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Vol. 27 No. 9 (2015): Vol 27 Issue 9

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Synthesis, Crystal Structures and Magnetic Characterization of Two Pyridinecarboxamide trans-Dicyanideiron(III) Building Blocks

https://doi.org/10.14233/ajchem.2015.18806
Xia Chen
College of Chemical Engineering, Shandong University of Technology, Zibo 255049, P.R. China
Lingqian Kong
Dongchang College, Liaocheng University, Liaocheng 252059, P.R. China
Hongyan Zhang
College of Chemical Engineering, Shandong University of Technology, Zibo 255049, P.R. China
Daopeng Zhang
College of Chemical Engineering, Shandong University of Technology, Zibo 255049, P.R. China

Corresponding Author(s) : Daopeng Zhang

dpzhang73@126.com

Asian Journal of Chemistry, Vol. 27 No. 9 (2015): Vol 27 Issue 9

Abstract

Two trans-dicyanometalates based-on qusi-planar tetradentate chelating pyridinecarboxamide ligand with the formula [H3O][Fe(bpb)-(CN)2]·2.5H2O (1) and [H3N(CH2)3NH3]0.5 [Fe(bpb)(CN)2]·2H2O (2) (bpb2- = 1,2-bis(pyridine-2-carboxamido)benzenate) has been obtained, structurally and magnetically characterized. Single X-ray diffraction reveals their same anionic mononuclear structure, in which the Fe(III) ion is six-coordinated with the four equatorial positions occupied by a N4 unit of the pyridinecarboxamide ligand and two axial ones from two C atoms of the cyanide groups. Magnetism characterization for these two compounds show the typical paramagnetic characteristic of the low-spin iron(III) ion.

Keywords

Cyanide precursor Synthesis Crystal structure Magnetic property
Chen, X., Kong, L., Zhang, H., & Zhang, D. (2015). Synthesis, Crystal Structures and Magnetic Characterization of Two Pyridinecarboxamide trans-Dicyanideiron(III) Building Blocks. Asian Journal of Chemistry, 27(9), 3373–3376. https://doi.org/10.14233/ajchem.2015.18806
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