(3-hydroxy-2-naphthoic acid) (L), a supramolecular compound Co(phen)2(H2O)2L·(H2O)4 (1) was synthesized. Its structure was determined by single crystal X-ray diffraction experiment. The compound crystallizes in the monoclinic system and adopts a centrosymmetric space group of C2/c. In Co(phen)2(H2O)2L·(H2O)4, two phen ligands coordinate to Co(II) through two N atoms, respectively. And the other two coordinated sites in the octahedron geometry of Co(II) are completed by four H2O through O atoms. Pamonic acid only acts as a counter anion. There are several hydrogen bonds between coordinated water of coordination cation, pamonic acid anion and solvent water molecules. These hydrogen bonding interactions assemble three components of this compound firmly and from a supramolecular chain along c-axis.

Keywords

Pamonic acid Supramolecular compound Hydrogen bond
Dong, M.-Q., Song, L., Ling, C., & Xue, K. (2012). Synthesis, Characterization and Crystal Structure of a Supramolecular Compound Diaquabis(1,10-phenanthroline-k2N,N’)cobalt(II) 4,4’-Methylenebis(3-hydroxy-2-naphthoate) Tetrahydrate. Asian Journal of Chemistry, 25(2), 1003–1005. https://doi.org/10.14233/ajchem.2013.13351
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