Hydrothermally Synthesis and Characterization of Lanthanide Coordination Polymers with (42.62.82)(43.63)2(46.67.82)(48.67) Topology {[Ln2(1,4-pda)3(H2O)]·2H2O}n (Ln = Pr, Nd, Dy)

Mei-Li Zhang; Na Gao; Lou-Jun Gao; Xu-Hua Han; Xiao-Li Chen

doi:10.14233/ajchem.2016.19247

Issue

Vol. 28 No. 1 (2016): Vol 28 Issue 1

Issue Published : October 5, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Hydrothermally Synthesis and Characterization of Lanthanide Coordination Polymers with (42.62.82)(43.63)2(46.67.82)(48.67) Topology {[Ln2(1,4-pda)3(H2O)]·2H2O}n (Ln = Pr, Nd, Dy)

https://doi.org/10.14233/ajchem.2016.19247

Mei-Li Zhang

Department of Chemistry and Chemical Engineering, Yan'an University, Shaanxi 716000, P.R. China

Na Gao

Department of Chemistry and Chemical Engineering, Yan'an University, Shaanxi 716000, P.R. China

Lou-Jun Gao

Department of Chemistry and Chemical Engineering, Yan'an University, Shaanxi 716000, P.R. China

Xu-Hua Han

Department of Chemistry and Chemical Engineering, Yan'an University, Shaanxi 716000, P.R. China

Xiao-Li Chen

Department of Chemistry and Chemical Engineering, Yan'an University, Shaanxi 716000, P.R. China

Corresponding Author(s) : Mei-Li Zhang

ydzml2332041@163.com

Asian Journal of Chemistry, Vol. 28 No. 1 (2016): Vol 28 Issue 1
Article Published : October 5, 2015

Abstract

Three 3D lanthanide coordination polymers {[Ln₂(1,4-pda)₃(H₂O)]·2H₂O}_n (1,4-pda = 1,4-phenylenediacetic acid, Ln = Pr for 1, Nd for 2 and Dy for 3) have been hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analyses and single-crystal X-ray diffraction techniques. The structure indicates that three complexes have similar structures and belong to monoclinic crystal system, P2₁/c space group. In which, trans-bis(μ₂-h²:h¹) and trans-bis(μ₂-h¹:h¹) 1,4-pda^2- anions link the Ln(III) center to generate a 2D network, furthermore, the dimensionality is extended to a (4,6)-connected 3D architecture with a Schläfli symbol of (4².6².8²)(4³.6³)₂(4⁶.6⁷.8²)(4⁸.6⁷) through same coordination mode 1,4-pda^2- anions linking. In additional, photoluminescence properties of three complexes have also been studied. (CCDC 1009612 for 1, 1009613 for 2 and 1009614 for 3).

Keywords

Lanthanide coordination polymers Crystal structure Luminescence

Zhang, M.-L., Gao, N., Gao, L.-J., Han, X.-H., & Chen, X.-L. (2015). Hydrothermally Synthesis and Characterization of Lanthanide Coordination Polymers with (42.62.82)(43.63)2(46.67.82)(48.67) Topology {[Ln2(1,4-pda)3(H2O)]·2H2O}n (Ln = Pr, Nd, Dy). Asian Journal of Chemistry, 28(1), 86–90. https://doi.org/10.14233/ajchem.2016.19247

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References

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O.M. Yaghi, M. O’Keeffe, N.W. Ockwig, H.K. Chae, M. Eddaoudi and J. Kim, Nature, 423, 705 (2003); doi:10.1038/nature01650.

M. O’Keeffe and O.M. Yaghi, Chem. Rev., 112, 675 (2012); doi:10.1021/cr200205j.

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Y. Zhao, D.S. Deng, L.F. Ma, B.M. Ji and L.Y. Wang, Chem. Commun., 49, 10299 (2013); doi:10.1039/c3cc45310c.

X.M. Wang, W.P. Wu, Y.H. Jiang, G.P. Yang and Z.P. Xi, Wuji Huaxue Xuebao, 30, 192 (2014).

Y. Cui, Y. Yue, G. Qian and P. Chen, Chem. Rev., 112, 1126 (2012); doi:10.1021/cr200101d.

A. Morozan and F. Jaouen, Energy Environ. Sci., 5, 9269 (2012); doi:10.1039/c2ee22989g.

Y.P. Cai, X.X. Zhou, Z.Y. Zhou, S.Z. Zhu, P.K. Thallapally and J. Liu, Inorg. Chem., 48, 6341 (2009); doi:10.1021/ic9007125.

O.Z. Yeşilel, G. Günay, C. Darcan, M.S. Soylu, S. Keskin and S.W. Ng, CrystEngComm, 14, 2817 (2012); doi:10.1039/c2ce06603c.

L.J. Chen, X. Chen, Q.B. Hou, M.X. Yang and S. Lin, Wuji Huaxue Xuebao, 30, 786 (2014).

H.Y. Deng, J.R. He, M. Pan, L. Li and C.Y. Su, CrystEngComm, 11, 909 (2009); doi:10.1039/b819608g.

Y.X. Ren, M.L. Zhang, D.S. Li, F. Fu, J.J. Wang, M. Du, X.Y. Hou and Y.P. Wu, Inorg. Chem. Commun., 14, 231 (2011); doi:10.1016/j.inoche.2010.10.030.

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J. Wang and X.Q. Zhao, Chinese J. Struct. Chem., 33, 7 (2014).

J. Wang, Y.H. Zhang and M.L. Tong, Chem. Commun., 3166 (2006); doi:10.1039/b604584g.

L. Pan, K.M. Adams, H.E. Hernandez, X. Wang, C. Zheng, Y. Hattori and K. Kaneko, J. Am. Chem. Soc., 125, 3062 (2003); doi:10.1021/ja028996w.

Y.W. Ren, J.X. Liang, J.X. Lu, B.W. Cai, D.B. Shi, C.R. Qi, H.F. Jiang, J. Chen and D. Zheng, Eur. J. Inorg. Chem., 2011, 4369 (2011); doi:10.1002/ejic.201100523.

G.M. Sheldrick, SADABS, A Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany (1997).

G.M. Sheldrick, SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany (1997).

G.M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany (1997).

Issue

Vol. 28 No. 1 (2016): Vol 28 Issue 1

Hydrothermally Synthesis and Characterization of Lanthanide Coordination Polymers with (42.62.82)(43.63)2(46.67.82)(48.67) Topology {[Ln2(1,4-pda)3(H2O)]·2H2O}n (Ln = Pr, Nd, Dy)

Corresponding Author(s) : Mei-Li Zhang

Abstract

Keywords

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