NdCl3-Schiff Base Complex as Catalyst for Formation of Water-Blown Semi-Rigid Polyurethane Foam

Anping Liao; Leilei Qiao; Rimei He; Ping Lan; Lihong Lan; Yanyue Lu; Mei Li

doi:10.14233/ajchem.2015.18793

Issue

Vol. 27 No. 9 (2015): Vol 27 Issue 9

Issue Published : May 26, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

NdCl3-Schiff Base Complex as Catalyst for Formation of Water-Blown Semi-Rigid Polyurethane Foam

https://doi.org/10.14233/ajchem.2015.18793

Anping Liao

School of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Guangxi Colleges and Universities, Key Laboratory of Chemical and Biological Transformation Process Technology, Nanning 530006, P.R. China

Leilei Qiao

Rimei He

Ping Lan

Lihong Lan

Yanyue Lu

Mei Li

Corresponding Author(s) : Anping Liao

gxanping@sina.com

Asian Journal of Chemistry, Vol. 27 No. 9 (2015): Vol 27 Issue 9
Article Published : May 26, 2015

Abstract

Neodymium chloride Schiff base complex was synthesized and characterized by scanning electron microscopy, elemental analysis, ¹H NMR, FT-IR and complexometric titration. This complex, combined with triethylenediamine, was used as a catalytic composite for the foaming reaction of all-water blown semi-rigid polyurethane foam. The effect of ratio of the complex to triethylenediamine on the properties of reaction product was investigated. This catalytic composite can be in place of organic tin catalyst such as stannous octoate, dibutyl tin dilaurate and other conventional polyurethane foam catalyst, which are usually unstable and toxic, leading to environmental hazards.

Keywords

Schiff base complexes of neodymium chloride Catalyst Water foaming Polyurethane foam

Liao, A., Qiao, L., He, R., Lan, P., Lan, L., Lu, Y., & Li, M. (2015). NdCl3-Schiff Base Complex as Catalyst for Formation of Water-Blown Semi-Rigid Polyurethane Foam. Asian Journal of Chemistry, 27(9), 3361–3364. https://doi.org/10.14233/ajchem.2015.18793

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References

X.Y. Xu, X.F. Ni and Z.Q. Shen, Polym. Bull., 53, 81 (2005); doi:10.1007/s00289-004-0319-4.
C. Daza, A. Kiennemann, S. Moreno and R. Molina, Energy Fuels, 23, 3497 (2009); doi:10.1021/ef9000874.
X. Zhu and Y.R. Wang, Appl. Mech. Mater., 184-185, 1302 (2012); doi:10.4028/www.scientific.net/AMM.184-185.1302.
L. Fan, L.F. Zhang and Z.Q. Shen, Chem. Res. Chin. Univ., 19, 516 (2003).
Q. Xu, Y.M. Hu, Y. Li, Z.H. Shi, Y.S. Wang and Y.R. Wang, Acta Polym. Sinica, 36 (2013).
L. Zhang, X.F. Ni, W.L. Sun and Z. Shen, Chinese J. Polym. Sci., 26, 475 (2008); doi:10.1142/S025676790800314X.
F. Peng, J. Ling, Z.Q. Shen and W.W. Zhu, Chem. J. Mol. Catal. A, 230, 135 (2005); doi:10.1016/j.molcata.2004.12.020.
X.J. Zhao, L.Y. Zhang, L.M. Jin and S.D. Fan, Chin. J. Org. Chem., 31, 1516 (2011).
G.W. Chen, Y.X. He, Q.J. Liu, X.Y. Li and Y.Q. Zhang, Plastics Sci. Technol., 124 (2014).
A.A. Abdel Hakim, M. Nassar, A. Emam and M. Sultan, Mater. Chem. Phys., 129, 301 (2011); doi:10.1016/j.matchemphys.2011.04.008.
O. Faruk, M. Sain, R. Farnood, Y. Pan and H. Xiao, J. Polym. Environ., 22, 279 (2014); doi:10.1007/s10924-013-0631-x.
M.M.A. Nikje, M. Haghshenas and A.B. Garmarudi, Polym. Bull., 56, 257 (2006); doi:10.1007/s00289-005-0470-6.
S.E. Liang, C.R. Tian, J.H. Wang and C.R. Wei, China Plastics, 90 (2010).
L.G. Xiao, J. Luo and B. Zhang, New Building Materials, 57 (2009).
L. Liu, X.H. Liu, C.C. Chao, X.Y. Sun, S.P. Weng, D.F. Xu and J.G. Wu, Spectrosc. Spectr. Anal., 536 (2004).
C.L. Shi, L.Q. Chen, F.X. Qiu and D.Y. Yang, Sci. Technol. Chem. Ind., 9 (2008).

References

X.Y. Xu, X.F. Ni and Z.Q. Shen, Polym. Bull., 53, 81 (2005); doi:10.1007/s00289-004-0319-4.

C. Daza, A. Kiennemann, S. Moreno and R. Molina, Energy Fuels, 23, 3497 (2009); doi:10.1021/ef9000874.

X. Zhu and Y.R. Wang, Appl. Mech. Mater., 184-185, 1302 (2012); doi:10.4028/www.scientific.net/AMM.184-185.1302.

L. Fan, L.F. Zhang and Z.Q. Shen, Chem. Res. Chin. Univ., 19, 516 (2003).

Q. Xu, Y.M. Hu, Y. Li, Z.H. Shi, Y.S. Wang and Y.R. Wang, Acta Polym. Sinica, 36 (2013).

L. Zhang, X.F. Ni, W.L. Sun and Z. Shen, Chinese J. Polym. Sci., 26, 475 (2008); doi:10.1142/S025676790800314X.

F. Peng, J. Ling, Z.Q. Shen and W.W. Zhu, Chem. J. Mol. Catal. A, 230, 135 (2005); doi:10.1016/j.molcata.2004.12.020.

X.J. Zhao, L.Y. Zhang, L.M. Jin and S.D. Fan, Chin. J. Org. Chem., 31, 1516 (2011).

G.W. Chen, Y.X. He, Q.J. Liu, X.Y. Li and Y.Q. Zhang, Plastics Sci. Technol., 124 (2014).

A.A. Abdel Hakim, M. Nassar, A. Emam and M. Sultan, Mater. Chem. Phys., 129, 301 (2011); doi:10.1016/j.matchemphys.2011.04.008.

O. Faruk, M. Sain, R. Farnood, Y. Pan and H. Xiao, J. Polym. Environ., 22, 279 (2014); doi:10.1007/s10924-013-0631-x.

M.M.A. Nikje, M. Haghshenas and A.B. Garmarudi, Polym. Bull., 56, 257 (2006); doi:10.1007/s00289-005-0470-6.

S.E. Liang, C.R. Tian, J.H. Wang and C.R. Wei, China Plastics, 90 (2010).

L.G. Xiao, J. Luo and B. Zhang, New Building Materials, 57 (2009).

L. Liu, X.H. Liu, C.C. Chao, X.Y. Sun, S.P. Weng, D.F. Xu and J.G. Wu, Spectrosc. Spectr. Anal., 536 (2004).

C.L. Shi, L.Q. Chen, F.X. Qiu and D.Y. Yang, Sci. Technol. Chem. Ind., 9 (2008).

Issue

Vol. 27 No. 9 (2015): Vol 27 Issue 9

NdCl3-Schiff Base Complex as Catalyst for Formation of Water-Blown Semi-Rigid Polyurethane Foam

Corresponding Author(s) : Anping Liao

Abstract

Keywords

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