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Ethylbenzotriazolium Bromide Ionic Liquid: A New Water Soluble Inhibitor for Corrosion of Mild Steel in Acid Media
Corresponding Author(s) : Suqin Liu
Asian Journal of Chemistry,
Vol. 25 No. 2 (2013): Vol 25 Issue 2
Abstract
The inhibiting effect of 1-ethyl-3-ethylbenzotriazolium bromide ionic liquid, [C2Et]Br, on the corrosion behaviour of mild steel in 5 wt. % HCl was investigated by using various techniques such as weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy. All studies showed that the increase in inhibition efficiency and decrease in the corrosion rate by increasing the inhibitor concentration. Polarization measurements indicated that the [C2Et]Br acted essentially as a mixed-type inhibitor. The electrochemical impedance study showed that corrosion inhibition took place by adsorption.
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- H. Ashassi-Sorkhabi and M. Es'haghi, Mater. Chem. Phys., 114, 267 (2009).
- Q.B. Zhang and Y.X. Hua, Electrochim. Acta, 54, 1881 (2009).
- Q.B. Zhang and Y.X. Hua, Mater. Chem. Phys., 119, 57 (2010).
- F.G. Liu, M. Du and J. Zhang, Corros. Sci., 51, 102 (2009).
- D. Nalini, R. Rajalakshmi and S. Subhashini, Asian J. Chem., 23, 335 (2011).
- A. Lewandowski and A. Swiderska-Mocek, J. Power Sources, 194, 601 (2009).
- H.M. Wang, K.L. Huang and Z.P. Zhu, Adv. Mater. Res., 239-242, 1409 (2011).
- S.M. Zhang, Y.W. Hou and W.G. Huang, Electrochim. Acta, 50, 4097 (2005).
- T. Tsuru, S. Haruyama and B. Gijutsu, J. Jpn. Soc. Corros. Eng., 27, 573 (1978).
- L. Elkadi, B. Mernari, M. Traisnel, F. Bentiss and M. Lagrenee, Corros. Sci., 42, 703 (2000).
References
H. Ashassi-Sorkhabi and M. Es'haghi, Mater. Chem. Phys., 114, 267 (2009).
Q.B. Zhang and Y.X. Hua, Electrochim. Acta, 54, 1881 (2009).
Q.B. Zhang and Y.X. Hua, Mater. Chem. Phys., 119, 57 (2010).
F.G. Liu, M. Du and J. Zhang, Corros. Sci., 51, 102 (2009).
D. Nalini, R. Rajalakshmi and S. Subhashini, Asian J. Chem., 23, 335 (2011).
A. Lewandowski and A. Swiderska-Mocek, J. Power Sources, 194, 601 (2009).
H.M. Wang, K.L. Huang and Z.P. Zhu, Adv. Mater. Res., 239-242, 1409 (2011).
S.M. Zhang, Y.W. Hou and W.G. Huang, Electrochim. Acta, 50, 4097 (2005).
T. Tsuru, S. Haruyama and B. Gijutsu, J. Jpn. Soc. Corros. Eng., 27, 573 (1978).
L. Elkadi, B. Mernari, M. Traisnel, F. Bentiss and M. Lagrenee, Corros. Sci., 42, 703 (2000).