Copyright (c) 2013 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Investigating the Association Behaviour of Cetyltrimethylammonium Bromide as Affected by the Content of Non-steroidal Antiinflammatory Drug and Temperature
Corresponding Author(s) : Abdur Rauf
Asian Journal of Chemistry,
Vol. 25 No. 1 (2013): Vol 25 Issue 1
Abstract
Critical micelle concentration of N-cetyl N,N,N-trimethyl ammonium bromide and its mixture with drug naproxen sodium were determined at different temperature by using surface tension technique. Naproxen sodium has been found to exhibit typical amphiphilic behaviour in aqueous solution in that they accumulate at interface, depressing the surface tension and form aggregate in solution at sufficiently high concentration. So critical micelle concentration of cetyltrimethylammonium bromide decreased as the concentration of drug increases and same is the case with temperature. Thermodynamic parameters like DGmic, DHmic and DSmic of micellization of cetyltrimethylammonium bromide were also determined in the presence of naproxen sodium salt at different temperature, which shows that free energy of micellization, is favoured in the presence of drug and become more favourable with the temperature.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- M.-R. Porter, Hand Book of Surfactant, 1-3, (1999).
- Th. F. Tadors, Surfactants Academic Press, Inc. (London), 12 (1984).
- Th. F. Tadors, Surfactants Academics Press, (London), pp. 2-9 (1984).
- B. Mohamed Barney and B. Zana. R, J. Colloid. Interface Sci., 267, 519 (2003).
- E.-D, Goddard and K.-P. Ananthapadmanabhan, Interactions of Surfactants with Polymers and Proteins; CRC Press: Boca Raton, Florida (1993).
- D. Langevin, Adv. Colloid. Interf. Sci., 467, 89 (2002).
- J. Funjin and W. Brown, Macromolecules, 27, 5024 (1994).
- G.F. Durrani, M.K. Baloch and G. Hameed, J. Chem. Soc. Pak., 3, 26 (2004).
- J.J. Taber, Pure Appl. Chem., 52, 1323 (1980).
- P. Bahadur and G. Reiss, Tenside Surf. Detg., 28, 173 (1991).
- P.N. Hurter and T.A. Hatton, Langmuir, 8, 1291 (1992).
- P. Alexandridis, Curr. Opin. Colloid. Interface Sci., 1, 490 (1996).
- K. Suzuki, Y. Saito, Y. Tokuoka, M. Abe and T. Sato, J. Am. Oil. Chem. Soc., 74, 55 (1997).
- M.K. Baloch, G. Hameed and A. Bano, J. Chem. Soc. Pak., 24, 77 (2002).
- D. Dhara and D.O. Shah, J. Phys. Chem. B, 105, 7133 (2001).
- A. Mohammad and G.R. Chaudry, A Text Book of Physical Chemistry, Ameen Publishers, Urdu Bazar, Lahore, Pakistan, edn. 1 (1999).
- M.E.L. McBain and E. Hutcinson, Solubilization and Related Phenomena, Academic Press, New York (1955).
- A. Reychler, Z. Kolloid, 12, 277 (1913).
- N.K. Adam, J. Phys. Chem., 29, 87 (1925).
- M.R. Porter, Hand Book of Surfactant, pp. 129-33 (1999).
- D. Attwood and A.T. Florence, Surfactant Systems, Chapman and Hall Ltd., London (1983).
- A. Khan, G. Fatima, M. Usman, W. Harrison and M. Siddiq, J. Chem. Soc. Pak., 31, 534 (2009).
- M.K. Baloch, A. Farzana, A. Rauf and G. Fatima, J. Appl. Polym. Sci., 114, 1444 (2009).
- P.C. Heimenz and R. Rajagopalan, Principles of Colloid and Surface Chemistry, M. Dekker, edn. 3 (1986).
- M.K. Baloch, A. Farzana, A. Rauf, G. Fatima and G. Hameed, J. Appl. Polym. Sci., 116, 2133 (2010).
- C.O. Rangel-Yagui, H.W.L. Hsu, A. Pessoa-Jr and L.C. Tavares, J. Pharm. Pharmaceut. Sci., 41, 237 (2005).
- M.J. Rosen, Surfactants and Interfacial Phenomena. Wiley-Interscience Publication (1978).
References
M.-R. Porter, Hand Book of Surfactant, 1-3, (1999).
Th. F. Tadors, Surfactants Academic Press, Inc. (London), 12 (1984).
Th. F. Tadors, Surfactants Academics Press, (London), pp. 2-9 (1984).
B. Mohamed Barney and B. Zana. R, J. Colloid. Interface Sci., 267, 519 (2003).
E.-D, Goddard and K.-P. Ananthapadmanabhan, Interactions of Surfactants with Polymers and Proteins; CRC Press: Boca Raton, Florida (1993).
D. Langevin, Adv. Colloid. Interf. Sci., 467, 89 (2002).
J. Funjin and W. Brown, Macromolecules, 27, 5024 (1994).
G.F. Durrani, M.K. Baloch and G. Hameed, J. Chem. Soc. Pak., 3, 26 (2004).
J.J. Taber, Pure Appl. Chem., 52, 1323 (1980).
P. Bahadur and G. Reiss, Tenside Surf. Detg., 28, 173 (1991).
P.N. Hurter and T.A. Hatton, Langmuir, 8, 1291 (1992).
P. Alexandridis, Curr. Opin. Colloid. Interface Sci., 1, 490 (1996).
K. Suzuki, Y. Saito, Y. Tokuoka, M. Abe and T. Sato, J. Am. Oil. Chem. Soc., 74, 55 (1997).
M.K. Baloch, G. Hameed and A. Bano, J. Chem. Soc. Pak., 24, 77 (2002).
D. Dhara and D.O. Shah, J. Phys. Chem. B, 105, 7133 (2001).
A. Mohammad and G.R. Chaudry, A Text Book of Physical Chemistry, Ameen Publishers, Urdu Bazar, Lahore, Pakistan, edn. 1 (1999).
M.E.L. McBain and E. Hutcinson, Solubilization and Related Phenomena, Academic Press, New York (1955).
A. Reychler, Z. Kolloid, 12, 277 (1913).
N.K. Adam, J. Phys. Chem., 29, 87 (1925).
M.R. Porter, Hand Book of Surfactant, pp. 129-33 (1999).
D. Attwood and A.T. Florence, Surfactant Systems, Chapman and Hall Ltd., London (1983).
A. Khan, G. Fatima, M. Usman, W. Harrison and M. Siddiq, J. Chem. Soc. Pak., 31, 534 (2009).
M.K. Baloch, A. Farzana, A. Rauf and G. Fatima, J. Appl. Polym. Sci., 114, 1444 (2009).
P.C. Heimenz and R. Rajagopalan, Principles of Colloid and Surface Chemistry, M. Dekker, edn. 3 (1986).
M.K. Baloch, A. Farzana, A. Rauf, G. Fatima and G. Hameed, J. Appl. Polym. Sci., 116, 2133 (2010).
C.O. Rangel-Yagui, H.W.L. Hsu, A. Pessoa-Jr and L.C. Tavares, J. Pharm. Pharmaceut. Sci., 41, 237 (2005).
M.J. Rosen, Surfactants and Interfacial Phenomena. Wiley-Interscience Publication (1978).